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    Wyświetlanie 1-5 z 5
    Tytuł:
    Geochemical interpretation and comparison of biomarker composition of bitumens obtained from coals and surrounding rocks
    Autorzy:
    Matuszewska, A.
    Powiązania:
    https://bibliotekanauki.pl/articles/1204922.pdf
    Data publikacji:
    2002
    Wydawca:
    Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
    Tematy:
    coal
    coal shales
    bitumens
    biomarkers
    GC-MS
    thermal maturity
    Opis:
    The bitumens obtained as the extraction products from a series of coals and surrounding rocks samples were fractionated onto aliphatic, aromatic and polar fractions. Aliphatic and aromatic fractions were then submitted to analysis using modern gas chromatography - mass spectrometry method. The distribution of n-alkanes was compared and parameters values characterising conditions of sedimentation and type of primary organic matter were calculated. In aliphatic fractions, a series of biomarkers was also identified as steranes, diasteranes, tricyclic diterpanes, hopanes and moretanes. The relatively high content of diasteranes was observed in the bitumens from shales bordering on coals. It confirms the literature data indicating possibility of catalytic influence of claystones on arrangement of steranes to diasteranes. The values of parameters calculated from the data characterising distribution of hopanes have indicated a possibility of generation of oils by some of analysed coals: flame as well as orthocoking coals.The aromatic compounds were also identified, mainly phenanthrenes being an important stage of aromatisation process of fossil organic matter.The comparison of characteristics of bitumens obtained from coals and surrounding rocks suggests a possibility of migration of various groups of organic compounds from coal layers to rocks bordering on them. The migration of organic mobile matter seems to be as well a result of a great difference of concentration between coal and surrounding rocks layers as of action of circulating waters or hydrothermal solutions. The temperature gradient and local intrusive bodies are of great significance for processes of oil migration. The examinations and conclusions presented in this work should be, however, taken as the introductory ones and have to be confirmed by analysis of a greater number of samples of various geological characteristics.
    Źródło:
    Polish Geological Institute Special Papers; 2002, 7; 169-180
    1507-9791
    Pojawia się w:
    Polish Geological Institute Special Papers
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Thermal maturity and depositional environments of organic matter in the post-Variscan succession of the Holy Cross Mountains
    Autorzy:
    Marynowski, L.
    Salamon, R.
    Narkiewicz, M.
    Powiązania:
    https://bibliotekanauki.pl/articles/2059919.pdf
    Data publikacji:
    2002
    Wydawca:
    Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
    Tematy:
    Holy Cross Mountains
    Permian
    Triassic
    biomarkers
    depositional environment
    thermal maturity
    Opis:
    The results of GC-MS investigations of biomarkers in organic matter from the epicontinental Permian and Triassic strata of the Holy Cross Mts. indicate generally suboxic (Permian) and oxic (Triassic, except for the Middle Muschelkalk) depositional environments with accompanying intensive bacterial reworking of organic remains. The biomarker spectra found in the Middle Muschelkalk and in the Entolium discites Beds (Upper Muschelkalk) show the presence of gammacerane, an increased concentration of C34 homohopanes and a Pr/Ph ratio not exceeding 1. All these observations suggest a hypersaline sedimentary environment with water column stratification and poorly oxygenated conditions. Thermal maturity investigations were based on both vitrinite reflectance and biomarker indices. The organic matter in the Triassic succession is slightly more mature along the northern margin of the Holy Cross Mts. than along their southern part, due probably to a regional increase in the maximum burial depth during the Mesozoic. The maturity of the Permian strata at Gałęzice (southern Holy Cross Mts.) is similar to that of the Triassic rocks whereas Kajetanów (in the north) is characterised by values significantly higher and comparable to those found in wells further north. The difference cannot be accounted for solely by differential burial depths, and implies the existence of a positive thermal anomaly active before the Middle Triassic. Our investigations generally confirmed the low thermal maturity of the Triassic. However, contrary to earlier interpretations, we suggest that the maximum burial depths based on a reconstructed thickness of the post-Triassic deposits may account for the observed maturity levels, assuming that geothermal gradients in the Mesozoic were similar to today's.
    Źródło:
    Geological Quarterly; 2002, 46, 1; 25-36
    1641-7291
    Pojawia się w:
    Geological Quarterly
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Comparative petrography and organic geochemistry of different types of organic matter occurring in the Outer Carpathians rocks
    Autorzy:
    Zielińska, Magdalena
    Fabiańska, Monika
    Więcław, Dariusz
    Misz-Kennan, Magdalena
    Powiązania:
    https://bibliotekanauki.pl/articles/2058565.pdf
    Data publikacji:
    2020
    Wydawca:
    Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
    Tematy:
    Polish Outer Carpathians
    redeposited organic matter
    organic matter petrography
    thermal maturity
    biomarkers
    Rock-Eval
    Opis:
    The characterization of organic matter (OM) in sedimentary rocks is important in many types of biological, geological and environmental research. The integrated use of microscopy and geochemistry, as here, is particularly useful in any attempt to define the origin and evolution of OM in sedimentary basins. The organic petrography and geochemistry different types of allogenic and authigenic OM from the Polish Outer Carpathian (POC) rocks were studied in present study to compare their genetic type, thermal maturity, depositional environment and post-sedimentation processes. Special attention was paid to redeposited coal clasts occurrences. The used techniques show differences in organic matter type originating from various sources. The organic petrography analysis shows that redeposited coal clasts (CC) and terrigenous organic matter (TOM) are composed predominantly of woody material (the gas-prone Type-III kerogen). Similar results were obtained during the Rock-Eval pyrolysis. Moreover, the GC-MS analysis of extracts indicated the additional source of OM, namely planktonic organic matter (POM) with oil-prone kerogen Type-I or II. This OM is in some cases high thermally mature and could potentially has allochthonous origin. The n-alkane, saturated and aromatic biomarker data revealed deposition of this POM in anoxic deltaic or close-shore sedimentary environments whereas the redeposited coal clasts were probably originally deposited in coal swamps as were the Upper Silesian bituminous coals.
