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    Wyświetlanie 1-2 z 2
    Tytuł:
    Study on Halide Ions Selectivity of Nuclear Grade Anion Exchange Resin Auchlite ARA-9366
    Autorzy:
    Singare, P. U.
    Patange, A. N.
    Powiązania:
    https://bibliotekanauki.pl/articles/412305.pdf
    Data publikacji:
    2014
    Wydawca:
    Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
    Tematy:
    selectivity
    ion exchange reactions
    halide ions
    nuclear grade resins
    anion exchange resins
    enthalpy
    equilibrium constant
    Auchlite ARA-9366
    Opis:
    The selectivity behaviour of nuclear grade anion exchange resin Auchlite ARA-9366 in chloride form towards iodide and bromide ions in the solution was studied. The trend in selectivity of the resin was predicted on the basis of thermodynamics of Clˉ/Iˉ and Clˉ/Brˉ uni-univalent ion exchange reactions. It was observed that the equilibrium constants K values for Clˉ/Iˉ ion exchange reaction were higher than that calculated for Clˉ/Brˉ exchange under identical experimental conditions. Also the enthalpy values for the two uni-univalent ion exchange reactions were calculated as -47.87 and -36.14 kJ/mol respectively. The high K and low enthalpy values obtained for Clˉ/Iˉ ion exchange reaction as compared to that obtained during Clˉ/Brˉ exchange supports higher selectivity of the resin towards iodide ions as compared to that towards bromide ions, when both the ions are present in the same solution.
    Źródło:
    International Letters of Chemistry, Physics and Astronomy; 2014, 11, 1; 67-73
    2299-3843
    Pojawia się w:
    International Letters of Chemistry, Physics and Astronomy
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Non Destructive Application of Radioactive Tracer Isotopes for Performance Evaluation of Industrial Grade Anion Exchange Resins Tulsion A-33 and Indion NSSR
    Autorzy:
    Singare, P. U.
    Powiązania:
    https://bibliotekanauki.pl/articles/411857.pdf
    Data publikacji:
    2013
    Wydawca:
    Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
    Tematy:
    radioisotopes
    non-destructive technique
    Tulsion A-33
    Indion NSSR
    nuclear grade resin
    anion exchange resins
    performance evaluation
    operational parameters
    131I
    82Br
    Opis:
    The present study deals with non-destructive application of radioactive tracer isotopes to evaluate the performance of Tulsion A-33 (nuclear grade) and Indion NSSR (non-nuclear grade) anion exchange resins. The performance evaluation was done by carrying out the iodide and bromide ion-isotopic exchange reactions using the above resins. It was observed that at a constant temperature of 40.0 °C, as the concentration of labeled iodide ion solution increases 0.001 M to 0.004 M, the percentage of iodide ions exchanged increases from 58.0 % to 64.0 % for Tulsion A-33 resins; and from 48.4 % to 50.8 % for Indion NSSR resins. Similarly in case of bromide ion-isotopic exchange reaction under identical experimental conditions, the percentage of bromide ions exchanged increases from 45.6 % to 50.4 % for Tulsion A-33 resin; and from 39.8 % to 44.6 % for Indion NSSR resin. It was also observed that during iodide ion-isotopic exchange reaction at 40.0 °C, using 1.000 g of ion exchange resins and 0.003 M labeled ionic solution, using Tulsion A-33 resin the values of specific reaction rate (min-1), amount of iodide ion exchanged (mmol), initial rate of iodide ion exchange (mmol/min) and log Kd were 0.229, 0.469, 0.107 and 10.6 respectively, which was higher than the values of 0.167, 0.375, 0.063 and 7.6 respectively as obtained by using Indion NSSR resins under identical experimental conditions. The overall results indicate superior performance of Tulsion A-33 over Indion NSSR resin under identical operational parameters.
    Źródło:
    International Letters of Chemistry, Physics and Astronomy; 2013, 13; 50-62
    2299-3843
    Pojawia się w:
    International Letters of Chemistry, Physics and Astronomy
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
      Wyświetlanie 1-2 z 2

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