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Tytuł:
Nitrogen and carbon dioxide fracturing fluids for the stimulation of unconventional shale plays
Autorzy:
Palmer, C.
Sito, Z.
Powiązania:
https://bibliotekanauki.pl/articles/299070.pdf
Data publikacji:
2013
Wydawca:
Akademia Górniczo-Hutnicza im. Stanisława Staszica w Krakowie. Wydawnictwo AGH
Tematy:
nitrogen
carbon dioxide
fracturing fluids
shale gas
Opis:
With the International Energy Agency (IEA) projecting that the global demand for natural gas to increase by 50% from 2010 to 2035, the exploration of unconventional gas reserves (e.g. shale gas, tight gas and coal bed methane) will gain increasing importance as conventional gas reserves become more depleted. To enhance the production of unconventional gas and oil, water-based fracturing fluids are extensively used for the stimulation of North American shale plays because they are inexpensive and offer excellent proppant transport into the fracture when used with gelled polymers. However, in circumstances where water-based fracturing fluids are unsuitable due to concerns related to water sensitivity and clay swelling, alternative fracturing fluids are used such as nitrogen and carbon dioxide treatments. Nitrogen and carbon dioxide fracturing fluids are particularly advantageous in depleted and shallow formations because they offer a non-damaging effect around the fracture, rapid cleanup of flowback fluid, and reduced water requirements compared to conventional water-based fracturing fluids. Much research has been published about water-based fracture treatments, therefore, this review paper considers the use of nitrogen and carbon dioxide fracturing fluids used for the stimulation of unconventional shale plays, mainly in North America. By analysing selected literatures studies, this review paper summarises the utilization of the various types of nitrogen and carbon dioxide treatments (i.e. straight gas, foam, energized, cryogenic liquids) across various shale plays such as the Montney play, the Devonian play, and the Marcellus play. The paper further identifies the major benefits and challenges of nitrogen and carbon dioxide treatments documented by well operators, which will facilitate knowledge transfer about the applicability of nitrogen and carbon dioxide fracturing fluids.
Źródło:
AGH Drilling, Oil, Gas; 2013, 30, 1; 191-198
2299-4157
2300-7052
Pojawia się w:
AGH Drilling, Oil, Gas
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The Biomethanization Gas Purification of Using Chlorophyll-Synthesizing Microalgae
Autorzy:
Dyachok, Vasil
Venher, Liubov
Huhlych, Sergij
Powiązania:
https://bibliotekanauki.pl/articles/2173378.pdf
Data publikacji:
2022
Wydawca:
Polskie Towarzystwo Inżynierii Ekologicznej
Tematy:
microalgae
Chlorella vulgaris
biogas
carbon dioxide
hydrogen sulfide
ammonia
nitrogen oxide
sulfur dioxide
Opis:
The paper shows the possibility of using chlorophyll-synthesizing microalgae of Chlorella vulgaris to purify biogas from carbon dioxide (CO2), hydrogen sulfide (H2S) and ammonia (NH3). Experimental dependences of the dynamics of CO2 uptake by microalgae under the action of H2S inhibitor and NH3 activator were presented. A mathematical description of the growth of biomass of microalgae Chlorella vulgaris, depending on the concentration of hydrogen sulfide and ammonia, was obtained. The optimal values of hydrogen sulfide and ammonia concentration for the efficient process of carbon dioxide uptake by chlorophyll-synthesizing microalgae Chlorella vulgaris from biomethanization gas were established.
