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Wyświetlanie 1-4 z 4
Tytuł:
Defect structure of Fe-Al and Fe-Al-X (X = Ni; Cu; Cr) metallic powders obtained by the self-decomposition method
Autorzy:
Hanc, A.
Frąckowiak, J.
Powiązania:
https://bibliotekanauki.pl/articles/147208.pdf
Data publikacji:
2004
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
iron aluminides
defects
points defects
Mössbauer spectroscopy
Fe-Al
Opis:
In the present work, the Fe-Al-X (X = Cu; Ni; Cr) metallic powders produced by the self-decomposition method of the Fe-Al doped alloys were examined by Mössbauer spectroscopy. The concentration of the Fe vacancies and the Fe atoms substituting Al (Fe-AS) was determined from the intensities of the sub-spectra in the Mössbauer analysis connected with distinct Fe environments. The results have shown that nickel and copper cause an increase of vacancy concentrations in comparison with the values found for Fe-Al metallic powders, whereas chromium decreases vacancy concentrations causing a significant increase of anti-site atoms Fe-AS concentration.
Źródło:
Nukleonika; 2004, 49,suppl.3; 7-11
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Point defects in the B2 - phase region of the Fe-Al system studied by Mössbauer spectroscopy and X-ray diffraction
Autorzy:
Hanc-Kuczkowska, A.
Powiązania:
https://bibliotekanauki.pl/articles/147904.pdf
Data publikacji:
2013
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
iron aluminides
Mössbauer spectroscopy
point defects
X-ray diffraction
Opis:
In this work Mössbauer spectroscopy and X-ray powder diffraction was used to study of point defects formation in intermetallic phases of the B2 structure of the Fe-Al system as a function of Al concentration. The results are compared with the concentrations of point defects determined from positron annihilation data. The values of the 57Fe isomer shift and quadrupole splitting for the components describing the point defects in the local environment of a Mössbauer nuclide are presented. The concentration of the Fe vacancies and Fe atoms substituting Al (i.e. anti-site atom, Fe-AS) are determined. The results show that an increase in Al content causes an increase in vacancy and Fe-AS concentrations.
Źródło:
Nukleonika; 2013, 58, 1; 123-126
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Ordering process in Fe-Al28Cr5 alloys studied by Mössbauer spectroscopy
Autorzy:
Hanc-Kuczkowska, A.
Kansy, J.
Deniszczyk, J.
Powiązania:
https://bibliotekanauki.pl/articles/147348.pdf
Data publikacji:
2013
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
Fe-Al28Cr5 alloys
formation of D03 phases
Mössbauer spectroscopy
Opis:
In the paper, studies of ternary Fe-Al28Cr5 alloys directed to characterization of mechanisms of the formation of ordered intermetallic phases influencing the possibilities of their practical application are shown. Also, a role of chromium as a modifier in kinetics of the formation of ordered phases is determined. Among the research method used, Mössbauer spectroscopy for the determination of hyperfine structure parameters was adopted. These parameters, sensitive to changes in spin and charge electron densities in the nearest neighbourhood of a Mössbauer isotope nucleus, caused by specific configurations of atoms, are directly connected with the degree of ordering of a compound. Spectral analysis has been carried out using the authors' software developed based on a theoretical model relating the shape of a Mössbauer spectrum to the sample microstructure. It has been shown that Mössbauer spectroscopy enables quantitative evaluation of the degree of ordering of phases occurring in samples characterized by large graining, in the case of which it is not possible to determine the long-range order parameter by X-ray diffraction.
Źródło:
Nukleonika; 2013, 58, 1; 67-71
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Phase Composition of Urban Soils by X-Ray Diffraction and Mössbauer Spectroscopy Analysis
Autorzy:
Kierlik, P.
Hanc-Kuczkowska, A.
Męczyński, R.
Matuła, I.
Dercz, G.
Powiązania:
https://bibliotekanauki.pl/articles/353120.pdf
Data publikacji:
2019
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
Mössbauer spectroscopy
X-ray diffraction
environmental protection
qualitative phase analysis
topsoil
Opis:
The main purpose of this study was to identify the mineral composition of soil sample taken from the upper layer of topsoil. High absorption of chemical substance is a characteristic for humus-organic layer of topsoil. The source of those substance could be a pollutant emitted to the atmosphere by human activity. The research area includes Upper Silesia region, which is the most industrial region of Poland. In the present study, the phase composition of the top soil separates were analyzed by using X-raydiffraction and Mössbauer spectroscopy. X-ray diffraction analysis revealed the presence of seven mineral phases in the material magnetic separated by lower current (quartz, illite, kaolinite, Fe3+ oxides, hematite, magnetite and pyrite). In case of higher current were identified four phases (quartz, muscovite, kaolinite and K0.94 Na0.06 (AlSi3 O8 )). Mössbauer spectroscopy was used for an extensive analysis of iron-containing phases (pyrrhotite, magnetite, aluminosilicate oxides with Fe3+ and kaolinite/Fe2+ silicate).
Źródło:
Archives of Metallurgy and Materials; 2019, 64, 3; 1029-1032
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-4 z 4

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