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Tytuł:
Metal Detoxification in Nature and Its Translation into Functional Adsorbent Materials
Autorzy:
Permana, Rega
Ihsan, Yudi Nurul
Powiązania:
https://bibliotekanauki.pl/articles/1030803.pdf
Data publikacji:
2020
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
adsorbent
bioinspired
heavy metal
polyphenol
Opis:
Nature has a remarkable strategies to overcome the unfavoring environmental condition by producing a unique chemical compounds, including polyphenol. Polyphenol residues in many living organism have been documented to express numerous biological function ranging from antioxidant, mechanical reinforcement as well as metal anchoring substances. This gave us insight of how nature converts toxic metal compound and deposits it into a harmless form. This review will discuss some natural strategies of living organism to metabolize metal in a safe manner so that the metal no longer harmful to them. Example taken from aluminum accumulating plants, vanadium accumulating marine tunicate and iron-reinforced mussel byssus, which all three utilized phenol derivative compound to chelate the metal. Advances made by incorporating cutting edge characterization tools allowed us to understand the exact mechanism of metal chelation at the atomic level. A comprehensive discussion of molecular mechanism governing the complexion between the phenolic compound and metal will be beneficial for further study to fabricate functional materials, for example adsorbent, to remediate contaminated water. Translating these natural strategies into an engineered polyphenol based adsorbent materials will be prospective to be further applied as a remediation agent as it is easily found in nature, cost effective and highly efficient.
Źródło:
World Scientific News; 2020, 145; 144-155
2392-2192
Pojawia się w:
World Scientific News
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Fixed Bed System Packed with Porous Materials for Removal of Organic Dye from Wastewater
Autorzy:
Cho, Young-Sang
Sung, Sohyeon
Powiązania:
https://bibliotekanauki.pl/articles/2203706.pdf
Data publikacji:
2023
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
porous particles
photocatalyst
adsorbent
fixed bed
Opis:
Fixed beds were adopted for removal of organic dye from water by photocatalytic decomposition or adsorption. To this end, macroporous titania or silica micro-particles were synthesized from emulsions as micro-reactors and packed in the bed. During feeding aqueous methylene blue solution, UV light was irradiated for generation of active radicals for removal of dye by photocatalytic decomposition. Porous silica particles were also used as adsorbents in the bed for continuous adsorption of organic dye. For regeneration of the porous titania or silica particles, rinsing with fresh water was carried out before repeated cycles.
Źródło:
Archives of Metallurgy and Materials; 2023, 68, 1; 51--56
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Adsorbent Characterization from Cocoa Shell Pyrolysis (Theobroma cacao L) and its Application in Mercury Ion Reduction
Autorzy:
Nursiah, Cut
Desvita, Hera
Elviani, Elviani
Farida, Nurlia
Muslim, Abrar
Rosnelly, Cut Meurah
Mariana, Mariana
Suhendrayatna, Suhendrayatna
Powiązania:
https://bibliotekanauki.pl/articles/24202895.pdf
Data publikacji:
2023
Wydawca:
Polskie Towarzystwo Inżynierii Ekologicznej
Tematy:
characterisation
pyrolysis
adsorbent
cocoa shell
mercury ion
Opis:
In this paper, we describe the characterization and application of adsorbent derived from the pyrolysis of cocoa shells, which is a natural source of adsorbent materials. The adsorbent that was used in this experiment is an environmentally friendly adsorbent that was prepared by the pyrolysis of cocoa shells. For 1.5 hours, the pyrolysis process was carried out at temperatures ranging from 300 to 380 °C. The adsorbent was characterized by scanning electron microscopy (SEM), Fourier transform infrared (FTIR) spectroscopy, and analysis with an X-ray diffraction (XRD) analyzer. Water-ash content and iodine absorption capacity were also determined in accordance with SNI 06-3730-1995. At a contact time of 90 minutes, the adsorption capacity of mercury ions was found to be 0.106 mg/gram. In this study, the adsorption of mercury ions with the adsorbent followed pseudo-second-order models with an R2 value of 0.9929.