Źródło:
Journal of Ecological Engineering; 2022, 23, 9; 259--264
2299-8993
Pojawia się w:
Journal of Ecological Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
About the Optimal Ratio Inhibitor and Activators of Carbon Dioxide Sorption Process by Using Chlorophyll-synthesizing Chlorella microalgae
Autorzy:
Dyachok, Vasil
Mandryk, Solomiia
Huhlych, Serhiy
Powiązania:
https://bibliotekanauki.pl/articles/1838425.pdf
Data publikacji:
2021
Wydawca:
Polskie Towarzystwo Inżynierii Ekologicznej
Tematy:
Chlorella microalgae
carbon dioxide
phosphorus oxide
nitrogen oxide
sulfur dioxide
inhibitor
activator
mathematical description
Opis:
The suppression of the inhibition effect by SO2 sulfur dioxide with the simultaneous action of two activators – P2O5 phosphorus oxide and NxOy nitrogen oxide, as well as the process of carbon dioxide absorption by chlorophyll-synthesizing microalgae Chlorella were studied in this work. The experimental dependences of the СО2 uptake dynamics by microalgae under the conditions of the SO2 inhibitor critical concentration action and the simultaneous presence of P2O5 and NxOy activators were shown. A mathematical description of the Chlorella microalgae biomass growth depending on the P2O5 and NxOy activators concentration, provided that there is a SO2 inhibitor constant concentration was obtained. The optimum values of the P2O5 phosphorus oxide and NxOy nitrogen oxides concentration at the SO2 inhibitor critical concentration for the carbon dioxide absorption by chlorophyll-synthesizing microalgae Chlorella process were established.
Źródło:
Journal of Ecological Engineering; 2021, 22, 5; 26-31
2299-8993
Pojawia się w:
Journal of Ecological Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Towards clean energy production
Autorzy:
Dors, M.
Powiązania:
https://bibliotekanauki.pl/articles/175564.pdf
Data publikacji:
2015
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
emission control
exhaust
nitrogen oxides
sulfur oxides
carbon dioxide
Opis:
Implementation of stringent regulations of emission from power plants requires the development of new strategies and technologies for removal of pollutants from exhaust gases. This article summarizes current state of PM, NOx, SO2 and CO2 abatement methods. The review is focused on the methods proved in industrial practice at commercially available and pilot installations.
Źródło:
Transactions of the Institute of Fluid-Flow Machinery; 2015, 127; 91-116
0079-3205
Pojawia się w:
Transactions of the Institute of Fluid-Flow Machinery
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Impact of land use change on greenhouse gases emissions in peatland: a review
Autorzy:
Hatano, R.
Powiązania:
https://bibliotekanauki.pl/articles/2082481.pdf
Data publikacji:
2019
Wydawca:
Polska Akademia Nauk. Instytut Agrofizyki PAN
Tematy:
carbon dioxide
ground water table
methane
nitrogen fertilizer
nitrous oxide
peatland
Opis:
Peatland is a significant storage of carbon and nitrogen on the earth’s surface. This paper reviews the impacts of changes in water table level and mineral nitrogen associated with human activities on greenhouse gases emissions in tropical peatland and northern boreal and temperate peatland, and evaluates the optimal water table level to minimize greenhouse gases emissions. CH4 emission increased significantly with the rise of ground water table level above -20 cm, and larger in northern peatland with plant mediated CH4 emission than tropical peatland with plant mediated oxygen supply. However, forest disturbance by fire in tropical peatland increased CH4 flux to the similar level in northern peatlands (8.3 mg C m-2 h-1) due to stagnant surface water associated with the peat subsidence. On the other hand, CO2 and N2O emissions were significantly lager in tropical peatland than in northern peatland especially due to nitrogen fertilization. CO2 and N2O emissions increased with falling ground water table level below -40 to -80 cm (19 Mg C ha-1 y-1 for CO2 and 700 kg N ha-1 y-1 for N2O). Total global warming potential was significantly low in the ground water table level from -20 and -40 cm.
Źródło:
International Agrophysics; 2019, 33, 2; 167-173
0236-8722
Pojawia się w:
International Agrophysics
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Characteristics of the spring/summer production in the Mecklenburg Bight (Baltic Sea) as revealed by long-term pCO2 data
Autorzy:
Schnaider, B.
Buecker, S.
Kaitala, S.
Maunula, P.
Wasmund, N.
