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Wyszukujesz frazę "Niobium" wg kryterium: Temat


Wyświetlanie 1-2 z 2
Tytuł:
Plasma Electrolytic Oxidation as a modern method to form porous coatings enriched in phosphorus and copper on biomaterials
Autorzy:
Rokosz, Krzysztof
Hryniewicz, Tadeusz
Powiązania:
https://bibliotekanauki.pl/articles/1190116.pdf
Data publikacji:
2016
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
Plasma Electrolytic Oxidation (PEO)
Niobium
Ti6Al4V
TNZ
Porous coatings
Opis:
In the paper, the porous coatings obtained on niobium and two titanium alloys (Ti6Al4V, and TNZ) after Plasma Electrolytic Oxidation (PEO), known also as Micro Arc Oxidation, were studied. The samples were treated at the voltage of 450 V for 3 minutes in the electrolyte consisting of 300 g and 600 g of copper nitrate Cu(NO3)2 in 1 litre of concentrated phosphoric acid H3PO4, consecutively. SEM and EDS studies were performed on the samples. Based on the obtained results it may be concluded that enriched in copper porous coatings on all studied materials were created in the electrolyte within copper nitrate amounting for 600 g. The proposed by the Authors factor to evaluate the obtained coatings, i.e. copper-to-phosphorus ratio, which for the studied materials amounted to 0.21, clearly indicates that the performed electrochemical PEO treatment for surface modification especially of bioimplants may be advised.
Źródło:
World Scientific News; 2016, 35; 44-61
2392-2192
Pojawia się w:
World Scientific News
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Theoretical investigations into the Spectrophotometrically Analyzed Niobium (V)-6-Chloro-3-hydroxy-7-methyl-2-(2’-thienyl)-4H-chromen-4-one Complex
Autorzy:
Dhonchak, Chetna
Agnihotri, Nivedita
Azam, Mohammad
Javed, Saleem
Muthu, Sambantham
Al-Resayes, Saud I.
Min, Kim
Powiązania:
https://bibliotekanauki.pl/articles/27315655.pdf
Data publikacji:
2023
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
Niobium
6-Chloro-3-hydroxy-7-methyl-2-(2’-thienyl)-4H-chromen-4-one
spectrophotometry
DFT
density functional theory
MEP
molecular electrostatic potential
Opis:
Pentavalent niobium cation forms a stable yellow-colored binary complex with 6-chloro-3-hydroxy-7-methyl-2-(2’- thienyl)-4H-chromen-4-one (CHMTC) in the ratio of 1:2. The complex is quantitatively extractable into carbon tetrachloride from HClO4 solution maintained at pH 1.26–1.75 and strictly adheres to Beer’s law as verified by the Ringbom plot with an optimized range of determination as 0.385–1.211 ppm of Nb(V). The ligand-metal complex system shows good precision, accuracy, sensitivity, and selectivity and handles satisfactorily the analysis of several samples of varying complexity. The results are highly reproducible as confirmed by statistical data. The stability of the complex is theoretically confirmed with the help of HOMO-LUMO values and the energy gap [for CHMTC, ΔEgap = 3.62 V and for Nb(V)-CHMTC Complex, ΔEgap = 2.97 eV]. The reactivity descriptors were calculated for detailed computational study to probe into the chemical behavior of the studied ligand and its complex. Further, mapped electrostatic potential diagrams help in justifying the donor sites of CHMTC ligand which is in accordance with the analytical findings.
Źródło:
Polish Journal of Chemical Technology; 2023, 25, 3; 63--70
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-2 z 2

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