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    Wyświetlanie 1-9 z 9
    Tytuł:
    Prediction of Detonation Pressure and Velocity of Explosives with Micrometer Aluminum Powders
    Autorzy:
    Zhang, Q.
    Chang, Y.
    Powiązania:
    https://bibliotekanauki.pl/articles/358334.pdf
    Data publikacji:
    2012
    Wydawca:
    Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
    Tematy:
    aluminized explosives
    detonation pressure
    nonideal explosives
    detonation velocity
    Opis:
    The data reported shows that the Chapman-Jouguet (CJ) detonation parameters of non-ideal explosives calculated from existing thermodynamic computer codes are significantly different from experimental results. We use CJ detonation theory to present a new approach predicting detonation pressure and velocity of aluminized explosives by thermodynamic detonation theory. There is no need to use the assumption of full and partial equilibrium of aluminum powder in reaction zones in the new approach. In this work the best agreement with experimental data was obtained by adjusting the parameter k in the Becker- Kistiakosky-Wilson equations of state (BKW-EOS). The detonation pressure and velocity values calculated by the present method agree well with the experimental results. All of the deviations for the calculated pressures of aluminized explosives are less than 9% and those for the detonation velocities are less than 7%.
    Źródło:
    Central European Journal of Energetic Materials; 2012, 9, 1; 77-86
    1733-7178
    Pojawia się w:
    Central European Journal of Energetic Materials
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Detonation Parameters of PlSEM Plastic Explosive
    Autorzy:
    Cardoso, Aline Anastacio
    Selesovsky, Jakub
    Künzel, Martin
    Kucera, Jindrich
    Pachman, Jiri
    Powiązania:
    https://bibliotekanauki.pl/articles/358518.pdf
    Data publikacji:
    2019
    Wydawca:
    Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
    Tematy:
    Detonation velocity
    PlSEM
    plastic explosive
    detonation pressure
    cylinder test
    Opis:
    PlSEM is a plastic explosive based on RDX, PETN and a non-explosive binder, and is used in linear shaped charges for demolition purposes. Its experimentally obtained detonation parameters are presented in the present paper. The detonation velocity was measured for cylindrical charges of various diameters, with and without confinement. The detonation pressure and particle velocity were determined using an impedance window matching technique, and cylinder tests were used to obtain the parameters of the JWL equation of state of the detonation products. Detonation velocities from 7.75 to 8.05 km·s–1 were obtained for unconfined charges with diameters from 4 to 8 mm, and from 8.15 to 8.24 km·s–1 for charges with 25 mm diameter. The experimentally determined detonation pressure was found to be 24.6 GPa.
    Źródło:
    Central European Journal of Energetic Materials; 2019, 16, 4; 487-503
    1733-7178
    Pojawia się w:
    Central European Journal of Energetic Materials
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    The Role of Product Composition in Determining Detonation Velocity and Detonation Pressure
    Autorzy:
    Politzer, P.
    Murray, J. S.
    Powiązania:
    https://bibliotekanauki.pl/articles/358258.pdf
    Data publikacji:
    2014
    Wydawca:
    Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
    Tematy:
    detonation velocity
    detonation pressure
    density
    detonation product composition
    detonation heat release
    Opis:
    Four sets of rules for predicting the detonation product compositions of explosives have been investigated: the Kamlet-Jacobs, the KistiakowskyWilson, the modified Kistiakowsky-Wilson and the Springall-Roberts. These can result, for a given compound, in significantly differing detonation products and amounts of heat release. However the resulting detonation velocities D and detonation pressures P obtained for the compound using the Kamlet-Jacobs equations are generally quite similar, with the Kamlet-Jacobs rules leading to the D and P that are, on average, closest to the experimental. The fact that the variations among the D and P values are relatively small can be attributed to a balancing of opposing effects relating to the quantities of gaseous products and the heat releases. Accordingly, obtaining reasonable accuracy for D and P does not necessarily imply corresponding accuracy for the product composition and heat release that were used. The analysis presented explains the observations that D and P can be correlated with loading density alone, even though product compositions are known to change with density.
    Źródło:
    Central European Journal of Energetic Materials; 2014, 11, 4; 459-474
    1733-7178
    Pojawia się w:
    Central European Journal of Energetic Materials
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Detonation Performance of Four Groups of Aluminized Explosives
    Autorzy:
    Xiang, D.-L.
    Rong, J.-L.
    He, X.