    Źródło:
    Geological Quarterly; 2020, 64, 1; 165--184
    1641-7291
    Pojawia się w:
    Geological Quarterly
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Biomarkery, Tmax oraz refleksyjność witrynitu jako wskaźniki dojrzałości termicznej materii organicznej w skałach osadowych – korelacje i zakres stosowalności
    Biomarkers, Tmax and vitrinite reflectance as organic matter thermal maturity indices in sedimentary rocks – correlations and scope of applicability
    Autorzy:
    Bieleń, W.
    Matyasik, I.
    Powiązania:
    https://bibliotekanauki.pl/articles/1835259.pdf
    Data publikacji:
    2018
    Wydawca:
    Instytut Nafty i Gazu - Państwowy Instytut Badawczy
    Tematy:
    dojrzałość termiczna
    materia organiczna
    refleksyjność witrynitu
    biomarkery
    thermal maturity
    organic matter
    vitrinite reflectance
    biomarkers
    Opis:
    Niniejsza praca przedstawia zależności między różnymi wskaźnikami określającymi stopień dojrzałości termicznej materii organicznej. W badaniach wykorzystano pomiar refleksyjności witrynitu (Ro), pomiar Tmax z analizy Rock-Eval, molekularne wskaźniki dojrzałości otrzymane z analizy GC-MS frakcji nasyconej i aromatycznej ekstrahowanej substancji organicznej. Wzięto pod uwagę próbki zawierające witrynit, a także takie, które w składzie (głównie próbki dolnopaleozoiczne) zawierały macerały witrynitopo- dobne lub bituminit. Wykonano analizę korelacyjną między wskaźnikami stopnia dojrzałości dla próbek fliszu karpackiego oraz próbek reprezentujących utwory syluru i ordowiku oraz kambru górnego. Wyniki tych badań przedstawiono w postaci diagramów korelacyjnych oraz tabel korelacyjnych z obliczonymi współczynnikami korelacji.
    This study was aimed to determine the relationship between the various thermal indices determining the degree of organic matter maturity. In the correlation studies, vitrinite reflectance Ro, Tmax parameter from Rock-Eval analysis and indicators calculated obtained from the from the GCMS analysis data of aromatic and saturated fractions were used. For these studies samples containing macerals of vitrinite as well as samples containing vitrinite-like macerals in their composition were taken into account. An analysis of the relationship between indicators of the degree of maturity for samples representing: flysch Carpathian and for Silurian, Ordovician and Cambrian rocks was done. The results of these studies are presented in the form of correlation diagrams and tables with calculated correlation coefficients.
    Źródło:
    Nafta-Gaz; 2018, 74, 8; 575-583
    0867-8871
    Pojawia się w:
    Nafta-Gaz
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Dystrybucja biomarkerów i dojrzałość termiczna materii organicznej w tonsteinie i węglu kamiennym z pokładu 385/2 z kopalni Bogdanka (Lubelskie Zagłębie Węglowe)
    Biomarkers distribution and thermal maturity of organic matter w tonsteinie i węglu kamiennym z pokładu 385/2 z kopalni Bogdanka "Bogdanka" mine (Lublin Coal Basin)
    Autorzy:
    Gola, M. R.
    Karger, M.
    Gazda, L.
    Powiązania:
    https://bibliotekanauki.pl/articles/2074840.pdf
    Data publikacji:
    2011
    Wydawca:
    Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
    Tematy:
    Lubelskie Zagłębie Węglowe
    tonstein
    biomarkery
    dojrzałość termiczna materii organicznej
    Lublin Coal Basin
    biomarkers
    thermal maturity of organic matter
    Opis:
    The paper presents results of geochemical analyses of organic matter (OM) in a tonstein bed and surrounding bituminous coal from the Upper Carboniferous (Westphalian B) coal seam no. 385/2 from the Bogdanka mine, Lublin Coal Basin. In all studied samples, including those of tonstein and bituminous coal, OM was found to be very similar in composition. Distribution of hydrocarbons in investigated rocks is characterized by strong predominance with odd-number carbon-atom of the long-chain n-alkanes in comparison to the even-number and high concentration of C29 steranes, what implies relatively high input of higher-plant OM in these samples. Minor concentration of C28 steranes and perylene points at presence of fungi. In all extracts, the tri- and tetracyclic diterpanes co-occur with their aromatized derivatives, what suggests presence of the tap resin species - precursors of the conifer families in the plant community. The abundance of sesquiterpanes, pentacyclic triterpanes and benzohopanes indicates a significant bacterial input, most possibly connected with bacterial activity after deposition of terrestrial OM. The original material of tonstein was pyroclastic in orgin, and deposited directly on plants living at the surface of a mire. That material hadn’t had any direct influence on chemicalOMtransformation. The biomarker data, both for coals and tonstein, reveals that sedimentary organic matter was heated up to a temperature corresponding to the level of immature/start of oil window. On the other hand, the increase in thermal maturity value, based on distribution of the aromatic hydrocarbons in organic matter in tonstein (theoretical vitrinite values - Rc, Rcs) are probably due to the presence of incompletely burned organic remains (charcoals), transported to the sedimentary basin along with volcanic ashes.
    Źródło:
    Przegląd Geologiczny; 2011, 59, 12; 777-784
    0033-2151
    Pojawia się w:
    Przegląd Geologiczny
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
      Wyświetlanie 1-5 z 5

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