Źródło:
Journal of Ecological Engineering; 2023, 24, 6; 366--375
2299-8993
Pojawia się w:
Journal of Ecological Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Preparation of Environmentally Friendly Adsorbent Using Oil Palm Boiler Ash, Bentonite and Titanium Dioxide Nanocomposite Materials
Autorzy:
Bukit, Nurdin
Ginting, Eva Marlina
Frida, Erna
Bukit, Bunga Fisikanta
Powiązania:
https://bibliotekanauki.pl/articles/2202292.pdf
Data publikacji:
2022
Wydawca:
Polskie Towarzystwo Inżynierii Ekologicznej
Tematy:
adsorbent
nanocomposite
bentonite
TiO2
Boiler Ash
Opis:
Using the products derived from agricultural wastes as low-cost adsorbent materials to remove organic or inorganic contaminants would be ideal, as these materials are readily available in many countries. This study aimed to prepare environmentally friendly adsorbents made from nanocomposite OPBA / Bentonite / TiO2. The coprecipitation method was used in preparing OPBA, and CTAB surfactant was added in bentonite preparation. Meanwhile, the manufacture of TiO2 was carried out using the sol-gel method. Characterization was done by XRD, FTIR, SEM, and BET. The adsorbent spectra did not show a significant shift in absorption where the O-H bonds were becoming weaker due to the presence of TiO2 in the interlayer of bentonite. Another possibility is due to the influence of calcination and heating. The O-H groups of H2O are hydroxylated and dehydrated from within between layers. The formation of the composite OPBA/TiO2/Bentonite does not change the crystallinity of TiO2 significantly. This proves that there is no decrease in photocatalyst activity after the addition of OPBA and bentonite. The morphology of the whole sample has a flake-like structure that has pores. The addition of OPBA into Bentonite/TiO2 causes a decrease in the specific surface area of the sample.
Źródło:
Journal of Ecological Engineering; 2022, 23, 12; 75--82
2299-8993
Pojawia się w:
Journal of Ecological Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Adsorptive solar refrigerators based on composite adsorbents 'silica gel – sodium sulphate'
Autorzy:
Belyanovskaya, Elena A.
Pustovoy, Grigoriy N.
Sukhyy, Kostyntyn M.
Sergiyenko, Yana O.
Yeromin, Oleksandr O.
Prokopenko, Elena .
Gubinsky, Mikhailo V.
Kizek, Ján
Lukáč, Ladislav
Powiązania:
https://bibliotekanauki.pl/articles/396041.pdf
Data publikacji:
2019
Wydawca:
Uniwersytet Zielonogórski. Oficyna Wydawnicza
Tematy:
adsorptive refrigerator
composite adsorbent
coefficient of performance
adsorptive capacity
regeneration temperature
chłodziarka adsorpcyjna
adsorbent
współczynnik wydajności
zdolność adsorpcyjna
temperatura
Opis:
The operation processes of adsorptive solar refrigerators based on composite adsorbents ‘silica gel - sodium sulphate’ were studied. The correlation between the adsorbent composition and the coefficient of the energy performance of the device was stated. As a consequence of the decreasing of adsorbent mass, the coefficient of performance is increased when sodium sulphate content in the composite increased. Effect of the regeneration process parameters on the composite on the coefficient of performance of the adsorptive refrigenerator was stated. The growth of the coefficient of performance is shown to result from decreasing the difference between adsorbent temperature and regeneration temperature from 85 to 55°C. The maximum values of the coefficient of performance of studied solar adsorptive refrigenerator about of 1.14 are stated for composites containing about 20 wt. % silica gel and 80 wt. % sodium sulphate.