    Powiązania:
    https://bibliotekanauki.pl/articles/358148.pdf
    Data publikacji:
    2016
    Wydawca:
    Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
    Tematy:
    aluminized explosive
    detonation pressure
    detonation velocity
    heat of detonation
    KHT code
    Opis:
    The detonation performances of TNT-, RDX-, HMX-, and RDX/AP-based aluminized explosives were examined through detonation experiments. The detonation pressure, velocity, and heat of detonation of the four groups of aluminized explosives were measured. Reliability verification was conducted for the experimental results and for those calculated with an empirical formula and the KHT code. The test results on detonation pressures and velocities were in good agreement with the predicted values when aluminum (Al) particles were considered inert. The experimental heat of detonation values exhibited good consistency with the predicted values when a certain proportion of Al particles was active. Ammonium perchlorate (AP) can effectively reduce the detonation pressure and improve the heat of detonation for the RDX/AP-based aluminized explosive. A comparison of the current test results and literature data shows that errors may exist in early test data. The test data presented in this study allow for an improved understanding of the detonation performance of the four groups of aluminized explosives.
    Źródło:
    Central European Journal of Energetic Materials; 2016, 13, 4; 903-915
    1733-7178
    Pojawia się w:
    Central European Journal of Energetic Materials
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Some Perspectives on Estimating Detonation Properties of C, H, N, O Compounds
    Autorzy:
    Politzer, P.
    Murray, J. S.
    Powiązania:
    https://bibliotekanauki.pl/articles/358498.pdf
    Data publikacji:
    2011
    Wydawca:
    Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
    Tematy:
    detonation velocity
    detonation pressure
    density
    enthalpy of formation
    detonation product composition
    explosives
    Opis:
    We have explored various aspects of the Kamlet-Jacobs equations for estimating detonation velocities and pressures. While the loading density of the explosive compound is certainly an important determinant of these properties, its effect can sometimes be overridden by other factors, such as the detonation heat release and/or the number of moles of gaseous products. Using a gas phase rather than solid phase enthalpy of formation in obtaining a compound's heat release can produce a signifcant error in the calculated detonation velocity. However a negative enthalpy of formation is not necessarily incompatible with excellent detonation properties. Additional evidence is presented to support Kamlet and Jacobs' conclusion that, for C, H, N, O explosives, assuming the detonation product composition to be N2(g)/H2O(g)/CO2(g)/C(s) gives overall quite satisfactory results.
    Źródło:
    Central European Journal of Energetic Materials; 2011, 8, 3; 209-220
    1733-7178
    Pojawia się w:
    Central European Journal of Energetic Materials
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Calculation of Thermochemical and Explosive Characteristics of Furoxanes
    Autorzy:
    Zhukov, I.
    Kozak, G. D.
    Powiązania:
    https://bibliotekanauki.pl/articles/358541.pdf
    Data publikacji:
    2008
    Wydawca:
    Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
    Tematy:
    furoxanes
    benzofuroxanes
    high-power energetic materials
    heat of detonation
    detonation velocity
    detonation pressure
    Opis:
    Search of high-power energetic materials is one primary line of development of chemical physics of combustion and explosion. Yield of such materials is usually very small, and its cost is very high. Calculation of unknown characteristics and properties is the only way out from this situation. There are different methods today that allow calculating unknown detonation performance and some of physicochemical properties. Examination of calculated detonation performance of furoxanes and benzofuroxanes compounds that are not enough investigated is presented in this work. These compounds are new high-power energetic materials. Influence of error in enthalpy of formation of these compounds on their detonation performance is also examined in this work. Furoxanes plays particular part among energetic materials. They are convenient blocks of molecules of high-power energetic materials. Joining of explosiphorus clusters of atoms are lead to obtaining of number of high-performance compounds. It is caused by flatten structure of furoxane ring, that lead to high density of compounds and are characterized by high and positive value of enthalpy of formation. Detonation performance of furoxanes was not study practically. That is why 10 furoxanes have been chosen as object of study (see Nomenclature). 7 of 10 studied furoxanes have anomalous elemental composition, because they are hydrogenfree. In order to evaluate possible error in computational detonation performance, explosive characteristics of 6 hydrogen-free energetic materials with known experimental data have been calculated.
    Źródło:
    Central European Journal of Energetic Materials; 2008, 5, 3-4; 45-54
    1733-7178
    Pojawia się w:
    Central European Journal of Energetic Materials
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Detonation Performance of Oxygen-rich Trinitromethylsubstituted Pyrazoles: an in-silico Investigation
    Autorzy:
    Naithani, N.
