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    Wyświetlanie 1-6 z 6
    Tytuł:
    The effect of NaCl concentration on the interaction energy between feldspar minerale
    Autorzy:
    Güven, Onur
    Can, Muhammed Fatih
    Karagüzel, Cengiz
    Powiązania:
    https://bibliotekanauki.pl/articles/2146939.pdf
    Data publikacji:
    2022
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    DLVO
    albite
    microcline
    NaCl
    Opis:
    The impact of the usage of monovalent ion concentration on the selective flotation of feldspar minerals has been receiving more attention in recent years. Although many experimental studies have been reported to justify its contribution to their flotation recovery, the effect of particle-particle interaction with theoretical calculations has rarely been studied. The objective of this study was, therefore, to explain the effect of monovalent ion concentration (in particular NaCl) on interactions between albite and microcline particles with a theoretical model based on the classical DLVO. The theoretical modeling results suggested that controlling the monovalent ion concentration not only adjusts the energy barrier between particles but also can be used to determine the critical salt concentration for further tests.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2022, 58, 5; art. no. 151031
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Interaction between mineral particles during ascharite flotation process and direct force measurement using AFM
    Autorzy:
    Li, Z.
    Han, Y.
    Li, Y.
    Gao, P.
    Powiązania:
    https://bibliotekanauki.pl/articles/110122.pdf
    Data publikacji:
    2017
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    ascharite
    serpentine
    quartz
    interaction
    AFM
    DLVO
    Opis:
    Interaction between mineral particles during ascharite flotation was investigated by flotation, zeta potential, Derjaguin-Landau-Verwey-Overbeek (DLVO) theory, atomic force microscope (AFM) and SEM-EDS tests. Flotation results showed that the ascharite recovery decreased significantly in the presence of serpentine. In order to improve the ascharite recovery, negative charged quartz was used to limit the detrimental effect of serpentine on ascharite flotation in this research. The effect of quartz on improving ascharite recovery was attributed to the particle surface interactions. The DLVO theory was applied to study the particles interaction in the aqueous solution. The fitting curves showed that serpentine could attach to the surface of quartz easily, and quartz would be well dispersed with ascharite. Therefore, quartz can improve the ascharite flotation performance effectively by interaction between particles. Zeta potential tests showed the opposite charges on the surfaces of mineral particles, which was the basic reason leading to particles interaction. The force measurement results of AFM indicated that the attraction force existed between serpentine and ascharite, as well as serpentine and quartz, but the force between quartz and ascharite was repulsive. The DLVO theory was in a good agreement with the results of AFM. Eventually, particles coating were observed by SEM-EDS, which supported the results of DLVO theory and AFM measurements. During the flotation process, addition of quartz would lead to attachment of serpentine to the quartz surface, so the adverse effect of serpentine on decreasing floatability of ascharite was weakened.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2017, 53, 2; 1161-1174
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Exploring the effect of sodium hexametaphosphate in coal slime flotation
    Autorzy:
    Lu, Tianshen
    Deng, Zhengbin
    Tang, Yun
    Tang, Haiwen
    Powiązania:
    https://bibliotekanauki.pl/articles/2200344.pdf
    Data publikacji:
    2023
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    sodium hexametaphosphate
    coal slime
    flotation
    DLVO
    Opis:
    In this paper, the influence of sodium hexametaphosphate (SHMP) in coal slime flotation was studied, and the interaction between SHMP and coal slime flotation particles was revealed through XRD test, contact angle measurement, zeta potential test, scanning electron microscopy analysis, XPS analysis, and DLVO theoretical calculation. The experimental results show that when the dosage of SHMP is 1500 g/t, the recovery rate of clean coal combustibles increases by 9.61 %. SHMP reduces the hydrophobicity of clay minerals (kaolinite) in coal slime flotation and also enhances the dispersibility of coal slime particle. Scanning electron microscopy and energy dispersive analysis showed that SHMP reduced the number of clay particles (kaolinite) on the coal surface, thereby reducing the ash content of the clean coal. In this paper, SHMP is mainly used to modify the surface of kaolinite so as to reduce the hydrophobicity of the mineral, that is, to improve the recovery rate of clean coal combustibles in coal slime flotation.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2023, 59, 1; art. no. 162075
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Improved flotation of heat treated lignite with saline solutions containing mono and multivalent ions
    Autorzy:
    Ozdemir, O.
    Ersoy, O. F.
    Guven, O.
    Turgut, H.
    Cinar, M.
    Çelik, M. S.