Źródło:
Civil and Environmental Engineering Reports; 2019, 29, 3; 200-208
2080-5187
2450-8594
Pojawia się w:
Civil and Environmental Engineering Reports
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Characterization of Spent Bleaching Earth as an Adsorbent Material for Dye Removal
Autorzy:
Yulikasari, Andriyan
Nurhayati, Ervin
Utama, Widya
Warmadewanthi, Idaa
Powiązania:
https://bibliotekanauki.pl/articles/2086386.pdf
Data publikacji:
2022
Wydawca:
Polskie Towarzystwo Inżynierii Ekologicznej
Tematy:
adsorbent
adsorption capacity
surface area
SBE
spent bleaching earth
Opis:
Initial research has been carried out to determine the potential of SBE as an adsorbent material through chemical and surface area characterization. Several analyses were performed, including oil content, BET, SEM-EDS, XRD, FTIR, and adsorption capacity. The oil content of the SBE samples were 0.05–0.09%, well below the standard (3%) of hazardous material classification according to the Indonesian government regulation. The chemical composition of SBE, measured by EDS, was dominated by Si and Al elements. XRD analysis revealed two 2-theta diffraction peaks indicated the presence of crystalline SiO2 and Al2O3 phases. Additionally, the results of the FTIR test also showed the dominance of Si-O and Al-O-H functional groups. The SBE morphology, as observed in SEM image, exhibited irregular shape and porous surface covered by impurities. These results supported by the BET data which showed SBE surface area of 10.86 m2g-1 and a mesopore volume of 2.49 cm3 (STP)g-1. Batch adsorption study conducted using low and high range concentration of methylene blue produced a maximum adsorption capacity of 7.993 mg/g and 40.485 mg/g, respectively. The adsorption isotherm analysis showed that the adsorption mechanism was in accordance with the Langmuir isotherm model. Considering its chemical characteristic, SBE has met the criteria for adsorbent material. Nevertheless, the small surface area requires SBE to be activated prior to use.
Źródło:
Journal of Ecological Engineering; 2022, 23, 4; 96--104
2299-8993
Pojawia się w:
Journal of Ecological Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Pulp and Paper Wastewater Treatment with Bottom Ash Using Jar Test
Autorzy:
Pisceselia, Dian F.
Arita, Susila
Agustina, Tuty Emilia
Powiązania:
https://bibliotekanauki.pl/articles/2202330.pdf
Data publikacji:
2023
Wydawca:
Polskie Towarzystwo Inżynierii Ekologicznej
Tematy:
adsorbent
pulp and paper wastewater
bottom ash
jar test
Opis:
The wastewater generated from pulp and paper production still contains pollutants and contaminants, so appropriate and economical materials are needed to reduce pollutants by using adsorbents from bottom ash. This study examined the characteristics of bottom ash and pulp and paper wastewater, the effect of stirring time, stirring speed, and adsorbent activation temperature on decreasing the environmental parameters of wastewater. The synthesis of bottom ash as an adsorbent was carried out by heating at 100 and 200 °C for 1 hour. The wastewater treatment process with maximum yield occurs at a stirring speed of 100 rpm for 50 min. The use of bottom ash without heating as an adsorbent in the pulp and paper wastewater treatment process has reduced TSS 77.5%, COD 85.72%, chloride 26.9%, TDS 1143 ppm, and EC 2180 s/cm, which have met the environmental quality standards.
Źródło:
Journal of Ecological Engineering; 2023, 24, 1; 188--194
2299-8993
Pojawia się w:
Journal of Ecological Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Powierzchniowe i strukturalne właściwości niemodyfikowanych i modyfikowanych żeli krzemionkowych
Surface and structural properties of unmodified and modified silica gels
Autorzy:
Choma, J.
Jaroniec, M.
Powiązania:
https://bibliotekanauki.pl/articles/237043.pdf
Data publikacji:
2000
Wydawca:
Polskie Zrzeszenie Inżynierów i Techników Sanitarnych
Tematy:
adsorpcja azotu
adsorbent
żele krzemionkowe
właściwości powierzchniowe
właściwości strukturalne
Opis:
Of the set of methods for the characterization of the surface and structural properties of unmodified and modified mesoporous silica gels (which is reviewed in the present paper), special consideration was given to the BET, [alfa]s-plot and Dollimore-Heal methods for the characterization of the adsorption process. For the needs of these characterization, use was made of the low-temperature (77 K) nitrogen adsorption isotherms on unmodified and octyl phase modified silica gel Nitrogen adsorption isotherms on unmodified and modified macroporous LiChrospherSi-1000 silica were used as the reference data. As shown by the results, an accurate characterization of nanoporous silica gels requires that the adsorption data be measured in the entire range of relative pressures. Another crucial problem is the selection of the reference solid because the resulting parameters of the porous structure depend on the reference adsorption isotherm used. The reference silica should display properties analogous to those of the silica studied.
