- Tytuł:
- Paramagnetic Centres in Coal Macerals
- Autorzy:
-
Słowik, G.
Więckowski, A. - Powiązania:
- https://bibliotekanauki.pl/articles/1536501.pdf
- Data publikacji:
- 2010-09
- Wydawca:
- Polska Akademia Nauk. Instytut Fizyki PAN
- Tematy:
-
61.66.Hq
76.30.Rn
89.30.ag - Opis:
- The electron paramagnetic resonance (EPR) study of coal macerals: exinite, vitrinite and inertinite separated from clarain of the Polish medium-rank coal with carbon content of 85.6 wt% C, were performed. Using the continuous microwave saturation technique (measurements at 223 K and 291 K), as a result of numerical analysis of recorded EPR spectra of exinite, vitrinite and inertinite, their multi-component structure was shown. The EPR spectra of exinite and vitrinite consist of three component lines: one Gaussian G and two Lorentzians: L1 and L3. The EPR spectra of inertinite consist of two narrow lines with Lorentzian line shape L2 and L3. Temperature measurements of studied coal macerals in the range 100-373 K were done. It was evidenced that, in group of paramagnetic centres responsible for Lorentzian L1 component line, paramagnetic centres with thermally excited triplet states (S = 1) exist. Existence of paramagnetic centres with thermally excited triplet states was not observed in inertinite.
- Źródło:
-
Acta Physica Polonica A; 2010, 118, 3; 507-510
0587-4246
1898-794X - Pojawia się w:
- Acta Physica Polonica A
- Dostawca treści:
- Biblioteka Nauki
Artykuł