- Tytuł:
- Preparation, Structure and Kinetic Analysis of the Thermal Behavior of Some Energetic Salts of 3-Hydrazino-4-amino-1,2,4-triazole
- Autorzy:
-
Wu, J. T.
Zhang, J. G.
Sun, M.
Yin, X.
Zhang, T. L. - Powiązania:
- https://bibliotekanauki.pl/articles/358073.pdf
- Data publikacji:
- 2013
- Wydawca:
- Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
- Tematy:
-
synthesis
crystal structure
thermal analysis
3-hydrazino-4-amino-1,2,4-triazole
energetic salts - Opis:
- As a key research objective for low melting explosives and propellants, energetic salts have received worldwide attention. 3-Hydrazino-4-amino-1,2,4triazole (HATr) is an important high-nitrogen compound (73.65% N) with good stability. This paper focuses on the energetic salts which were formed between HATr and picric acid (PA) or 2,4,6-trinitroresorcinol (TNR). Single crystals of HATr·PA and HATr·TNR·H2O were grown and their crystal structures determined at low temperature. They both belong to the monoclinic system, P21/n space group. The thermal characteristics of the two target salts were investigated using DSC and TG-DTG. In addition, the non-isothermal decomposition kinetics, heats of combustion and sensitivity have also been investigated. The detonation pressures (P) and detonation velocities (D) of the salts have been calculated using the K-J equations. The results indicated that both salts have certain potential applications as gunpowder and propellant materials.
- Źródło:
-
Central European Journal of Energetic Materials; 2013, 10, 4; 481-493
1733-7178 - Pojawia się w:
- Central European Journal of Energetic Materials
- Dostawca treści:
- Biblioteka Nauki
Artykuł