- Tytuł:
-
D-Rybono-1,4-lakton. Część 2, Wykorzystanie w syntezie organicznej – wybrane reakcje
D-Ribono-1,4-lactone. Part 2, Use in organic synthesis – selected reactions - Autorzy:
-
Madaj, J.
Samaszko-Fiertek, J.
Ślusarz, R.
Dmochowska, B. - Powiązania:
- https://bibliotekanauki.pl/articles/171521.pdf
- Data publikacji:
- 2017
- Wydawca:
- Polskie Towarzystwo Chemiczne
- Tematy:
-
D-Rybono-1,4-lakton
C-glikozydy
analogi nukleozydów
neplanocyna
D-ribono-1,4-lactone
C-glycosides
nucleosides analogs
neplanocin - Opis:
- There are many examples of syntheses with d-ribono-1,4-lactone as a substrate. Among all, its biggest advantage is undoubtedly its accessibility. It can be synthesized on a large scale from naturally available raw materials. Its characteristic feature is the stable configuration of individual carbon atoms in multiple reaction conditions. Very important is the presence of a carbonyl moiety, allowing for a variety of additions which is crucial for carbon-carbon bond formation, the most difficult synthesis in organic chemistry. In this article we present selected examples of articles that were published after 1984. In this year, the second article describing the Use of d-Ribonolactone in Organic Synthesis [36] was published. After this time many articles describing the use of the entitled lactone as a substrate in organic synthesis were published. We thought it would be worthwhile to present in Polish a selection of them. C-Glycosides and nucleoside analogs are a particularly important type of synthesized products. Examples of their synthesis are presented in this work, namely, neplanocin A [5], B [31] and F [24], citreovirdin [14], 2-bromopyridin α- and β-d-ribofuranosides [10], 4-deazaformicin A [27] and varitriol [ 33].
- Źródło:
-
Wiadomości Chemiczne; 2017, 71, 11-12; 861-885
0043-5104
2300-0295 - Pojawia się w:
- Wiadomości Chemiczne
- Dostawca treści:
- Biblioteka Nauki
Artykuł