Powiązania:
https://bibliotekanauki.pl/articles/47443.pdf
Data publikacji:
2015
Wydawca:
Polska Akademia Nauk. Instytut Oceanologii PAN
Tematy:
Mecklenburg Bight
Baltic Sea
carbon dioxide
surface water
spring bloom
nitrogen fixation
Źródło:
Oceanologia; 2015, 57, 4
0078-3234
Pojawia się w:
Oceanologia
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effect of Fuel Combustion Products on Carbon Dioxide Uptake Dynamics of Chlorophyll Synthesizing Microalgae
Autorzy:
Dyachok, Vasyl Volodymyrovych
Mandryk, Solomiya
Katysheva, Victiria
Huhlych, Serhiy
Powiązania:
https://bibliotekanauki.pl/articles/123458.pdf
Data publikacji:
2019
Wydawca:
Polskie Towarzystwo Inżynierii Ekologicznej
Tematy:
carbon dioxide
sulfur oxides
nitrogen oxides
phosphorus oxides
Chlorella
chlorophyll synthesizing microalgae
biomass growth
Opis:
The research on the effect of sulfur oxides (SO2), nitrogen oxides (NxOy) and phosphorus oxides (P2O5) on carbon dioxide (CO2) uptake dynamics of chlorophyll synthesizing microalgae was conducted. The analytic dependences of microalgae growth rates under their CO2 uptake, SO2, NxOy and P2O5 concentrations were obtained. Mathematical models enabling to predict the maximum values of SO2, NxOy and P2O5 oxides concentrations without inhibiting the CO2 uptake dynamics of chlorophyll synthesizing microalgae were built based on the obtained experimental research results.
Źródło:
Journal of Ecological Engineering; 2019, 20, 6; 18-24
2299-8993
Pojawia się w:
Journal of Ecological Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Origin of natural gases in the autochthonous Miocene strata of the Ukrainian Carpathian Foredeep and its Mesozoic basement
Autorzy:
Kotarba, M. J.
Koltun, Y. V.
Powiązania:
https://bibliotekanauki.pl/articles/191381.pdf
Data publikacji:
2011
Wydawca:
Polskie Towarzystwo Geologiczne
Tematy:
microbial gases
thermogenic gases
stable carbon isotopes
stable hydrogen isotopes
carbon dioxide
nitrogen
Miocene strata
Mesozoic strata
Opis:
Methane concentrations in natural gases accumulated in the Lower and Upper Badenian and Lower Sarmatian reservoirs of the Bilche-Volytsia Unit in the western part of the Ukrainian Carpathian Foredeep usually exceed 96 vol%. Methane was generated by microbial reduction of carbon dioxide in the marine environment. Microbial methane and ethane were produced mainly during sedimentation of Miocene clays and muds. It is possible that this microbial process continues today. Higher light hydrocarbons (ethane in part, and mainly propane, butanes and pentanes) were generated during the diagenesis and the initial stage of the low-temperature, thermogenic processes from Type III and III/II kerogen deposited in Miocene strata and/or Middle and Upper Jurassic basement rocks. Limited variations in the values of geochemical hydrocarbon indices and stable isotope ratios of methane, ethane and propane with the depth indicate similar gas generation conditions within the whole Miocene succession. The microbial gases (methane and partly ethane) generated during microbial processes within the Miocene strata later migrated to the Upper Jurassic and the Upper Cretaceous (Cenomanian) reservoirs of the Mesozoic basement, and to the bottommost Lower Badenian reservoirs of the analysed Letnia, Orkhovychi, Rudky and Vereshchytsia fields. The low hydrogen concentrations within the Miocene strata as well as within the Upper Jurassic and the Upper Cretaceous (Cenomanian) reservoirs of the Mesozoic basement, and within the bottommost Lower Badenian reservoirs are also related to microbial processes. Carbon dioxide and nitrogen, which are common minor constituents, were generated by both microbial and low-temperature thermogenic processes. Moreover, CO2 also underwent secondary processes, mainly dissolution in water, during migration. At least part of the nitrogen accumulated in the Rudky field, which is remarkably high in N2 (96.9 vol%), is probably of atmospheric origin and was introduced to the reservoir by secondary recovery methods.