Źródło:
Ochrona Środowiska; 2000, 2; 3-8
1230-6169
Pojawia się w:
Ochrona Środowiska
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
From waste to treat waste : exploitation of marble dust as a harmful pollutant to a green adsorbent for dyes and heavy metals from industrial wastewater
Autorzy:
Attia, H.A.
Farghaly, Mohamed G.
Saleh, A.M.
Abdel Khalek, M.A.
Powiązania:
https://bibliotekanauki.pl/articles/2175448.pdf
Data publikacji:
2022
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
marble dust
pollutant
adsorbent
dye
heavy metals
textile wastewater
Opis:
The marble dust as a harmful industrial waste of marble fabrication was evaluated as aneconomical and efficient green adsorbent for Acid Red-1 dye and lead ions. The XRD, XRF, particle size, surface area and zeta-potential measurements were used to characterize the marble dust. The removal efficiency was optimized by studying several parameters such as pH, temperature, contact time, adsorbent dose and initial concentration. The optimum removal was achieved at pH 6, 20°C after 60 min in the presence of 2.5g/L marble dust. The rates of adsorption were found to follow the pseudo-second-order model. The results showed better fitting to Freundlich isotherm. The thermodynamic studies revealed that the adsorption process is spontaneous, exothermic and favorable at low temperature. The free energy (∆G°), enthalpy (∆H°), and entropy (∆S°) changes were calculated to predict the nature of adsorption.The removal efficiency was improved by calcination of the marble at 700°C. Application for textilewastewater showed high removal efficiency up to 99.9%of inorganic and organic pollutants. The product of treatment was used in the concrete and bricks manufactured, so there is nogeneration of second-order pollutants.
Źródło:
Physicochemical Problems of Mineral Processing; 2022, 58, 6; art. no. 154007
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Bio-polishing sludge adsorbents for dye removal
Autorzy:
Zaini, M. A. A.
Norulaina, A.
Mohd Azizi, C. Y.
Powiązania:
https://bibliotekanauki.pl/articles/779794.pdf
Data publikacji:
2016
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
adsorption
adsorbent
bio-polishing sludge
methylene blue
chemical treatment
Opis:
The objective of this work is to evaluate the removal of methylene blue dye by bio-polishing sludge-based adsorbents. The adsorbents were characterized according to the specific surface area, pH upon the treatment and surface functional groups. The adsorption of dye was carried out at room temperature, and the adsorption data were analyzed using the isotherm and kinetics models. The bio-polishing sludge is rich in ash content, and the presence of surface functional groups varied with the treatment strategies. The specific surface area of adsorbents is between 7.25 and 20.8 m2 /g. Results show that the maximum removal of methylene blue by sludge adsorbents was observed to have the following order: untreated sludge (SR) > zinc chloride-treated (SZ) > microwave-dried (SW) = potassium carbonate-treated (SK) > acid-washed (SH). The maximum adsorption capacities for SR and SZ as predicted by the Langmuir model are 170 and 135 mg/g, respectively. Although SR demonstrates a higher maximum removal than SZ, the latter exhibits greater removal intensity and rate constant even at high dye concentration. The bio-polishing sludge is a promising adsorbent for dye wastewater treatment.
