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Wyświetlanie 1-3 z 3
Tytuł:
Energetic Nitrogen-rich Salts
Autorzy:
Wu, J.-W.
Zhang, J.-G.
Zhang, T.-L.
Yang, L.
Powiązania:
https://bibliotekanauki.pl/articles/358479.pdf
Data publikacji:
2015
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
energetic salts
synthesis
characterization
crystal structure
review
Opis:
Energetic salts as a unique class of energetic materials have recently been investigated widely, since they possess advantages over their atomically similar nonionic analogues – they tend to exhibit lower vapor pressures, higher densities and better thermal stabilities. Furthermore, these salts are readily improved upon by the appropriate combination of different cations and anions. Over the last twenty years, our group has continued to synthesize and study novel ionic energetic materials. Here, we have summarized all of the series of nitrogen-rich energetic salts. This review gives an overview of the various studies dealing with synthetic aspects and some of the physicochemical properties of ionic compounds that are based on ammonia, guanidine, semicarbazide, carbohydrazide, tetrazine, tetrazole, triazole and imidazole. In addition, their potential applications in the fields of explosives and propellants are discussed. We hope these investigations will be helpful in providing a wider insight for future research in the area of energetic salts.
Źródło:
Central European Journal of Energetic Materials; 2015, 12, 3; 417-437
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Predicted Crystal Structures, Analysis, Impact Sensitivities and Morphology of Solid High-Energy Complexes: Alkaline-Earth Carbohydrazide Perchlorates
Autorzy:
Liu, Y.
Zhang, R.
Feng, C.-G.
Yang, L.
Zhang, T.-L.
Powiązania:
https://bibliotekanauki.pl/articles/358890.pdf
Data publikacji:
2015
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
crystal structure
density of state
thermodynamic property
impact sensitivity
crystal morphology
Opis:
The crystal structures, density of states, energy gap, thermodynamic properties, impact sensitivities and morphology of beryllium carbohydrazide perchlorate ([Be(CHZ)3](ClO4)2), magnesium carbohydrazide perchlorate ([Mg(CHZ)3](ClO4)2), calcium carbohydrazide perchlorate ([Ca(CHZ)3] (ClO4)2), strontium carbohydrazide perchlorate ([Sr(CHZ)3](ClO4)2) and barium carbohydrazide perchlorate ([Ba(CHZ)3](ClO4)2) were investigated using the density functional theory (DFT) and crystal morphology theory. The results show that all of the complexes have six-coordinated distorted octahedra, which is different from previous works. This was rationalised by consideration of the intermolecular interactions in the crystal structures. Hence the crystal structure is now more reliable. The chemical reactions of the whole molecule may be triggered by an electron transition of CHZ or ClO4 −. Furthermore the energy gaps were observed, and the values of the impact sensitivities were inferred to have the following sequence: [Be(CHZ)3](ClO4)2 > [Mg(CHZ)3](ClO4)2 > [Sr(CHZ)3](ClO4)2 > [Ca(CHZ)3](ClO4)2 > [Ba(CHZ)3](ClO4)2. In addition, the thermodynamic equations at 25-1000 K were obtained. The positive values of the standard molar free enthalpies shows that carbohydrazide perchlorates are stable at 298.15 K. The (1 0 -1) and (0 0 2) faces are the most important growth directions of the crystal morphologies, and have the minimum growth rates. From the cleaved main growth faces, it can be deduced that surface active agents with active hydrogen atoms in the functional groups could be used as crystal-control reagents to control the crystal morphology for alkaline-earth carbohydrazide perchlorates.
Źródło:
Central European Journal of Energetic Materials; 2015, 12, 2; 229-248
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Preparation, Structure and Kinetic Analysis of the Thermal Behavior of Some Energetic Salts of 3-Hydrazino-4-amino-1,2,4-triazole
Autorzy:
Wu, J. T.
Zhang, J. G.
Sun, M.
Yin, X.
Zhang, T. L.
Powiązania:
https://bibliotekanauki.pl/articles/358073.pdf
Data publikacji:
2013
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
synthesis
crystal structure
thermal analysis
3-hydrazino-4-amino-1,2,4-triazole
energetic salts
Opis:
As a key research objective for low melting explosives and propellants, energetic salts have received worldwide attention. 3-Hydrazino-4-amino-1,2,4triazole (HATr) is an important high-nitrogen compound (73.65% N) with good stability. This paper focuses on the energetic salts which were formed between HATr and picric acid (PA) or 2,4,6-trinitroresorcinol (TNR). Single crystals of HATr·PA and HATr·TNR·H2O were grown and their crystal structures determined at low temperature. They both belong to the monoclinic system, P21/n space group. The thermal characteristics of the two target salts were investigated using DSC and TG-DTG. In addition, the non-isothermal decomposition kinetics, heats of combustion and sensitivity have also been investigated. The detonation pressures (P) and detonation velocities (D) of the salts have been calculated using the K-J equations. The results indicated that both salts have certain potential applications as gunpowder and propellant materials.
Źródło:
Central European Journal of Energetic Materials; 2013, 10, 4; 481-493
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-3 z 3

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