Źródło:
Annales Societatis Geologorum Poloniae; 2011, 81, No 3; 425-441
0208-9068
Pojawia się w:
Annales Societatis Geologorum Poloniae
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Thermogenic gases generated from coals and shales of the Upper Silesian and Lublin basins : hydrous pyrolysis approach
Autorzy:
Kotarba, Maciej J.
Bilkiewicz, Elżbieta
Jurek, Krzysztof
Waliczek, Marta
Więcław, Dariusz
Zych, Hieronim
Powiązania:
https://bibliotekanauki.pl/articles/2059608.pdf
Data publikacji:
2021
Wydawca:
Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
Tematy:
hydrous pyrolysis gas
gaseous hydrocarbon
carbon dioxide
molecular nitrogen
stable C, H, N isotopes
Upper Silesian
Lublin Coal basins
Opis:
In order to provide a better characterization of the origin and volume of thermogenic gas generation hydrous pyrolysis (HP) experiments were performed on coals and shales at 330 and 360oC for 72 hours. The maturity range of coals and shales used for HP varies from 0.57 to 0.92% Ro. The maturity increase caused by HP at 330 and 360oC ranges from 1.32 to 1.39% and from 1.71 to 1.83%, respectively. δ13C of CH4, 2H6, C3H6 and n-C4H10 in HP gases versus their reciprocal C-number have a concave relationship, and therefore do not follow a linear trend. δ2H of CH4, 2H6 and C3H6 in HP gases versus their reciprocal H-number show both linear and convex-concave relationships. The growth of CO2 yields during HP was higher for shales than for coals. H2S yields from shales are higher than from coals, which can be connected with catalytic and adsorbed influence of shale matrix. H2 was also generated in notable quantities from water and organic matter of coals and bigger amounts from shales. N2 yields grow with the increase of Ro after 3oC HP and it is more enriched in 15N isotope than after 330C.
Źródło:
Geological Quarterly; 2021, 65, 2; 65: 26
1641-7291
Pojawia się w:
Geological Quarterly
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
PO4 release at the sediment surface under anoxic conditions: a contribution to the eutrophication of the Baltic Sea?
Autorzy:
Schneider, B.
Powiązania:
https://bibliotekanauki.pl/articles/49162.pdf
Data publikacji:
2011
Wydawca:
Polska Akademia Nauk. Instytut Oceanologii PAN
Tematy:
anoxia
biogeochemical condition
carbon dioxide
deep water
dissolved inorganic nitrogen
eutrophication
hydrogen sulphide
mineralization
nutrient concentration
oxygen
phosphate
sediment
Opis:
The vertical profiles of phosphate, total CO2 and oxygen/hydrogen sulphide were determined in the deep water of the Gotland Sea during March 2003 to July 2006 with a temporal resolution of 2–3 months. This time span included the shift from anoxic to oxic conditions resulting from a water renewal event, as well as the transition back to anoxic waters during the subsequent two-year stagnation period. The data from depths below 150 m were used to identify and quantify phosphate release and removal processes. The relationship between the total CO2 generated by mineralization (CT1 min) and the PO4 concentrations indicated that the initial decrease in the phosphate concentrations after the inflow of oxygen-rich water was mainly a dilution effect. Only about one third of the PO4 removal was a consequence of the precipitation of insoluble iron-3-hydroxo-phosphates (Fe-P), which occurred slowly at the sediment surface under oxic conditions. From the CT1 min/PO4 ratios it was also concluded that the formation of Fe-P was reversed during the later phase of the stagnation, when the redoxcline approached a depth of 150 m. A phosphate mass balance was performed for four deep water sub-layers in order to quantify the dissolution of Fe-P during the stagnation period and thus to estimate the amount of Fe-P deposited during the last inflow of oxygen-rich water. A value of about 50 mmol-P m−2 was found, which refers to the specific biogeochemical conditions during the change from anoxic to oxic conditions that preceded the stagnation period.
