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    Tytuł:
    A Validated Reverse Phase HPLC Technique for the Determination of TATB Assay
    Autorzy:
    Bhattacharyya, S. C.
    Patil, R. S.
    Santosh, M. S. S. N. M.
    Bhattacharya, B.
    Malik, R. K.
    Mehra, A.
    Powiązania:
    https://bibliotekanauki.pl/articles/951496.pdf
    Data publikacji:
    2016
    Wydawca:
    Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
    Tematy:
    TATB
    HPLC
    HPTLC
    explosive
    LOQ
    LOD
    Opis:
    The main hurdle for the estimation of the purity of 1,3,5-triamino-2,4,6-trinitrobenzene (TATB) is its insolubility in most of the known organic solvents. In the conventional method, TATB is digested with steam in a modified Kjeldahl digester and the ammonia evolved is estimated quantitatively. To do away with this cumbersome method, a simple, rapid HPLC technique using a reverse phase C-18 column has been established for quantitative determination of the purity of TATB. A sharp and symmetrical peak with a retention time of 2.92 min at 355 nm is obtained for pure TATB when the flow rate is 2.0 mL/min. The linearity of the detector response has been studied with sample concentrations ranging from 10 to 50 mg/L. The method addresses two important issues of sample preparation and the precision of measurement. Unlike the previously reported HPLC techniques which mainly aimed at the detection of TATB, the present work is a validated account of a quantitative estimation of purity. Regular production batch samples have been assayed by this method and the results are compared with those obtained from the conventional analysis. The HPLC method is convenient and reliable for quality control of the product at the plant level.
    Źródło:
    Central European Journal of Energetic Materials; 2016, 13, 3; 641-657
    1733-7178
    Pojawia się w:
    Central European Journal of Energetic Materials
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Studies on High Burning Rate Composite Propellant Formulations using TATB as Pressure Index Suppressant
    Autorzy:
    Mehilal, -
    Jawalkar, S.
    Kurva, R.
    Sundaramoorthy, N.
    Dombe, G.
    Singh, P. P.
    Bhattacharya, B.
    Powiązania:
    https://bibliotekanauki.pl/articles/951502.pdf
    Data publikacji:
    2012
    Wydawca:
    Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
    Tematy:
    composite propellant
    ammonium perchlorate
    TATB
    pressure index suppressant
    Opis:
    High burning rate propellant compositions are generally used in gas generators to eject missile from canister. Because of high burning rate, pressure index of the composition increases during burning. To reduce the pressure index, a high burning rate composite propellant formulations (~20 mm/s) based on AP/HTPB/Al have been prepared by incorporating TATB and studied in detail for viscosity build-up, thermal and mechanical properties, sensitivity as well as burning rate and pressure index (n). The data indicate that there is a decrease in end of mix viscosity on increasing the percentage of TATB. The same trend was also observed with mechanical properties while significant improvement in overall thermal stability was clearly observed. The sensitivity data indicate that impact and friction values show decreasing trend infer better safe to handle. The burn rate data reveal that on addition of TATB from 0.5 to 2% decrease in burning rate was not observed while on addition of further TATB up to 5% and beyond this significant decrease in burning rate was observed. The data on pressure index (n) also reveal that TATB is very effective in reducing the 'n' value up to 2% and beyond this 'n' value increases close to standard composition. The data on 'n' value reveal that it reduces from 0.47 to that of standard composition to 0.36 for the compositions containing TATB up to 2.0% in the pressure range of 60-90 kg/cm2.
    Źródło:
    Central European Journal of Energetic Materials; 2012, 9, 3; 237-249
    1733-7178
    Pojawia się w:
    Central European Journal of Energetic Materials
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Process Optimization for the Gas-Liquid Heterogeneous Reactive Crystallization Process Involved in the Preparation of the Insensitive High Explosive TATB
    Autorzy:
    Nandi, A. K.
    Kshirsagar, A. S.
    Thanigaivelan, U.
    Bhattacharyya, S. C.
    Mandal, A. K.
    Pandey, R. K.
    Bhattacharya, B.
    Powiązania:
    https://bibliotekanauki.pl/articles/358228.pdf
    Data publikacji:
    2014
    Wydawca:
    Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
    Tematy:
    TATB
    TCTNB
    amination
    reaction crystallization
    chloride impurity
    particle size
    Opis:
    The thermally stable, insensitive, high explosive 1,3,5-triamino-2,4,6- trinitrobenzene (TATB) is manufactured by amination of 1,3,5-trichloro-2,4,6- trinitrobenzene (TCTNB) in toluene with NH3 gas. It is an isothermal, single-feed, semi-batch, gas-liquid heterogeneous, reaction crystallization process. The amination process is discussed by applying the chemical engineering methodology of mass transfer and reactive crystallization processes based on Two-Film Mass- Transfer (TFMT) theory. Kinetic expressions have been developed to define the chemical reactions as well as the physical phenomena (mass transfer) associated with this process. A single expression has been derived to explain the dependence of the ammonia consumption rate on various process parameters. Subsequently, the influence of various process parameters on the product quality (particle size and chloride impurity content) has been studied on the laboratory scale. Finally, the process has been established in the pilot plant, with optimized process conditions, to realize TATB of desired particle size and chloride content. The effects of feeding excess ammonia, and the presence of mercaptans/hydrogen sulphide impurities in poor quality toluene on the formation of certain undesirable by-products in TATB, are also discussed.
    Źródło:
    Central European Journal of Energetic Materials; 2014, 11, 1; 31-57
    1733-7178
    Pojawia się w:
    Central European Journal of Energetic Materials
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
      Wyświetlanie 1-3 z 3

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