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Wyświetlanie 1-2 z 2
Tytuł:
Modified bentonite-derived materials as catalystsfor selective catalytic reduction of nitrogen oxides
Autorzy:
Szymaszek, Agnieszka
Kubeł, Maciej
Samojeden, Bogdan
Motak, Monika
Powiązania:
https://bibliotekanauki.pl/articles/185436.pdf
Data publikacji:
2020
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
pillared bentonite
acid activation
alumina
iron
copper
selective catalytic reduction
NO
DeNO
aktywacja kwasem
glinka
żelazo
miedź
Selektywna redukcja katalityczna
Opis:
In the last few years, cationic layered clays, including bentonites have been investigated as potentialcatalysts for SCR DeNOxsystems. In this work, bentonite as the representative of layered clays wasmodified in order to obtain an alternative, low-cost NH3–SCR catalyst. Samples of raw clay wereactivated with HCl or HNO3, treated with C2H2O4and subsequently pillared with alumina by the ion-exchange. Afterwards, the modified materials were impregnated with iron and copper. The obtainedcatalysts were characterized by XRD and FT-IR. SCR catalytic tests carried out over analyzed samplesindicated the conversion of NO of approximately 90% for the most active sample. The type of acidused for modification and the type of active phase strongly influenced the catalytic properties of theanalyzed materials.
Źródło:
Chemical and Process Engineering; 2020, 41, 1; 13--24
0208-6425
2300-1925
Pojawia się w:
Chemical and Process Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Physicochemical properties and NH3-SCR catalytic performance of intercalated layered aluminosilicates
Autorzy:
Szymaszek-Wawryca, Agnieszka
Díaz, Urbano
Samojeden, Bogdan
Motak, Monika
Powiązania:
https://bibliotekanauki.pl/articles/24085707.pdf
Data publikacji:
2023
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
bentonite
DeNOx
pillaring
iron
copper
Opis:
The representative of natural layered clays, bentonite, was modified according to two routes and tested as a new catalyst for selective catalytic reduction of nitrogen oxides with ammonia (NH3-SCR). The natural acid-activated clay was ion-exchanged with Na+ or remained in H-form and pillared with metal oxides. In order to limit the number of synthesis steps, iron as an active phase was introduced simultaneously with Al2O3 during the intercalation procedure. Additionally, the samples were doped with 0.5 wt% of copper to promote low-temperature activity. It was found that the performed modifications resulted in disorganization of the ordered layered arrangement of bentonite. Nevertheless, acid activation and pillaring improved structural and textural parameters. The results of catalytic tests indicated that the samples containing Fe2O3 pillars promoted with Cu exhibited the highest NO conversion of 85% at 250°C (H-Bent-AlFe-Cu) and 75% at 300°C (Na-Bent-AlFe-Cu). What is important, activity of the protonated samples in the high-temperature region was noticeably affected by the side reaction of ammonia oxidation, correlated with the production of NO and resulting in N2O emission during the process comparing to Na-Bentonite catalysts.
Źródło:
Physicochemical Problems of Mineral Processing; 2023, 59, 4; art. no. 171381
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-2 z 2

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