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Wyświetlanie 1-8 z 8
Tytuł:
Characteristics of the Ahmadabad hematite/barite deposit, Iran – studies of mineralogy, geochemistry and fluid inclusions
Autorzy:
Babaei, A. H.
Ganji, A.
Powiązania:
https://bibliotekanauki.pl/articles/94546.pdf
Data publikacji:
2018
Wydawca:
Uniwersytet im. Adama Mickiewicza w Poznaniu
Tematy:
geochemistry
trace elements
rare earth elements
Semnan
geochemia
pierwiastki śladowe
pierwiastki ziem rzadkich
REE
Opis:
The Ahmadabad hematite/barite deposit is located to the northeast of the city of Semnan, Iran. Geostructurally, this deposit lies between the Alborz and the Central Iran zones in the Semnan Subzone. Hematite-barite mineralisation occurs in the form of a vein along a local fault within Eocene volcanic host rocks. The Ahmadabad deposit has a simple mineralogy, of which hematite and barite are the main constituents, followed by pyrite and Fe-oxyhydroxides such as limonite and goethite. Based on textural relationships between the above-mentioned principal minerals, it could be deduced that there are three hydrothermal mineralisation stages in which pyrite, hematite and barite with primary open space filling textures formed under different hydrothermal conditions. Subsequently, in the supergene stage, goethite and limonite minerals with secondary replacement textures formed under oxidation surficial conditions. Microthermometric studies on barite samples show that homogenisation temperatures (TH) for primary fluid inclusions range from 142 to 256°C with a temperature peak between 200 and 220°C. Salinities vary from 3.62 to 16.70 NaCl wt% with two different peaks, including one of 6 to 8 NaCl wt% and another of 12 to 14 NaCl wt%. This indicates that two different hydrothermal waters, including basinal and sea waters, could have been involved in barite mineralisation. The geochemistry of the major and trace elements in the samples studied indicate a hydrothermal origin for hematite and barite mineralisation. Moreover, the Fe/Mn ratio (>10) and plots of hematite samples of Ahmadabad ores on Al-Fe-Mn, Fe-Mn-(Ni+Co+ Cu)×10, Fe-Mn-SiX2 and MnO/TiO2 – Fe2O3/TiO2 diagrams indicate that hematite mineralisation in the Ahmadabad deposit occurred under hydrothermal conditions. Furthermore, Ba and Sr enrichment, along with Pb, Zn, Hg, Cu and Sb depletion, in the barite samples of Ahmadabad ores are indicative of a low temperature hydrothermal origin for the deposit. A comparison of the ratios of LaN/YbN, CeN/YbN, TbN/LaN, SmN/NdN and parameters of Ce/Ce* and La/La* anomalies of the hematite, barite, host volcanic rocks and quartz latite samples to each other elucidate two important points: 1) the barite could have originated from volcanic host rocks, 2) the hematite could have originated from a quartz latite lithological unit. The chondrite normalised REE patterns of samples of hematite barite, volcanic host rocks and quartz latite imply that two different hydrothermal fluids could be proposed for hematite and barite mineralisation. The comparison between chondrite normalised REE patterns of Ahmadabad barite with oceanic origin barite and low temperature hydrothermal barite shows close similarities to the low temperature hydrothermal barite deposits.
