- Tytuł:
- Synthesis of nanoscale zero-valent iron doped carbonized zeolitic imidazolate framework-8 for methylene blue removal in water
- Autorzy:
-
Chen, Shuai
Qiao, Lemeng
Feng, Xuejiao
Huang, Yufu
Gao, Guilan
Guan, Jie
Lin, Donghai - Powiązania:
- https://bibliotekanauki.pl/articles/2204144.pdf
- Data publikacji:
- 2023
- Wydawca:
- Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
- Tematy:
-
Nanoscale zero-valent iron
Carbonized zeolitic imidazolate framework-8
Mesoporous carbon
Methylene blue - Opis:
- Nanoscale zero-valent iron-doped carbonized zeolitic imidazolate framework-8 (nZVI/CZIF-8) was prepared by carbonation of ferric nitrate and ZIF-8 at 800 °C and used as an adsorbent to remove methylene blue (MB) from water. The synthesized nZVI/CZIF-8 has a specific surface area of 806.9 m2/g, a pore volume of 0.86 cm3/g and an nZVI content of 1.35%, respectively. Both the nZVI/CZIF-8 and CZIF-8 have identical functional groups of O-H, C-H and C=C. With the increase of CZIF-8 size, MB removal rate increased. The doping of nZVI increased the MB removal percentage from 74.5% for ZIF-8 to 96.2% within 80 min for nZVI/CZIF-8. The MB removal percentage increased with the dosage of nZVI/CZIF-8. The MB adsorption with the adsorbents conforms to the Freundlich adsorption isothermal model and the removal rate fitted well to a pseudo-first-order model. The results demonstrate the feasibility of synthesizing high active and stable nZVI/CZIF-8 particles.
- Źródło:
-
Polish Journal of Chemical Technology; 2023, 25, 1; 12--19
1509-8117
1899-4741 - Pojawia się w:
- Polish Journal of Chemical Technology
- Dostawca treści:
- Biblioteka Nauki
Artykuł