Źródło:
Polish Journal of Chemical Technology; 2016, 18, 4; 15-21
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The Needles of Aleppo Pine From the Province of Taza-Morocco – A Biomaterial of Great Potential
Autorzy:
Mahmoud, Rachid
Hjouji, Kaoutar
Mehdaoui, Imane
Saoudi Hassani, El Mokhtar
Ben Abbou, Mohamed
Majbar, Zineb
Taleb, Mustapha
Rais, Zakia
Powiązania:
https://bibliotekanauki.pl/articles/2202321.pdf
Data publikacji:
2023
Wydawca:
Polskie Towarzystwo Inżynierii Ekologicznej
Tematy:
Aleppo pine
pine needle
physicochemical characterization
spectroscopic characterization
adsorbent
biomaterial
essential oil
Opis:
The needles of the Aleppo pine (Pinus halepensis) (PA) are very abundant in the forest of the National Park of Tazekka (Ta-za-Morocco) and are unexploitable. Moreover, they constitute a potential danger because they facilitate the outbreak of wildfires. To solve this problem, we have considered turning these needles into a biomaterial that could be used as raw material for different uses, such as wastewater treatment. The biomaterial of the Aleppo pine is obtained from its needles which are harvested in spring, dried, cut, crushed, and sieved. The powder obtained is analyzed before and after the extraction of essential oil. The physicochemical and spectroscopic analyses show that this biomaterial is porous, hygroscopic, slightly acidic, moderately moist, and not very conducive. Its average density in the anhydrous state is 0.6. It is rich in carbon (79.91%) and oxygen (18.91%) in the form of aromatic compounds and ketone imprints; thus, relating the presence of cellulose, pectin, lignin, and hemicellulose. Its composition in mineral elements (Na, Mg, Ca, K, Cl, S) is deficient. Gas chromatography-mass spectrometry (GC-MS) analysis of the oils extracted from the needle powder relates that it is a complex mixture of bioactive compounds such as mono-terpenoid α and β-pinene hydrocarbons. These results show that our biomaterial can be used as an adsorbent in wastewater treatment and the extracted essential oils can be used in the pharmacological, agro-food field.
Źródło:
Journal of Ecological Engineering; 2023, 24, 1; 41--50
2299-8993
Pojawia się w:
Journal of Ecological Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Removal of zinc, cadmium and nickel from mining waste leachate using walnut shells
Autorzy:
Ayala, Julia
Fernandez, Begona
Powiązania:
https://bibliotekanauki.pl/articles/208277.pdf
Data publikacji:
2019
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
metal ions
adsorption
biosorption
adsorbent
kinetics
copper
jony metali
adsorpcja
biosorpcja
kinetyka
miedź
Opis:
The removal of heavy metals from aqueous solutions using walnut shells was investigated. The effects of pH, contact time, initial metal concentration, adsorbent concentration, and co-ions were studied in synthetic solutions. Metal uptake was found to be dependent on the initial pH of the solution; the removal rate increased upon increasing pH, showing the highest affinity at pH 5–7. The amount of metal removed improved with increasing initial concentration. Increasing adsorbent dosage enhanced removal efficiency, but reduced the amount absorbed per unit mass of walnut shells. The presence of co-ions suppressed the uptake of heavy metals, divalent ions having a more negative effect than monovalentions. The adsorption of Zn, Cd and Ni onto walnut shells was found to fit Langmuir and Freundlich isotherms. The results obtained in the tests with mining waste leachate showed the potential use of walnut shells for the removal of heavy metals.
Źródło:
Environment Protection Engineering; 2019, 45, 2; 141-158
0324-8828
Pojawia się w:
Environment Protection Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Isotherm studies of malachite green removal by yarn processing sludge-based activated carbon
Badanie izoterm usuwania zieleni malachitowej przez osad ściekowy modyfikowany węglem aktywnym
Autorzy:
Tang, Shu Hui
Zaini, Muhammad Abbas Ahmad
Powiązania:
https://bibliotekanauki.pl/articles/106340.pdf
Data publikacji:
2019
Wydawca:
Towarzystwo Chemii i Inżynierii Ekologicznej
Tematy:
adsorbent
adsorption
chemical activation
dye removal
sludge
adsorpcja
aktywacja chemiczna
usuwanie barwników
szlam
Opis:
Adsorption is an effective wastewater treatment technique which has been widely used in various industrial applications. However, the high operation cost involving commercial activated carbon in industrial processes is the main drawback. Sewage sludge is an auspicious precursor of activated carbon owing to its high carbon content, rich functional groups, low cost, high availability and abundance. This research was aimed to establish the feasibility of converting yarn processing sludge into activated carbon by KI + KOH activation and char at 700 °C for 1 h. The effect of preparation strategies on the properties of sludge-based adsorbents (SBA) was reviewed. The applications of SBAs in the removal of dyes and model pollutants were discussed. The results from this study proved that the preparation of yarn processing sludge-based activated carbon via KI + KOH activation is feasible and effective in the adsorption of dye. This paper provides further insight on the preparation methods of sludge-based adsorbents and dye wastewater treatment using these adsorbents.
