- Tytuł:
- Synergistic extraction of Cr(VI) from Ni(II) and Co(II) by flat sheet supported liquid membranes using TIOA and TBP as carriers
- Autorzy:
-
Eyupoglu, V.
Surucu, A.
Kunduracioglu, A. - Powiązania:
- https://bibliotekanauki.pl/articles/778162.pdf
- Data publikacji:
- 2015
- Wydawca:
- Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
- Tematy:
-
flat sheet supported liquid membrane
selective extraction of Cr(VI)
TIOA
TBP
synergistic extraction
facilitated mass transfer - Opis:
- In present study, the synergistic separation of Cr(VI) has been investigated from synthetic acidic solution containing Cr(VI), Co(II) and Ni(II) by fl at sheet supported liquid membrane (FSSLM) technique using triisooctylamine (TIOA) and tri-n-butyl phosphate (TBP) as carriers. The main goal of the study was based in the exploring of the synergistic effect of TBP on selective extraction of Cr(VI) in presence of Co(II) and Ni(II) ions. The various parameters related with membrane and aqueous solution properties were studied to identify the optimum extraction and stripping conditions of the Cr(VI) through FSSLM. In the optimum conditions, initial mass flux (J0) and separation factors (βCr/Co and βCr/Ni) were obtained as 1.49 x 10-05 (kg/m2.s), 382.2 and 725.3 respectively from aqueous H2SO4 media through Celgard 2500 (Celgard Inc., USA) polymer support. As a result, the considerable synergistic infl uence on selective transport of Cr(VI) through FSSLM using TIOA and TBP as carriers has been identified.
- Źródło:
-
Polish Journal of Chemical Technology; 2015, 17, 2; 34-42
1509-8117
1899-4741 - Pojawia się w:
- Polish Journal of Chemical Technology
- Dostawca treści:
- Biblioteka Nauki