    George, B. K.
    Powiązania:
    https://bibliotekanauki.pl/articles/358132.pdf
    Data publikacji:
    2018
    Wydawca:
    Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
    Tematy:
    nitropyrazole
    aminonitropyrazoles
    detonation velocity
    detonation pressure
    density functional theory
    high energy molecules
    Opis:
    A new class of high energy molecules was designed and their detonation properties were evaluated using thermo-chemical parameters obtained from quantum chemical calculations at B3LYP/6-31G(d,p) level. The designed molecules exhibited high density, positive oxygen balance and excellent detonation properties. The impact sensitivity of these molecules, in terms of H50 values, was also evaluated from structural correlations. Among these, 3,4,5-tris(trinitromethyl)1H-pyrazol-1-amine (N13) showed the highest detonation pressure (40.67 GPa) and highest detonation velocity (9.17 km/s), though it exhibited high impact sensitive (H50 = 15 cm). Interestingly, 4,5-dinitro-3-(trinitromethyl)-1H-pyrazol-1-amine (N01) (detonation pressure 39.69 GPa; detonation velocity 9.23 km/s) was found to be an ideal high energy molecule with a near zero oxygen balance. The H50 value of N01 was predicted to be 64 cm, which is higher in magnitude, indicating a lower sensitivity than that of the conventionally used RDX (H50 = 26 cm).
    Źródło:
    Central European Journal of Energetic Materials; 2018, 15, 4; 537-533
    1733-7178
    Pojawia się w:
    Central European Journal of Energetic Materials
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Nitro Groups vs. N-Oxide Linkages: Effects Upon Some Key Determinants of Detonation Performance
    Autorzy:
    Politzer, P.
    Murray, J. S.
    Powiązania:
    https://bibliotekanauki.pl/articles/358223.pdf
    Data publikacji:
    2017
    Wydawca:
    Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
    Tematy:
    C,H,N,O explosives
    detonation velocity
    detonation pressure
    N-oxides
    polyazines
    polyazoles
    detonation heat release
    crystal density
    heats of formation
    gaseous detonation products
    Opis:
    Increasing the nitrogen/carbon ratios in the molecular frameworks of C,H,N,O explosives has attracted considerable attention because it tends to result in more positive heats of formation and often greater densities. In conjunction with this, there has been a growing interest in N-oxide linkages, N+ → O−, as another source of oxygen in these compounds, in addition to or even possibly replacing NO2 groups. In this study, for a series of polyazines and polyazoles, we have compared the effects of introducing a single N-oxide linkage or NO2 group upon key properties that affect detonation velocity and detonation pressure. We found that: (1) The heats of formation per gram of compound, which is what is relevant for this purpose, are almost always higher for the N-oxides. (2) The nitro derivatives have greater densities and detonation heat releases. In relation to the latter, it must be kept in mind that increasing detonation heat release tends to be accompanied by increasing sensitivity. (3) The N-oxides produce more moles of gaseous detonation products per gram of compound.
    Źródło:
    Central European Journal of Energetic Materials; 2017, 14, 1; 3-25
    1733-7178
    Pojawia się w:
    Central European Journal of Energetic Materials
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Study on the Detonation Parameters of Aluminized Explosives Based on a Disequilibrium Multiphase Model
    Autorzy:
    Pei, H.
    Nie, J.
    Jiao, Q.
    Powiązania:
    https://bibliotekanauki.pl/articles/358535.pdf
    Data publikacji:
    2014
    Wydawca:
    Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
    Tematy:
    nonideal explosives
    velocity of detonation
    detonation pressure
    relaxation timescale
    Opis:
    Detonation models are usually based on the classical Euler equations of gas dynamics under the assumption of thermodynamic equilibrium. However reported data show the Chapman-Jouguet (CJ) detonation parameters of nonideal explosives based on thermodynamic equilibrium codes are significantly different from experimental results. Based on the conventional CJ model, a new multiphase flow model, not in thermal equilibrium, was considered in this study. This approach was applied to compute the velocity of detonation for several aluminized explosives. The predictions are better than the CJ equilibrium model and are in excellent agreement with experimental data. All of the deviations for the velocity of detonation (VOD) are less than 4%.
    Źródło:
    Central European Journal of Energetic Materials; 2014, 11, 4; 491-500
    1733-7178
    Pojawia się w:
    Central European Journal of Energetic Materials
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
      Wyświetlanie 1-9 z 9

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