Źródło:
Geologos; 2018, 24, 1; 55-68
1426-8981
2080-6574
Pojawia się w:
Geologos
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effect of Rare Earth Cerium Addition on Oxidation Behavior of Co-Al-W Alloys at 800°C
Autorzy:
Migas, Damian
Liptáková, Tatiana
Moskal, Grzegorz
Powiązania:
https://bibliotekanauki.pl/articles/2048827.pdf
Data publikacji:
2022
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
rare earth elements
REE
cyclic oxidation
γ-γ′ cobalt-based superalloys
Co-Ce
Opis:
The γ/γ′ Co-based alloys are a new class of cobalt superalloys, which are characterized by remarkable high temperature strength owing to strengthening by γ′-Co3(Al, X) phases. In this investigation, the effect of cerium addition on oxidation behavior of model Co-Al-W alloys was studied. The introduction of Ce aimed at improvement of the oxidation resistance of γ′-forming Co-based superalloys. The minor additions of cerium (0.1, 0.5 at.%) were added to the base alloy Co-9Al-9W. The alloys were prepared via induction vacuum melting (VIM). Further, a primary microstructure of the alloys was analyzed with particular regard to a segregation of Ce. The thermogravimetric analysis (TG) under non-isothermal conditions was used to preliminary estimate the oxidation behavior of alloys at different temperatures. During experiment, differential thermal analysis (DTA) was performed simultaneously. After this test, cyclic oxidation expermients was carried out at 800°C for 500 h. In as-cast state, Ce segregates to interdendritic areas and forms intermetallic phases. The effect connected with melting of interdendritic precipitates was observed at 1160°C. Ce-containing alloys were less prone of oxide spallation. Moreover, oxidation rate of these alloys substantially decreased after 100h of oxidation, whereas mass of the sample corresponding to base alloy continued to increase.
Źródło:
Archives of Metallurgy and Materials; 2022, 67, 1; 203-208
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Pierwiastki ziem rzadkich (REE) w środowiskach powierzchniowych litosfery
Rare Earth Elements (REE) in surface environments of the lithosphere
Autorzy:
Kwecko, P.
Powiązania:
https://bibliotekanauki.pl/articles/2075552.pdf
Data publikacji:
2016
Wydawca:
Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
Tematy:
pierwiastki ziem rzadkich
REE
gleba
skały
minerały
rare earth elements (REE)
soil
rocks
minerals
Opis:
In the Polish geochemical literature there is no general discussion of the occurrence and behaviour of REE in surface environments. This text is an attempt to review the world literature concerning the REE occurrence and behaviour mainly in rocks, minerals (primary and secondary) and soils, and during hypergenic and soil-forming processes. The article also presents the atomic structure and properties of REE, their divisions and participation in the biosphere, organic matter and sediments of selected Polish lakes and, additionally, anthropogenic sources. Particular attention is given to primary and secondary REE minerals and their presence in rocks, soils (including soil-forming processes) and hypergenic processes. The main source of REE is the primary minerals of acid and siliceous igneous rocks and secondary minerals of sedimentary rocks. Among primary minerals the largest quantities of REE are concentrated in heavy minerals (anatase, ilmenite, sphe- ne, rutile and zircon). Basic silicate weathering leads to the formation of secondary clay minerals which, together with iron and manganese oxides and carbonates, are the main sources of REE as secondary minerals.
Źródło:
Przegląd Geologiczny; 2016, 64, 11; 902--917
0033-2151
Pojawia się w:
Przegląd Geologiczny
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Two new separation schemes for the group isolation of rare earth elements (REE) from biological and other matrices and their determination by ICP-MS, NAA and chromatographic methods
Autorzy:
Dybczyński, R. S.
Samczyński, Z.
Bartosiewicz, I.
Kulisa, K.
Polkowska-Motrenko, H.
Pyszynska, M.
Zuba, I.
Powiązania:
https://bibliotekanauki.pl/articles/147581.pdf
Data publikacji:
2017
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
rare earth elements
REE
lanthanides
ion exchange chromatography
NAA
ICP-MS
accuracy
certified reference materials
CRM
Opis:
Two new group separation schemes, based on ion exchange chromatography, for the selective and quantitative isolation of rare earth elements (REE) from accompanying elements, were devised. After checking their performance with the aid of radioactive tracers, the schemes were further used together with ICP-MS, NAA and ion exchange chromatography for the determination of Sc, Y, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb and Lu in two certified reference materials (CRMs). The results were compared with another series of analyses, where the REEs were determined directly, i.e. without pre-separation, by instrumental neutron activation analysis (INAA) and inductively coupled plasma mass spectrometry (ICP-MS). It was demonstrated that while direct INAA and ICP-MS in most instances provide reliable results for the majority of REEs, for some elements, notably Sc, Yb and Tm in the cases of ICP-MS and INAA, respectively, systematic errors occur or may potentially occur.