Źródło:
Chemistry-Didactics-Ecology-Metrology; 2019, 24, 1-2; 127-134
2084-4506
Pojawia się w:
Chemistry-Didactics-Ecology-Metrology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Wpływ zmian temperatury i czasu wygrzewania próbek skał mułowców na rozkład wielkości porów i powierzchnię właściwą BET na podstawie analiz izoterm adsorpcji
Effects of changes in temperature and heating times in the preparation of mudstones rock samples, on pore size distribution and specific surface BET measurements based on adsorption isotherm analysis
Autorzy:
Dudek, Lidia
Powiązania:
https://bibliotekanauki.pl/articles/1834957.pdf
Data publikacji:
2019
Wydawca:
Instytut Nafty i Gazu - Państwowy Instytut Badawczy
Tematy:
mułowce
adsorpcja
desorpcja
adsorbent
adsorbat
powierzchnia właściwa
temperatura wygrzewania
mudstones
adsorption
desorption
adsorbate
specific surface area
heating temperature
Opis:
Celem pracy jest przedstawienie efektów wygrzewania próbek skał ilasto-mułowcowych na ich strukturę porową, a konkretnie powierzchnię właściwą BET. Struktura porowa surowych i częściowo wygrzanych próbek była mierzona metodą adsorpcji azotu w niskiej temperaturze, w tym przypadku w temperaturze wrzenia ciekłego azotu. Otrzymane izotermy adsorpcji i desorpcji tych próbek były podobne i można je było zaklasyfikować jako typ II, według klasyfikacji IUPAC (Sing et al., 1985). Badania adsorpcyjne wykonano na próbkach skał ilastomułowcowych z utworów ordowiku i syluru oraz fliszu karpackiego. Selekcję próbek przeprowadzono na podstawie analizy składu mineralogicznego, opierając się na ilościowej analizie rentgenowskiej (tabela 3). Głównym kryterium wyboru była zawartość węglanu wapnia, ze względu na to, iż przyjmuje się, że węglany nie ulegają żadnym przemianom poniżej 550°C. Okazało się jednak, że przemiany następują już w znacznie niższych temperaturach. Dla każdej próbki wykonano co najmniej 30 pomiarów adsorpcyjnych, w sumie wykonując ich około 120 pomiarów. Otrzymano krzywe kumulacyjne oraz funkcje rozkładu objętości porów wyznaczone za pomocą algorytmu BJH (ang. Barrett-Joyner-Halenda) (Barrett et al., 1951), z gałęzi desorpcji przy użyciu równania statystycznej grubości warstwy Halseya i korekcji Faass (Faass, 1981) oraz wartości powierzchni właściwej BET (Brunauer et al., 1938). Analizując otrzymane wyniki można stwierdzić, że wszystkie próbki przed przystąpieniem do badania – w celu minimalizacji błędów pomiarowych związanych z heterogenicznością – należy przesiać przez sito 0,5 mm. Następnie po wygrzaniu i przedmuchaniu próbki w urządzeniu SmartPrep należy zatkać probówkę korkiem w celu eliminacji ponownego zawilgocenia. Konsekwencją wygrzewania próbki już nawet w temperaturze 65°C jest wzrost wartości Ro o 3%, lecz przy wygrzewaniu w 425°C rośnie ona aż o 500%. Po wykonaniu analizy adsorpcji azotem zauważono, że wszystkie próbki, niezależnie od ich współczynnika wzrostu lub spadku powierzchni właściwej BET z temperaturą, wykazują tendencję do lokalnych minimów w zakresie 130–190°C i 360–425°C oraz lokalnych maksimów 65–105°C i 250–320°C, których to wyjaśnienie powinno być przedmiotem osobnej pracy analizującej szczegółowo zjawiska fizycznochemiczne występujące w podobnym trendzie we wszystkich analizowanych próbkach.