Źródło:
Oceanologia; 2011, 53, (1-TI)
0078-3234
Pojawia się w:
Oceanologia
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Recruiting and using agricultural biogas
Pozyskiwanie i wykorzystanie biogazu rolniczego
Autorzy:
Kowalska, A.
Powiązania:
https://bibliotekanauki.pl/articles/793525.pdf
Data publikacji:
2011
Wydawca:
Komisja Motoryzacji i Energetyki Rolnictwa
Tematy:
biogas
agricultural biogas
biomass
renewable energy
biogas production
biogas composition
methane
carbon dioxide
hydrogen sulphide
carbon monoxide
nitrogen
oxygen
Opis:
We are calling gas acquired of biomass, in particular from the installation alterations of animal wastes or plant, of the sewage treatment plant and landfill sites. The large potential of the biogas production has the farming. In farm households considerable quantities of waste which can be used in the fermentation are arising. Special agricultural cultivations and waste of the food production are a next source of biomass. In the article vital statistics were described about biogas, the process of the biogas production and conditions in which he should run.
Biogazem nazywamy gaz pozyskany z biomasy, w szczególności z instalacji przeróbki odpadów zwierzęcych lub roślinnych, oczyszczalni ścieków oraz składowisk odpadów. Największy potencjał produkcji biogazu ma rolnictwo. W gospodarstwach hodowlanych powstają znaczne ilości odpadów, które mogą być wykorzystane w procesie fermentacji. Kolejnym źródłem biomasy są specjalne uprawy rolne oraz odpady produkcji spożywczej. W artykule przedstawiono podstawowe informacje na temat biogazu, procesu produkcji biogazu oraz warunków w jakich powinien przebiegać.
Źródło:
Teka Komisji Motoryzacji i Energetyki Rolnictwa; 2011, 11C
1641-7739
Pojawia się w:
Teka Komisji Motoryzacji i Energetyki Rolnictwa
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Origin of natural gases in the autochthonous Miocene strata of the Polish Carpathian Foredeep
Autorzy:
Kotarba, M. J.
Powiązania:
https://bibliotekanauki.pl/articles/191377.pdf
Data publikacji:
2011
Wydawca:
Polskie Towarzystwo Geologiczne
Tematy:
microbial methane
stable carbon isotopes
thermogenic hydrocarbon gases
carbon dioxide
nitrogen
sulphide hydrogen
autochthonous Miocene strata
Polish Carpathian Foredeep
Opis:
Methane concentrations in natural gases accumulated in the autochthonous Miocene strata of the Polish Carpathian Foredeep (between Kraków and Przemyśl) usually exceeded 90 vol%. Methane and part of the ethane were generated during microbial reduction of carbon dioxide in the marine environment, mainly during the sedimentation of Miocene clays and muds. It is possible that this microbial process has continued even recently. Higher light hydrocarbons (mainly propane, butanes and pentanes) were generated during the diagenesis and the initial stage of the low-temperature thermogenic process. Very small changes in the values of geochemical hydrocarbon indices and stable isotope ratios of methane, ethane and propane with depth are evidence for similar gas generation conditions within the whole Badenian and Lower Sarmatian successions. Only in a few natural gas accumulations within the Upper Badenian and Lower Sarmatian reservoirs are thermogenic gases or thermogenic components present, both generated from mixed, type III/II kerogen. These thermogenic gases, now accumulated mainly in the bottom part of Miocene strata, probably resulted from thermogenic processes in the Palaeozoic– Mesozoic basement and then migrated to the Miocene strata along the fault zones. The presence of low hydrogen concentrations (from 0.00 to 0.26 vol%) within the Miocene strata is related to recent microbial processes. Carbon dioxide and nitrogen, which are common minor constituents, were generated in both microbial and low-temperature thermogenic processes. However, CO2 has also undergone secondary processes, mainly dissolution in water during migration. Hydrogen sulphide, which occurs in natural gases of Lower Badenian strata, was most probably generated during microbial sulphate reduction of the Lower Badenian gypsum and anhydrites.
