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Wyświetlanie 1-4 z 4
Tytuł:
Effective Removal of Iron (II) from Aqueous Solution by Adsorption using Zn/Cr Layered Double Hydroxides Intercalated with Keggin Ion
Autorzy:
Oktriyanti, Melantina
Palapa, Neza Rahayu
Mohadi, Risfidian
Lesbani, Aldes
Powiązania:
https://bibliotekanauki.pl/articles/125462.pdf
Data publikacji:
2020
Wydawca:
Polskie Towarzystwo Inżynierii Ekologicznej
Tematy:
adsorption
iron(II)
desorption
zinc
chromium
layered double hydroxide
Opis:
Zn/Cr and Zn/Cr layered double hydroxides (LDHs) intercalated with Keggin ion [α-SiW12O40]4-were successfully synthesized at room temperature and pH value of 10. The synthesized materials were characterized by means of the XRD, BET, and FT-IR analyses and used as an adsorbent iron(II). The adsorption process was investigated by studying pH, the kinetics, and thermodynamic properties of the adsorption process. The results showed the interlayer Zn/Cr LDHs was 7.53 Å and increase to 10.26 Å on Zn/Cr LDHs intercalated with Keggin ion [α-SiW12O40]4-. The BET analysis showed that the pore volume of both materials increased from 0.063 cm3 g-1 to 0.163 cm3 g-1. The pH point zero charge measurement for the Zn/Cr LDHs material was 10 while LDHs Zn/Cr intercalated with Keggin ion [α-SiW12O40]4- was 8. Zn/Cr LDHs intercalated with Keggin ion [α-SiW12O40]4- has higher adsorption capacity than Zn/Cr LDHs without intercalation. Desorption of iron (III) was successfully conducted using HCl as reagent showing the involvement of ion exchange in the adsorption.
Źródło:
Journal of Ecological Engineering; 2020, 21, 5; 63-71
2299-8993
Pojawia się w:
Journal of Ecological Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Soft Ion Divalent Metals toward Adsorption on Zn/Al-POM Layered Double Hydroxide
Autorzy:
Silaen, Luna
Elfita, -
Mohadi, Risfidian
Normah, -
Juleanti, Novie
Palapa, Neza Rahayu
Lesbani, Aldes
Powiązania:
https://bibliotekanauki.pl/articles/2027762.pdf
Data publikacji:
2021
Wydawca:
Polskie Towarzystwo Inżynierii Ekologicznej
Tematy:
soft divalent metal ions
adsorption
polyoxometalate
regeneration
Opis:
Development of Zn/Al layered double hydroxide by intercalation using polyoxometalate (POM) $K_4 [α-SiW_12O_40]$ to Zn/Al-POM was investigated. The success of the modification is evidenced by the XRD, FT-IR, and BET characterization data. XRD characterization showed an increase in the interlayer distance from 8.59 Å in Zn/Al LDHs to 10.26 Å in Zn/Al-POM. This success is also supported by the FT-IR data with the appearance of vibrations around $779–979 cm^{-1}$ which indicates the vibration of the polyoxometalate compound in Zn/Al-POM. Other supporting data in the form of BET also prove an increase in surface area from 1.968 $m^2$/g in Zn/Al LDHs to 14.042 $m^2$/g Zn/Al-POM. The ability of Zn/Al-POM as an adsorbent is proven through several parameters such as kinetics, isotherm, thermodynamics, and regeneration for $Cd^{2+}$, $Pb^{2+}$, $Ni^{2+}$, and $Co^{2+}$. Adsorption kinetics showed that Zn/Al-POM was more likely to follow the pseudo-second-order adsorption kinetics model for $Cd^{2+}$, $Pb^{2+}$, $Ni^{2+}$, and $Co^{2+}$. The results of determining the adsorption isotherm parameters of Zn/Al-POM tend to follow the Freundlich isotherm model with a maximum adsorption capacity of 74.13 mg/g on $Pb^{2+}$. The regeneration process showed that Zn/Al-POM was more resistant than Zn/Al LDHs up to 3 cycles. It was proven that Zn/Al-POM was able to survive in the last cycle up to 69.19% on $Ni^{2+}$.