Źródło:
Nukleonika; 2017, 62, 3; 199-211
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Przegląd głównych minerałów pierwiastków ziem rzadkich : złoto XXI wieku
Review of the major minerals of rare earth elements : gold of the 21st century
Autorzy:
Ryder, P.
Nowak, M.
Powiązania:
https://bibliotekanauki.pl/articles/2075335.pdf
Data publikacji:
2015
Wydawca:
Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
Tematy:
REE
pierwiastki ziem rzadkich
apatyt
bastnazyt
ksenotym
loparyt
monazyt
rare earth elements (REE)
apatite
bastnäsite
xenotime
loparite
monazite
Opis:
The constant evolution of civilisation and ever more advanced technologies have forced the global economy to search for new and renewable resources. Since the 1950s, rare earth elements (REE) have played an increasingly significant role in the production of new materials. The REE form a group of 17 elements (15 lanthanides, yttrium and scandium) with special properties that distinguish them from the other elements. These unique and essential raw materials have numerous applications nowadays. Without the rare earths, many branches of industry would not be able to function. The main resources of the REE come from the rocks with mineralization enriched in minerals with a higher REO (rare earth oxides) contents. Although there are around 270 different REE-bearing mineral species, the exploitation of the REE refers to less than 10 minerals. Five major REE minerals (the major minerals from group of bastnäsite (bastnaesite), monazite, xenotime, apatite and perovskite (loparite)) are characterized and described. The REO percentage content varies from max. 16% in apatite to max. 79% in bastnäsite. The examples shown were chosen due to their importance and level of extraction. This review-paper has been based on the compilation of data from mineralogical publications, mineralogical data websites and metallurgical articles about the alloys and their compounds.
Źródło:
Przegląd Geologiczny; 2015, 63, 6; 348--362
0033-2151
Pojawia się w:
Przegląd Geologiczny
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Stratigraphy of the Albian-Cenomanian (Cretaceous) phosphorite interval in central Poland: a reappraisal
Autorzy:
Machalski, Marcin
Olszewska-Nejbert, Danuta
Wilmsen, Markus
Powiązania:
https://bibliotekanauki.pl/articles/24024713.pdf
Data publikacji:
2023
Wydawca:
Polska Akademia Nauk. Czasopisma i Monografie PAN
Tematy:
Polska
Cretaceous
phosphorites
rare earth elements
biostratigraphy
sequence stratigraphy
Polska
kreda
fosforyty
metale ziem rzadkich
REE
biostratygrafia
stratygrafia sekwencji
Opis:
Several closely-spaced phosphorite beds stand out at the Albian–Cenomanian transition in the mid-Cretaceous transgressive succession at the northeastern margin of the Holy Cross Mountains, central Poland. They form a distinctive condensed interval of considerable stratigraphical, palaeontological, and economic value. Here, we correlate the classical section at Annopol with a recently investigated section at Chałupki. We propose a new stratigraphic interpretation of the phosphorite interval, based on lithological correlations, Rare Earth Elements and Yttrium (REE+Y) signatures of phosphorites, age-diagnostic macrofossils, and sequence stratigraphic patterns. This interval has long been considered as exclusively Albian in age. However, new macrofossil data allow us to assign the higher phosphorite levels at Annopol and Chałupki, which were the primary target for the phosphate mining, to the lower Cenomanian. In terms of sequence stratigraphy, the phosphorite interval encompasses the depositional sequence DS Al 8 and the Lowstand System Tract of the successive DS Al/Ce 1 sequence. The proposed correlation suggests that lowstand reworking during the Albian–Cenomanian boundary interval played an important role in concentrating the phosphatic clasts and nodules to exploitable stratiform accumulations. Our conclusions are pertinent to regional studies, assessments of natural resources (in view of the recent interest in REE content of the phosphorites), and dating of the fossil assemblages preserved in the phosphorite interval. On a broader scale, they add to our understanding of the formation of stratiform phosphorite deposits.