Źródło:
Annales Societatis Geologorum Poloniae; 2011, 81, No 3; 409-424
0208-9068
Pojawia się w:
Annales Societatis Geologorum Poloniae
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Estimating shipping emissions – A case study for cargo Port of Zadar, Croatia
Autorzy:
Knezević, V.
Pavin, Z.
Čulin, J.
Powiązania:
https://bibliotekanauki.pl/articles/2063981.pdf
Data publikacji:
2021
Wydawca:
Uniwersytet Morski w Gdyni. Wydział Nawigacyjny
Tematy:
Port of Zadar
air pollutant emission
estimating shipping emissions
nitrogen oxides
particulate matter
volatile organic compounds
carbon dioxide
green port
Opis:
Reducing air pollutant emissions and energy consumption, as a necessary step to make ports more sustainable, is one of the crucial tasks and challenges of port management. Some of the port strategies to meet the term “green port” usually include reducing fuel consumption from vessels and vehicles in ports. This paper estimates the emission inventory of maritime traffic for the cargo Port of Zadar. For this research, emissions from cargo ships are estimated in the period from January 01. 2018 until October 01. 2019. The “bottom-up” methodology has been applied for estimating emissions, which includes detailed data on the ship’s characteristics (engine power, the load factor, fuel type, the emission factor) and time spent cruising and hotelling. The emissions from cargo ships have been estimated for three ship’s activities: cruising in the reduced speed zone, hotelling (time spent at berth), and maneuvering. The emission results (tons/year) refer to the pollutants such as nitrogen oxides (NOx), sulphur oxides (SOx), particulate matter (PM), volatile organic compounds (VOC), and carbon dioxide (CO2) which represents greenhouse gases. Estimating emission inventory is the first step for planning effective port air quality control. Some recommendations for reducing emissions in port areas are emphasized in this paper.
Źródło:
TransNav : International Journal on Marine Navigation and Safety of Sea Transportation; 2021, 15, 3; 615--620
2083-6473
2083-6481
Pojawia się w:
TransNav : International Journal on Marine Navigation and Safety of Sea Transportation
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Szacowanie wartości opałowej i ciepła spalania gazu syntezowego powstającego w procesie zgazowywania karbonizatu otrzymanego z osadów ściekowych
Estimation of lower Heating value and higher heating value of syngas from carbonized sewage sludge gasifi cation
Autorzy:
Stępień, P.
Pulka, J.
Białowiec, A.
Powiązania:
https://bibliotekanauki.pl/articles/236328.pdf
Data publikacji:
2018
Wydawca:
Polskie Zrzeszenie Inżynierów i Techników Sanitarnych
Tematy:
osady ściekowe
toryfikacja
zgazowywanie
gaz syntezowy
tlen
dwutlenek węgla
siarkowodór
azot
sewage sludge
torrefaction
gasification
syngas
oxygen
carbon dioxide
hydrogen sulfide
nitrogen
Opis:
Jednym ze sposobów zagospodarowania osadów ściekowych może być ich zgazowywanie po wcześniejszej toryfikacji. W pracy przedstawiono wyniki symulacji procesu zgazowania karbonizatu uzyskanego podczas toryfikacji osadu ściekowego. Modelowanie procesu zgazowywania karbonizatu przeprowadzono w zakresie temperatury od 973 K do 1473 K, przy zastosowaniu powietrza jako czynnika zgazowującego. W każdej z temperatur przeprowadzono dziesięć symulacji, podczas których zmieniano wartość stosunku molowego tlenu do węgla (O/C). Uzyskane wyniki wykazały, że karbonizat otrzymany w procesie toryfikacji osadu ściekowego przez 60 min w temperaturze 533°K pozwolił na uzyskanie w temperaturze zgazowywania 973 K i przy stosunku molowym O/C=0,1 gazu syntezowego o największej wartości ciepła spalania (16,44 MJ/m3). Przeprowadzona analiza regresji wielokrotnej pozwoliła określić wpływ parametrów technologicznych (temperatura, stężenie czynnika zgazowującego) na uzyskane wartości ciepła spalania i wartości opałowej otrzymanego gazy syntezowego. Wykazano, że zmienną wpływającą w istotny sposób na proces zgazowania karbonizatu było stężenie czynnika zgazowującego, przy czym wraz z jego wzrostem następowało pogorszenie właściwości paliwowych gazu syntezowego. Parametrem technologicznym wpływającym nieistotnie na ten proces okazała się temperatura zgazowywania karbonizatu, ponieważ wraz z jej wzrostem nie odnotowano większych zmian w kaloryczności uzyskiwanego gazu syntezowego.