Źródło:
Journal of Ecological Engineering; 2021, 22, 10; 109-120
2299-8993
Pojawia się w:
Journal of Ecological Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Improving the Performance of Mg/Cr LDH by Forming Metal Oxides Mg/Cr-Ni Using Coprecipitation Method as Adsorbent for Cationic Dyes
Autorzy:
Yuliasari, Nova
Badri, Arini Fousty
Siregar, Patimah Mega Syah Bahar Nur
Palapa, Neza Rahayu
Mardiyanto
Mohadi, Risfidian
Lesbani, Aldes
Powiązania:
https://bibliotekanauki.pl/articles/2105268.pdf
Data publikacji:
2022
Wydawca:
Polskie Towarzystwo Inżynierii Ekologicznej
Tematy:
adsorption
metal oxide
rhodamine B
methylene blue
regeneration
Opis:
This study aimed to determine the adsorption capacity of rhodamine-B (Rh-B) and methylene blue (MB) on Mg/Cr-Ni adsorbents. The Mg/Cr-Ni adsorbent was synthesized by the coprecipitation method. The results of the characterization of Mg/Cr-Ni using XRD analysis showed the formation of oxides at an angle of 2θ = 31.726°, 33°, and 45.44°. The surface area of Mg/Cr-Ni is 23.139 m2/g. The adsorption capacity test for Mg/Cr-Ni for Rh-B and MB were 85.470 mg/g and 166.667 mg/g, respectively. The adsorption kinetics model followed the pseudo second order (PSO). The adsorption process is endothermic and occurs spontaneously at any temperature. Mg/CrNi showed stability in the adsorption process of Rh-B and MB for 5 regeneration cycles.
Źródło:
Journal of Ecological Engineering; 2022, 23, 6; 67--74
2299-8993
Pojawia się w:
Journal of Ecological Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
High Structural Stability and Adsorption Capacity of Zn/Al-Biochar and Cu/Al-Biochar Toward Adsorption of Cr(VI)
Autorzy:
Palapa, Neza Rahayu
Taher, Tarmizi
Siregar, Patimah Mega Syah Bahar Nur
Normah, -
Juleanti, Novie
Wijaya, Alfan
Badri, Arini Fousty
Lesbani, Aldes
Powiązania:
https://bibliotekanauki.pl/articles/1839586.pdf
Data publikacji:
2021
Wydawca:
Polskie Towarzystwo Inżynierii Ekologicznej
Tematy:
layered double hydroxide
chromium
adsorption
reusability
Opis:
Layered double hydroxide (LDH) Zn/Al and Cu/Al was synthesized by using the coprecipitation method under base condition at pH 10 following with formation of composites based on biochar (BC) to form Zn/Al-BC and Cu/ Al-BC. The materials were characterized by XRD, FTIR, BET, and thermal analyses. Furthermore, materials was applied as adsorbent of Cr(VI) on aqueous solution. The performance of composites as adsorbent was evaluated by reusability of adsorbent toward Cr(VI) adsorption process. The results showed that Cu/Al-BC and Zn/Al-BC can reuse the re-adsorption process with the adsorption ability of more than 60%. The adsorption capacity of Cu/ Al-BC and Zn/Al-BC was higher than that of starting materials and up to 384.615 mg/g for Cu/Al-BC and 666.667 mg/g for Zn/Al-BC. Both composites showed the potential adsorbents to remove Cr(VI) from aqueous solution.
Źródło:
Journal of Ecological Engineering; 2021, 22, 4; 213-223
2299-8993
Pojawia się w:
Journal of Ecological Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-4 z 4

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