Źródło:
Acta Geologica Polonica; 2023, 73, 1; 1--31
0001-5709
Pojawia się w:
Acta Geologica Polonica
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Dystrybucja pierwiastków ziem rzadkich (REE) w procesie sekwencyjnego ługowania węgla z pokładu 404 KWK „Pniówek” (GZW)
The distribution of rare earth elements (REE) during sequential chemical leaching of coal from seam 404, “Pniówek” Coal Mine (USCB)
Autorzy:
Adamczyk, Z.
Jakóbik, A.
Komorek, J.
Lewandowska, M.
Osadnik, M.
Powiązania:
https://bibliotekanauki.pl/articles/113453.pdf
Data publikacji:
2016
Wydawca:
STE GROUP
Tematy:
pierwiastki ziem rzadkich
REE
sekwencyjne chemiczne ługowanie
warstwy rudzkie
GZW
rare earth elements (REE)
sequential chemical leaching
Ruda beds
USCB
Opis:
Celem pracy było określenie dystrybucji pierwiastków ziem rzadkich (REE) w procesie sekwencyjnego chemicznego ługowania próbek węgla z pokładu 404 KWK Pniówek. Na potrzeby pracy wykorzystano pięciostopniową zmodyfikowaną procedurę ługowania opisaną w pracy D.A. Spears. Zawartość REE w uzyskanych roztworach oznaczono metodą ICP-MS). Analizowano oddzielnie udziały REE w próbkach bruzdowych węgla oraz w roztworach będących produktami sekwencyjnego ługowania substancji nieorganicznej i organicznej węgla. Stwierdzono zróżnicowany udział REE w analizowanych próbkach węgla. Normalizacja udziałów REE do chondrytów wykazała obecność małej anomalii ujemnej dla Eu i większej dodatniej dla Gd. Na wszystkich krzywych po znormalizowaniu widoczne jest wzbogacenie próbek węgla w LREE i odpowiednio niższy mało zróżnicowany udział HREE. Podobnym przebiegiem charakteryzują się krzywe po znormalizowaniu uzyskane dla produktów ługowania związanych z substancją organiczną węgla (etap IV-V) i krzemianami. Krzywe normalizacyjne uzyskane dla produktów ługowania związanych z substancją mineralną (etap I-III) dla poszczególnych próbek węgla są podobne. Wszystkie charakteryzują się dodatnimi anomaliami w zakresie Sm-Tb oraz wzbogaceniem udziałów MREE względem LREE.
The aim of the study was to determine the distribution of REE in coal using during the sequential chemical leaching of four coal samples from 404 seam of Ruda beds of “Pniówek” coal mine. The five digestion steps were used to determine REE distribution. In this study adopted the leaching procedure described in work D.A. Spears.The content of REE in obtained solutions was determined by ICP-MS method.The contents of REE in the samples was analyzed in coal and separately in the solutions which were products of the sequential leaching of inorganic and organic substances of coal. It was found that the REE content in coal samples is varied. The contents of REE were normalized to chondrites. It showed a small negative anomaly for Eu and larger positive anomaly for Gd. The enrichment in LREE of coal samples and respectively lower and less diverse of HREE content are shown on all of the normalized curves. The normalized curves obtained for chondrites REE content in the leaching products connected with organic substance (stage IV-V) have a similar course.The normalized curves obtained for chondrites REE content of the leaching products connected with mineral substance (stage I-III) for the individual samples of coal were similar. All these curves are characterized by positive anomalies in the range of Sm-Tb and enrichment in MREE relative to LREE.