One of the methods of sewage sludge management may be its gasification with prior torrefaction. Simulation results of gasification of the carbonized sewage sludge obtained in the process of torrefaction were presented. Modeling of the carbonized sludge gasification process was performed in temperatures ranging from 973 K to 1473 K with air applied as a gasifying agent. Ten simulations were performed at each temperature, during which the molar ratio of oxygen to carbon (O/C) was varied. The results showed that the carbonized sludge obtained by torrefaction for 60 min at 533 K allowed for production of syngas with the highest heating value (16.44 MJ/m3) at gasification temperature of 973 K and the molar ratio O/C=0.1. Multiple regression analysis allowed for determination of statistical significance of technological parameters (temperature, concentration of gasifying agent) on both the lower heating value (LHV) and the higher heating value (HHV) of syngas produced. The obtained results demonstrated that a variable that significantly influenced the gasification process was the gasification agent concentration. With its increase, the fuel properties of syngas deteriorated. There were no more significant changes in calorific value of the obtained syngas with the increase in temperature, therefore temperature was the technological parameter considered to affect the process in a less significant manner.
Źródło:
Ochrona Środowiska; 2018, 40, 1; 45-50
1230-6169
Pojawia się w:
Ochrona Środowiska
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Processes regulating pCO2 in the surface waters of the Central Eastern Gotland Sea: a model study
Autorzy:
Kuznetsov, I.
Neumann, T.
Schneider, B.
Yakushev, E.
Powiązania:
https://bibliotekanauki.pl/articles/48971.pdf
Data publikacji:
2011
Wydawca:
Polska Akademia Nauk. Instytut Oceanologii PAN
Tematy:
Baltic Sea
biogeochemical modelling
brackish water
carbon dioxide
Cyanoprokaryota
detritus
ecological status
ecosystem
ERGOM model
nitrogen fixation
seasonal change
surface water
water exchange
Opis:
This work presents a one-dimensional simulation of the seasonal changes in CO2 partial pressure (pCO2). The results of the model were constrained using data from observations, which improved the model’s ability to estimate nitrogen fixation in the central Baltic Sea and allowed the impact of nitrogen fixation on the ecological state of the Baltic Sea to be studied. The model used here is the public domain water-column model GOTM (General Ocean Turbulence Model), which in this study was coupled with a modifed Baltic Sea ecosystem model, ERGOM (The Baltic Sea Research Institute’s ecosystem model). To estimate nitrogen fixation rates in the Gotland Sea, the ERGOM model was modified by including an additional cyanobacteria group able to fix nitrogen from March to June. Furthermore, the model was extended by a simple CO2 cycle. Variable C:P and N:P ratios, controlled by phosphate concentrations in ambient water, were used to represent cyanobacteria, detritus and sediment detritus. This approach improved the model’s ability to reproduce sea-surface phosphate and pCO2 dynamics. The resulting nitrogen fixation rates in 2005 for the two simulations, with and without the additional cyanobacteria group, were 259 and 278 mmol N m−2 year−1 respectively.
Źródło:
Oceanologia; 2011, 53, 3
0078-3234
Pojawia się w:
Oceanologia
Dostawca treści:
Biblioteka Nauki
Artykuł
Wyświetlanie 1-15 z 17

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