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Wyświetlanie 1-6 z 6
Tytuł:
Silicon and aluminium in groundwater of the Kłodzko Region (the Sudetes, )land) - partial geochemical equilibrium with secondary solid phases
Autorzy:
Dobrzyński, D.
Powiązania:
https://bibliotekanauki.pl/articles/2059234.pdf
Data publikacji:
2006
Wydawca:
Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
Tematy:
Sudetes
groundwater geochemistry
aluminosilicate phases
hydroxyaluminosilicate HAS
silicon
aluminium
Opis:
The chemistry of shallow, cold groundwater in the eastern part of the Kłodzko Region (the Sudetes, SW Poland) was investigated, Groundwaters occur in the short turn-over time zone of the hydrogeological systems. The aquifers are composed of various bedrock types (metamorphic, igneous and sedimentary). Silicon and aluminium concentrations in the waters of particular aquifers are documented. The aqueous chemistry is interpreted in terms of the solubility of solid phases to indicate phases that are responsible for silicon and/or aluminium solubility control. Locally and/or periodically (seasonally) partial geochemical equilibrium between the groundwater and the secondary solid phases might be reached and maintained. In groundwater with a pH below 6.7, aluminium activity is usually controlled by the reversible congruent dissolution of A1(OH)3 forms, whereas silicon activity is probably controlled by the solubility the SiO2 form (chalcedony). At pHs above 6.7, the incongruent reaction between the hydroxyaluminosilicate colloid (HASB) and forms of Al(OH), controls both silicon and aluminium activities.
Źródło:
Geological Quarterly; 2006, 50, 3; 369-382
1641-7291
Pojawia się w:
Geological Quarterly
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Badania potencjału redoks na przykładzie sudeckich wód leczniczych
Research of redox potential on the example of curativewaters in the Sudetes Mts., Poland
Autorzy:
Dobrzyński, D.
Powiązania:
https://bibliotekanauki.pl/articles/2074741.pdf
Data publikacji:
2010
Wydawca:
Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
Tematy:
chemizm wód podziemnych
ptencjał redoks
wody lecznicze
Sudety
groundwater chemistry
redox potential
curative water
Sudetes
Opis:
In Poland, the redox potential (EH) is seldomly measured in groundwater. Since the year 2006 determination of redox potential is required for documenting properties of curative mineral waters. Investigations of redox conditions in groundwater need both proper measurement and interpretation. In the paper, crucial questions of: 1) redox equilibrium in groundwater, 2) field measurement, 3) correction methods, and 4) EH interpretation are presented. Some aspects of applying the redox potential for interpreting groundwater chemistry and using geochemical modelling are illustrated by hydrochemical data of curative waters from spas in the Sudetes Mts., SW Poland. Main reasons of the common redox non-equilibrium found in groundwater are co-existence of numerous aqueous redox pairs and usually non-equilibrium in particular redox pairs. Redox determinations have to be done in the field, and require extreme cleanness and precision, e.g., measuring without contact with the atmospheric air. Field measurements must be corrected to the standard hydrogen electrode, considering: type of reference electrode, concentration of electrode filling solution, type of standard redox solution, and water temperature. The redox potential has been measured in water at first from all the Sudetic spas, totally in 33 water intakes. In curative waters from the Sudetes corrected EH ranges between –159 mV and +343 mV. Usually, thermal waters show lower EH values than cold, CO2-rich waters. The lowest redox potential was found in the hottest thermal waters, i.e., in water from Zdzisław intake (in Lądek Zdrój) and C-2 intake (in Cieplice Śląskie Zdrój). Generally, the higher the pH, the lower the EH in groundwater. Methods of geochemical modelling, which are often and often applied in groundwater research, also require the EH determination. Information about EH are used in the calculation of speciation models of water, and affect the results of whole geochemical modelling as well as evaluations of the saturation state. The speciation-solubility modelling for the Sudetic curative waters, presented in the paper, shows that the proper correction of field EH measurement determines the quality of calculations. Improperly corrected EH values might lead to species activity errors, even up to several order of magnitudes, and erroneous interpretation of the mineral phases stability in the hydrogeochemical system.
Źródło:
Przegląd Geologiczny; 2010, 58, 1; 46-53
0033-2151
Pojawia się w:
Przegląd Geologiczny
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Rola częściowych równowag chemicznych w kontrolowaniu aktywności krzemu w sudeckich wodach leczniczych
The role of partial chemical equilibrium for silicon activity controlling in curative mineral waters, the Sudetes, Poland
Autorzy:
Dobrzyński, D.
Powiązania:
https://bibliotekanauki.pl/articles/2063200.pdf
Data publikacji:
2009
Wydawca:
Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
Tematy:
równowagi chemiczne
krzem
wody podziemne
Sudety
wody lecznicze
koloidy glinokrzemianowe HASB
Sudetes
silicon
groundwaters
curative water
chemical equilibrium
hydroxyaluminosilicate colloid HASB
Opis:
Skład chemiczny sudeckich wód leczniczych został poddany interpretacji z punktu widzenia kontroli rozpuszczalności krzemu. W termalnych wodach leczniczych Lądka-Zdroju i Cieplic Śląskich-Zdroju istnieją warunki sprzyjające trwałości koloidu glinokrzemianowego HASB. Aktywność krzemu w zarówno chłodnych, jak i termalnych wodach leczniczych może być kontrolowana przez częściowe równowagi chemiczne reakcji inkongruentnego rozpuszczania faz glinokrzemianowych z utworzeniem Al(OH)3.