Źródło:
Systemy Wspomagania w Inżynierii Produkcji; 2016, 5 (17); 21-37
2391-9361
Pojawia się w:
Systemy Wspomagania w Inżynierii Produkcji
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Contents of Rare Earth Elements in Acidic Waters Linked to Mining of Coal and Lignite (Upper Silesia and Muskau Bend, Southern Poland)
Zawartości pierwiastków ziem rzadkich w kwaśnych wodach związanych z górnictwem węgla kamiennego i węgla brunatnego (Górny Śląsk i Łuk Mużakowa, południowa Polska)
Autorzy:
Bauerek, Arkadiusz
Bebek, Małgorzata
Białecka, Barbara
Mitko, Krzysztof
Thomas, Maciej
Powiązania:
https://bibliotekanauki.pl/articles/1812062.pdf
Data publikacji:
2019
Wydawca:
Politechnika Koszalińska. Wydawnictwo Uczelniane
Tematy:
acid mine drainage
AMD
rare earth elements
REE
coal
lignite
acidity
sulfates
kwaśny drenaż górniczy
pierwiastki ziem rzadkich
węgiel
węgiel brunatny
kwasowość
siarczany
Opis:
The aim of the research was comparison rare earth elements contents in acidic waters related to coal mining in the eastern part of the Upper Silesian Coal Basin (USCB), southern Poland, and the former lignite mining in the Polish part of the Muskau Bend. Acidic runoff waters flowing down from mine waste piles in the USCB are enriched with REEs (ΣREEs 478.5 and 1831.9 µg/l) compared to waters filling old lignite mining excavations (ΣREEs 19.7-145.3 µg/l). High concentrations of REEs in acidic waters from the USCB result from their high aggressiveness (acidity 1020 mg/l CaCO3 and 3820 mg/l CaCO3, pH 2.4 and 3.0) to loamy sediments being a source of REEs, and increase as the time of their contact increases. Concentrations of NASC-normalized REEs show that waters from the USCB are enriched in MREEs (Sm, Eu, Gd and Tb), while the waters from the Muskau Bend are characterized by a positive anomaly of LREEs (La and Ce) and a less marked anomaly of MREEs (Gd, Tb and Dy).
Celem badań było porównanie zawartości pierwiastków ziem rzadkich w kwaśnych wodach związanych z wydobyciem węgla kamiennego, we wschodniej części Górnośląskiego Zagłębia Węglowego (GZW) oraz związanych z dawnym wydobyciem węgla brunatnego w polskiej części Łuku Mużakowa. Kwaśne wody spływu powierzchniowego z hałd odpadów górniczych GZW są wzbogacone w pierwiastki ziem rzadkich (REE) (ΣREE 478,5 i 1831,9 μg/l) w porównaniu do wód wypełniających stare wyrobiska górnicze węgla brunatnego (ΣREE 19,7-145,3 μg/l). Wysokie stężenia REE w kwaśnych wodach z GZW wynikają z ich wysokiej agresywności (kwasowość 1020 mg/l CaCO3 i 3820 mg/l CaCO3, pH 2,4 i 3,0) względem ilastych osadów będących źródłem REE i rosną wraz z upływem czasu ich kontaktu z osadami. Stężenia pierwiastków ziem rzadkich znormalizowane do północnoamerykańskiego łupku złożonego (NASC) pokazują, że kwaśne wody z GZW są wzbogacone w pośrednie pierwiastki ziem rzadkich (MREE) (Sm, Eu, Gd i Tb), podczas gdy wody z Łuku Mużakowa charakteryzują się dodatnią anomalią stężeń lekkich pierwiastków ziem rzadkich LREE (La i Ce) i mniej wyraźnymi anomaliami pierwiastków pośrednich MREE (Gd, Tb i Dy).
Źródło:
Rocznik Ochrona Środowiska; 2019, Tom 21, cz. 2; 1040-1060
1506-218X
Pojawia się w:
Rocznik Ochrona Środowiska
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-8 z 8

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