    Powiązania:
    https://bibliotekanauki.pl/articles/109640.pdf
    Data publikacji:
    2018
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    flotation
    heat treatment
    lignite
    DLVO
    Saline Solutions
    Opis:
    Flotation of lignites is inherently difficult. However, pre-heat treatment of coal is also known to make coal surfaces more hydrophobic possibly through removal of water entrapped in the structure of coal. In this context, the objective of this study was, therefore, to determine changes in the hydrophobicity of some lignites under moderately controlled heat treatment and correlate the flotation response of lignites in different salt solutions of NaCl, KCl, CaCl2, and MgCl2 without using any reagent. The results of flotation tests suggested that under the present test conditions, it was possible to float thermally pre-treated lignite samples of partially hydrophobic character in salt solutions in the absence of collector and frother. In addition, the effect of heat treatment on hydrophobicity, and in turn flotation was explained by a theoretical model based on extended DLVO interactions to quantify the effects of both heat treatment and salt concentration on bubble-particle interactions. The results of theoretical modeling suggested that the removal of hydrogen containing groups from coal surfaces significantly contribute to the electrical double layer and hydrophobic forces that govern the magnitude of energetic barrier and also the extent of bubble-particle attachment.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2018, 54, 4; 1070-1082
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Diffuse-layer surface potentials of colemanites mined in Turkey
    Autorzy:
    Senol-Arslan, Dilek
    Drelich, Jaroslaw W.
    Powiązania:
    https://bibliotekanauki.pl/articles/2146938.pdf
    Data publikacji:
    2022
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    colemanite
    surface potential
    atomic force microscopy
    boron
    DLVO
    Opis:
    Colemanite crystal specimens were handpicked at Kestelek, Emet (Hisarcik, Espey), Bigadic mines in Turkey for characterization of their composition and surface potential. X-ray diffraction analysis revealed no differences in mineralogical makeup of the crystals, but elemental analysis indicated differences in the type of trace (<0.1 wt%) elements. Zeta potential measurements showed small differences in zeta potential values, with isoelectric points (iep) varying from about pH = 9.6 to pH = 10.2. However, no correlation was found between iep and the type of trace elements. Additionally, atomic force microscopy (AFM) was employed to measure the colloidal interactions between a silicon nitride (Si3N4) cantilever tip and colemanite crystal surfaces in 1 wt% colemanite-saturated aqueous solutions at three different pHs (8.4, 9.4 and 11). The Derjaguin-Landau-Verwey-Overbeek theory (DLVO) was applied to examine the AFM tip interactions with colemanite surfaces in an aqueous solution of colemanite saturated solutions. The results revealed attractive forces at pH = 8.4 and 9.4 and repulsive forces at pH = 11, confirming the location of an isoelectric point for colemanite specimens somewhere between pH = 9.5 and pH = 10.1. Theoretical analysis of the force curves using the DLVO theory allowed for assessment of both surface charge density and surface potential for colemanite specimens used in this study.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2022, 58, 5; art. no. 151933
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Effect of flow structure and colloidal forces on aggregation rate of small solid particles suspended in aqueous solutions
    Autorzy:
    Tyl, Grzegorz
    Kondracki, Juliusz
    Jasińska, Magdalena
    Powiązania:
    https://bibliotekanauki.pl/articles/2086810.pdf
    Data publikacji:
    2021
    Wydawca:
    Polska Akademia Nauk. Czytelnia Czasopism PAN
    Tematy:
    aggregation
    shear flow
    DLVO
    particles
    colloidal forces
    population balance
    zbiór
    przepływ ścinający
    cząstki
    siły koloidalne
    bilans populacji
    Opis:
    In this paper aggregation of small solid particles in the perikinetic and orthokinetic regimes is considered. An aggregation kernel for colloidal particles is determined by solving the convection-diffusion equation for the pair probability function of the solid particles subject to simple shear and extensional flow patterns and DLVO potential field. Using the solution of the full model the applicability regions of simplified collision kernels from the literature are recognized and verified for a wide range of Péclet numbers. In the stable colloidal systems the assumption which considers only the flow pattern in a certain boundary layer around central particle results in a reasonable accuracy of the particle collision rate. However, when the influence of convective motion becomes more significant one should take into account the full flow field in a more rigorous manner and solve the convection-diffusion equation directly. Finally, the influence of flow pattern and process parameters on aggregation rate is discussed.
    Źródło:
    Chemical and Process Engineering; 2021, 42, 4; 369--389
    0208-6425
    2300-1925
    Pojawia się w:
    Chemical and Process Engineering
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
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