Chemical composition of curative mineral waters from the Sudetic spas was interpreted in terms of silicon solubility control. In thermal waters from Lądek-Zdrój and Cieplice Śląskie-Zdrój, conditions for stability of hydroxyaluminosilicate HASB are maintained. In both cold and thermal waters, silicon might be controlled by partial chemical
Źródło:
Biuletyn Państwowego Instytutu Geologicznego; 2009, 436, z. 9/1; 87-94
0867-6143
Pojawia się w:
Biuletyn Państwowego Instytutu Geologicznego
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Silica solubility in groundwater from Permian volcanogenic rocks (the Sudetes Mts., SW Poland) : the role of reversible aluminosilicate solids
Autorzy:
Dobrzyński, D.
Powiązania:
https://bibliotekanauki.pl/articles/2059124.pdf
Data publikacji:
2006
Wydawca:
Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
Tematy:
Sudetes
groundwater chemistry
volcanic rocks
silicon
aluminium
hydroxyaluminosilicates (HAS)
allophanes
Opis:
The chemistry of groundwater in Permian volcanic rocks (rhyolitic tuffs, trachyandesites) in two small headwater catchments (the SudetesMts., SW Poland) has been investigated. The calculated transfer of silica released during weathering is greater than the real concentration in groundwater, and indicates that part of the silica is immobilized in secondary aluminosilicates. Silica solubility is interpreted in terms of the solubility of reversible secondary aluminosilicates (allophanes, hydroxyaluminosilicates). Partial chemical equilibrium of these phases is sometimes locally achieved. In groundwaters with pH above 6.7 from trachyandesites of the BukowiecMt. type, chemical equilibrium with respect to the hydroxyaluminosilicate HASB is probably maintained. Its solubility constant, calculated accordingly to the method given by Schneider et al. (2004), is lgK HASB = –44.74 (۪.52), and indicates that this "field" HASB has a solubility lower than the published experimental value (lgK HASB = –40.6 ۪.15) for synthetic HASB (op.cit.). Non-equilibrium with respect to aluminosilicates in groundwaters from rhyolitic tuffs and from trachyandesites of the Stożek Wielki Mt. type is caused by the short turn-over time of groundwater in the systemand by the poor neutralisation capacity of the bedrock. The silica concentration in these groundwaters results from steady-state conditions achieved between weathering release, hydrological removal and precipitation of secondary phases. The hydrogeochemical data are conducive to the presence of allophane minerals in the weathered rhyolitic tuffs.
Źródło:
Geological Quarterly; 2006, 50, 4; 407-417
1641-7291
Pojawia się w:
Geological Quarterly
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Estimation of inorganic carbon sources in groundwater recharge by inverse geochemical modelling (Carboniferous aquifer, the Intra-Sudetic Basin, SW Poland)
Autorzy:
Dobrzynski, D.
Powiązania:
https://bibliotekanauki.pl/articles/2060223.pdf
Data publikacji:
2008
Wydawca:
Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
Tematy:
Polska
Sudetes
inverse geochemical modelling
radiocarbon activity
groundwater chemistry
Opis:
Geochemical modelling was applied in quantification of chemical reactions responsible for the chemistry of groundwater in the recharge zone of a Carboniferous aquifer (the Sudety Mts., SW Poland). Calculation of the contribution of dissolved in organic carbon (DIC) sources allowed estimation of the initial radiocarbon activity in the recharge to groundwater. The 14C activity calculated upon the results of geochemical modelling is consistent with the 14C activity measured in groundwater. Geochemical modelling can be applied for estimation of the initial 14C activity in recharge water as well as the 14C activity in groundwater along the flow path. Methods of geochemical modelling have an advantage over empirical methods because they combine the effects of various chemical reactions occurring in the geochemical system.
Źródło:
Geological Quarterly; 2008, 52, 2; 191-191
1641-7291
Pojawia się w:
Geological Quarterly
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
German jako wskaźnik warunków hydrogeochemicznych w jeleniogórskim systemie geotermalnym
Germanium as an indicator of hydrogeochemical conditions in the Jelenia Góra Geothermal System
Autorzy:
Dobrzyński, D.
Gruszczyński, T.
Birski, Ł.
Powiązania:
https://bibliotekanauki.pl/articles/2075752.pdf
Data publikacji:
2017
Wydawca:
Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
Tematy:
german
silikon
woda termalna
system geotermalny
Jelenia Góra
Sudety
Polska
germanium
silicon
thermal water
Jelenia Góra Geothermal System
Sudetes
Polska
Opis:
Geochemical studies on trace elements in thermal waters from Cieplice, Karpniki and Staniszów (Jelenia Góra Geothermal System, Sudetes, Poland) revealed a presumably regional relation between germanium and silicon. The Ge:Si ratios in waters of Cieplice are likely controlled by the chemical equilibrium process of silicate minerals transformation in granite aquifer-rocks. Geochemical inverse mass balance modelling using main rock-forming minerals of actual composition shows that incongruent dissolution ofprimary silicate minerals with forming secondary (clay minerals, silica forms) phases is responsible for thermal water chemistry in Cieplice. Available data on germanium in silicate minerals combined with the results of geochemical modelling give Ge:Si ratios close to real values. A chemical non-equilibrium, and a gradual decrease of both the germanium content and the Ge:Si ratio have been identified in the thermal waters from two new intakes (Karpniki, Staniszów).
Źródło:
Przegląd Geologiczny; 2017, 65, 11/1; 946--950
0033-2151
Pojawia się w:
Przegląd Geologiczny
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-6 z 6

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