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Wyszukujesz frazę "phosphate removal" wg kryterium: Wszystkie pola


Wyświetlanie 1-4 z 4
Tytuł:
Application of cross-linked chitosan for phosphate removal from aqueous solutions
Autorzy:
Filipkowska, Urszula
Jóźwiak, Tomasz
Szymczyk, Paula
Powiązania:
https://bibliotekanauki.pl/articles/1035181.pdf
Data publikacji:
2014
Wydawca:
Sieć Badawcza Łukasiewicz - Polskie Towarzystwo Chitynowe
Tematy:
adsorption
chitosan
cross-linked chitosan
epichlorohydrin
glutaraldehyde
phosphates
Opis:
This study investigated the effectiveness of phosphate adsorption onto non-cross-linked chitosan beads [CHs], and onto chitosan beads cross-linked with glutaraldehyde [ALD-CHs] and epichlorohydrin [ECH-CHs]. The weight ratio of glutaraldehyde to chitosan was 1:2 (w/w), whereas that of epichlorohydrin to chitosan was 2:1 (w/w). The optimal pH value of the phosphate adsorption process was determined at pH 3 for cross-linked chitosan and at pH 4 for noncross- linked chitosan. The time needed to reach the equilibrium concentration reached 60 min for both adsorbents. Experimental data were described with the heterogeneous Langmuir model (double Langmuir equation). The most effective adsorbent of phosphates was shown to be chitosan cross-linked with epichlorohydrin [ECH-CHs] - for which the adsorption capacity reached 139.4 mg/g d.m.CHs. In the case of the remaining adsorbents (chitosan [CHs] and chitosan crosslinked with glutaraldehyde [ALD-CHs]) the adsorption capacity was lower and accounted for 44.38 mg/g d.m.CHs and 108.24 mg/g d.m.CHs, respectively.
Źródło:
Progress on Chemistry and Application of Chitin and its Derivatives; 2014, 19; 5-14
1896-5644
Pojawia się w:
Progress on Chemistry and Application of Chitin and its Derivatives
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Phosphate removal from aqueous solutions by chitin and chitosan in flakes
Autorzy:
Szymczyk, Paula
Filipkowska, Urszula
Jóźwiak, Tomasz
Kuczajowska-Zadrożna, Małgorzata
Powiązania:
https://bibliotekanauki.pl/articles/1034690.pdf
Data publikacji:
2016
Wydawca:
Sieć Badawcza Łukasiewicz - Polskie Towarzystwo Chitynowe
Tematy:
adsorption
chitin
chitosan
phosphate
Opis:
The article presents the effectiveness of phosphate adsorption on the flakes of chitin and chitosan. Studies performed determined adsorption capacity of chitin and chitosan, best among the tested adsorption pH and the equilibrium time. Langmuir model was used to describe the results. The highest removal efficiency of phosphorus compounds using chitin was obtained at pH 3 and with chitosan at pH 4. The study of phosphate equilibrium concentration time obtained for both sorbents was carried out at three concentrations of 1, 5 and 10 mg/dm3. The highest sorption efficiency of the phosphate using chitin was achieved after 20 minutes of the process and at the chitosan after 40 minutes. In the case of chitosan after the equilibrium time the effect of partial P-PO4 release was observed, which could be related to the change in pH of the solution by the sorbent. Studies have shown that chitosan is a more effective absorbent for phosphorus compounds. The maximum adsorption capacity of chitosan with phosphate was 6.65 mg/g, and chitin - 2.09 mg/g.
