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Wyszukujesz frazę "poly(caprolactone)" wg kryterium: Temat


Wyświetlanie 1-2 z 2
Tytuł:
New homogeneous blends of dibutyrylchitin and aliphatic polyesters
Autorzy:
Sobecki, Paweł P.
Pabin-Szafko, Barbara
Powiązania:
https://bibliotekanauki.pl/articles/1035501.pdf
Data publikacji:
2010
Wydawca:
Sieć Badawcza Łukasiewicz - Polskie Towarzystwo Chitynowe
Tematy:
biodegradable polyester
blends
dibutyrylchitin
poly(ε-caprolactone)
polylactide
Opis:
The results of physical modification of dibutyrylchitin (DBCH) for the purpose of improvement of its imperfect mechanical properties are presented. Thus, the novel blends of DBCH and biodegradable aliphatic copolymer derived from ε-caprolactone, L-lactide and glycolide (PCLG) in various proportions were prepared and examined. DBCH/PCLG blends with PCLG contents between 6 - 50 wt% were successfully prepared in film form with the thickness in the range of 10 - 500 μm. The morphology of these blend films was studied by means of differential scanning calorimetry and infrared spectroscopy. DBCH was found to be able to form miscible blends with PCLG polyester within the whole composition range studied; revealed that blends were composed of an amorphous homogeneous phase as evidenced by the presence of a single glass transition temperature, that to decrease with increasing PCLG content in materials. Furthermore, physical modification of DBCH with polyester resulted in superior mechanical properties – the blended materials exhibited a much higher toughness and elongation at break as well as a lower value of elasticity modulus.
Źródło:
Progress on Chemistry and Application of Chitin and its Derivatives; 2010, 15; 47-54
1896-5644
Pojawia się w:
Progress on Chemistry and Application of Chitin and its Derivatives
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Physicochemical characteristics of chitin-polyester systems in dependence on their composition
Autorzy:
Sobecki, Paweł P.
Pabin-Szafko, Barbara
Szumilewicz, Joanna
Powiązania:
https://bibliotekanauki.pl/articles/1035429.pdf
Data publikacji:
2011
Wydawca:
Sieć Badawcza Łukasiewicz - Polskie Towarzystwo Chitynowe
Tematy:
biodegradable
blends
dibutyrylchitin
poly(ε-caprolactone)
polyesters
polylactide
Opis:
In order to improve the properties of their individual components, the compositions of dibutyrylchitin (DBC) and aliphatic polyesters (PCLG) were prepared and examined. The studied systems are homogeneous in a wide range of composition and molar masses of their components. The homogeneities of the blends made it possible to form smooth and transparent films, which were investigated by mechanical testing. It was found that the chemical structure and molar mass of a polyester component had an effect on mechanical properties of the systems. The films were subjected to hydrolytic degradation in media of various pH values (4.0, 7.4 and 13.0) at 37 °C. Furthermore, it was found that the molar mass and composition of the PCLG component clearly affected the rate of hydrolysis of the studied systems. The effect of hydrophilicity of the DBC/PCLG blends on degradation rate was also investigated. Consequently, by an appropriate choice of the components it is possible to control the profile of hydrolytic degradation of the DBC/PCLG systems.
Źródło:
Progress on Chemistry and Application of Chitin and its Derivatives; 2011, 16; 23-30
1896-5644
Pojawia się w:
Progress on Chemistry and Application of Chitin and its Derivatives
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-2 z 2

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