The purpose of this work was to show the effects of heating up of mudstones rock samples, on their pore structure and especially on their specific surface BET. Porous structures of both – raw and partly heated samples – were measured using nitrogen adsorption method at low temperature i.e. boiling temperature of liquid nitrogen. Adsorption and desorption isotherms obtained for these samples were similar and they could be classified as type II according to IUPAC classification (Sing et al. 1985). Adsorption testing was conducted on clay-mudstone rock samples from Ordovician, Silurian and Carpathian Flysch layers. Sample selection was based on mineral content analysis outcome from quantitative X-ray analysis. The main selection criteria was calcium carbonate content, due to the fact that theoretically they do not undergo any transformations below 550°C, it turned out, however, that they might occur at much lower temperatures. At least 30 adsorption measurements were taken for each sample, totaling about 120 adsorption measurements. Cumulative curves were obtained together with pore volume distribution functions using BJH (BarrettJoyner-Halenda) (Barrett et al., 1951) algorithm from the desorption branch using Halsey’s statistical layer thickness equation and Faass (Faass, 1981) correction and also specific surface measurements (BET). Analysis of the obtained results allow us to conclude, that all samples should be put through the 0.5 mm sieve before analysis to minimize the error associated with its heterogenity. Later, after the sample has been preheated and Nitrogen vented in SmartPrep apparatus, it has to be cork sealed to eliminate secondary moisture adsorption. The consequence of preheating of a rock sample even at 65°C is the increase in its Vitrinite Reflectance by 3%, but after preheating it at 425°C, VR increases even by 500%. After adsorption analysis it was concluded that all the samples – regardless of whether their BET, change with temperature was positive or negative – showed local minima in 130–190°C and 360–425°C, and local maxima in 65–105°C and 250–320°C which phenomena should be examined in detail in further research, in order to analyse both physical and chemical processes present in similar trend in all analyzed samples.
Źródło:
Nafta-Gaz; 2019, 75, 1; 10-16
0867-8871
Pojawia się w:
Nafta-Gaz
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Materiały kompozytowe MOF-grafen
MOF-graphene composites
Autorzy:
Szczęśniak, B.
Choma, J.
Jaroniec, M.
Powiązania:
https://bibliotekanauki.pl/articles/171770.pdf
Data publikacji:
2017
Wydawca:
Polskie Towarzystwo Chemiczne
Tematy:
kompozyty MOF-grafen
adsorpcja gazów
magazynowanie gazów
adsorbenty
CO2
VOCs
H2
CH4
MOF-graphene composites
gas adsorption
gas storage
adsorbent
Opis:
The effective capture of harmful gases and clean energy sources are of great importance for protection of the environment. In this regard, it is possible to take advantage of the MOF-graphene composites to develop new technologies for environmental and energy-related applications. These composites attract a great attention around the world due to their higher adsorption affinity toward CO2, volatile organic compounds (VOCs), H2 and CH4 reported in comparison to the parent MOFs. Integration of MOFs with graphene nanosheets can be a very effective strategy not only to improve their adsorption performance but also to generate new chemical and physical properties that are not present in MOFs alone. In this review we present the progress in the field of gas capture/storage using MOF-graphene composites with special attention on the correlation between composition, structure and adsorption properties.
Źródło:
Wiadomości Chemiczne; 2017, 71, 9-10; 671-691
0043-5104
2300-0295
Pojawia się w:
Wiadomości Chemiczne
Dostawca treści:
Biblioteka Nauki
Artykuł
Wyświetlanie 1-15 z 17

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