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Wyszukujesz frazę "adsorption dynamics" wg kryterium: Temat

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    Wyświetlanie 1-3 z 3
    Tytuł:
    Adsorption with chemical reaction in porous catalyst pellets under alternate concentration fields. Uniform temperature case
    Autorzy:
    Bizon, K.
    Tabiś, B.
    Powiązania:
    https://bibliotekanauki.pl/articles/185479.pdf
    Data publikacji:
    2016
    Wydawca:
    Polska Akademia Nauk. Czytelnia Czasopism PAN
    Tematy:
    catalyst pellets
    reaction
    diffusion
    adsorption
    dynamics
    peleta katalityczna
    reakcja
    dyfuzja
    adsorpcja
    dynamika
    Opis:
    The work concerns the dynamic behaviour of a porous, isothermal catalyst pellet in which a simultaneous chemical reaction, diffusion and adsorption take place. The impact of the reactant adsorption onto the pellet dynamics was evaluated. A linear isotherm and a non-linear Freundlich isotherm were considered. Responses of the pellet to sinusoidal variations of the reactant concentration in a bulk gas were examined. It was demonstrated that the dynamics of the pellet is significantly affected both by accounting for the adsorption and by the frequency of the bulk concentration variations. The sorption phenomenon causes damping of the concentration oscillations inside the pellet and damping of its effectiveness factor oscillations. Depending on the frequency of the concentration oscillations in the bulk, the remarkable oscillations can involve an entire volume of the pellet or its portion in the vicinity of the external surface.
    Źródło:
    Chemical and Process Engineering; 2016, 37, 4; 473-484
    0208-6425
    2300-1925
    Pojawia się w:
    Chemical and Process Engineering
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Zinc ion adsorption on carbon nanotubes in an aqueous solution
    Autorzy:
    Ansari, A.
    Mehrabian, M. A.
    Hashemipour, H.
    Powiązania:
    https://bibliotekanauki.pl/articles/779155.pdf
    Data publikacji:
    2012
    Wydawca:
    Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
    Tematy:
    adsorption
    molecular dynamics simulation
    heavy metals
    electrostatic force
    interaction energy
    functional groups
    Opis:
    The literature devoted to numerical investigation of adsorption of heavy metal ions on carbon nanotubes is scarce. In this paper molecular dynamics is used to simulate the adsorption process and to investigate the effect of the infl uencing parameters on the rate of adsorption. The predictions of the molecular dynamics simulation show that the adsorption process is improved with increasing the temperature, pH of solution, the mass of nanotubes, and surface modifi cation of CNT using hydroxyl and carboxyl functional groups. The results predicted by the model are compared with the experimental results available in the literature; the close agreement validates the accuracy of the predictions. This study reveals that the water layers around the carbon nanotubes and the interaction energies play important roles in the adsorption process. The study also shows that electrostatic force controls the attraction of zinc ions on the nanotube sidewall.
    Źródło:
    Polish Journal of Chemical Technology; 2012, 14, 3; 29-37
    1509-8117
    1899-4741
    Pojawia się w:
    Polish Journal of Chemical Technology
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Effect of the oxygen-containing functional group on the adsorption of hydrocarbon oily collectors on coal surfaces
    Autorzy:
    Wan, He
    Hu, Xianglin
    Luukkanen, Saija
    Qu, Juanping
    Zhang, Chonghui
    Xue, Jiwei
    Li, Hui
    Yang, Wei
    Yang, Shenghong
    Bu, Xianzhong
    Powiązania:
    https://bibliotekanauki.pl/articles/2146920.pdf
    Data publikacji:
    2022
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    oxygen-containing functional groups
    hydrocarbon oily collectors
    molecular dynamics simulation
    coal surfaces
    adsorption
    Opis:
    The oxygen-containing functional groups (OCFG) on the coal surface affect the adsorption effect of hydrocarbon oily collectors (HOC). An investigation of the interaction between the HOC and OCFG in the absence and presence of water is conducive to understanding the effect of OCFG type on the adsorption of HOC on the coal surface. In this paper, FTIR analysis was used to analyze the OCFG type of coal surface. The adsorption behavior of HOC on different OCFG surfaces was investigated using molecular dynamics simulation. The results indicated the presence of OCFG such as -OH, -COOH, -C=O, and -COCH3 on the coal surface. In conditions without water, the effect of OCFG on HOC adsorption capability follows the order -COOH > -C=O > -OH > -COCH3. In an aqueous solution, the effect of OCFG on HOC adsorption capability follows the order -C=O>-COCH3>-OH>-COOH. Moreover, the hydrophilicity of OCFG is the key factor that affects the adsorption effect of HOC. In other words, the adsorption effect of HOC on the coal surface in an aqueous solution does not depend on the strength of the interaction between the OCFG and HOC in the absence of water, but on the hydrophilicity of the OCFG. The -COOH and -OH on the coal surface are not conducive to the adsorption of HOC onto the coal surface. Masking the -COOH and -OH of the coal surface is beneficial in improving the coal flotation performance with HOC as a collector.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2022, 58, 4; art. no. 149937
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
      Wyświetlanie 1-3 z 3

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