Źródło:
Progress on Chemistry and Application of Chitin and its Derivatives; 2016, 21; 192-202
1896-5644
Pojawia się w:
Progress on Chemistry and Application of Chitin and its Derivatives
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effect of Magnetite Oxide Nanoparticles and Tungsten Oxide Nanoparticles on Phosphate Removal from Aqueous Solutions
Autorzy:
EL-Baz, Amro
Mokhtar, Mona
Abdo, Ahmed
Powiązania:
https://bibliotekanauki.pl/articles/24201790.pdf
Data publikacji:
2023
Wydawca:
Polskie Towarzystwo Inżynierii Ekologicznej
Tematy:
phosphate removal
nanoparticles
Fe3O4 NPs
WO3 NPs
adsorption
desorption
Opis:
Phosphate (P) removal from aqueous solutions were studied by a new mineral adsorbent, tungsten (VI) oxide (WO3) nanoparticles (NPs), which has not been the subject of much research in the field of removing P contaminants from agricultural wastewater. In this paper, P was removed from aqueous solutions by a new mineral adsorbent, WO3 NPs and it was compared with magnetite (iron IV) oxide (Fe3O4) nanoparticles (NPs) under the same ambient operating conditions i.e., The influence of the dosage of adsorbents, initial P concentration, contact time, pH and temperature. The values that achieved the best removal were recorded. It was concluded that the best limits for pH were at 2–3, contact time at 40 minutes, temperature at 45 °C and adsorbent dose at 1.0 g/L. Best results of the variables were applied on samples of real agricultural wastewater, which achieved removal ratio of 77.3% and 75.42% for Fe3O4 and WO3 NPs, respectively. SEM, EDX and FTIR images and analyses were conducted to describe the characteristics of nano-adsorbents used before and after P adsorption in aqueous solutions. The P adsorption kinetics for aqueous solutions were examined by fitting results of the experiment to both the first & second pseudo-kinetically models. The outcome indicated that kinematic data fit better with pseudo-second-order kinetic models. Moreover, the information captured from equilibrium adsorption was analyzed using isothermal methods (by Langmuir & Freundlich Forms). Their results showed that the Freundlich form is considered more suitable than Langmuir form in analyzing the biosorption of P ions. The thermodynamic demeanor of P adsorption by Fe3O4 and WO3 NPs was analyzed and evaluated, and the thermodynamic data analyses confirmed the process of P adsorption was spontaneous. The ΔG° value was negative, while ΔH° and ΔS° values found to be positive, which means that the adsorption of P was a spontaneous, random and endothermic operation. In general, Fe3O4 and WO3 nanoparticles had a high efficiency in removing phosphate from water. In addition, WO3 NPs has been identified as one of the most promising adsorbents due to its rapid and effective adsorption of pollutants.
Źródło:
Journal of Ecological Engineering; 2023, 24, 3; 287--303
2299-8993
Pojawia się w:
Journal of Ecological Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Preparation of sorbent with a high active sorption surface based on blast furnace slag for phosphate removal from wastewater
Autorzy:
Kostura, B.
Dvorsky, R.
Kukutschová, J.
Študentová, S.
Bednář, J.
Mančík, P.
Powiązania:
https://bibliotekanauki.pl/articles/207447.pdf
Data publikacji:
2017
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
blast furnace slag
aqueous solutions
phosphorus
silicate
adsorbents
adsorption
adsorpcja
fosfor
krzemiany
odpady ściekowe
żużel wielkopiecowy
Opis:
A new method has been presented, which leads to a significant improvement of the adsorption ability of blast furnace slag (BFS). An ultra-high pressure water jet mill cavitation disintegrator and a controlled vacuum freeze dryer were used to disintegrate amorphous BFS. Specific surface areas of both BFS and disintegrated slag (BFS-D) were measured using the SBET method. BFS-D was obtained with an average particle size of 198 nm and with 27-times bigger free specific surface area than that of original BFS. The BFS-D was tested as an adsorbent of phosphate from aqueous solutions. Adsorption data were analysed using the Freundlich and Langmuir adsorption isotherms. The BFS-D after phosphate adsorption was characterized using FTIR. The theoretical adsorption capacity of the BFS-D was 30.49 mg P/g, which represents an increase by 126.7% compared to the original BFS. Surface precipitation of hydroxyapatite was dominant retention mechanism.
Źródło:
Environment Protection Engineering; 2017, 43, 1; 161-168
0324-8828
Pojawia się w:
Environment Protection Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-4 z 4

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