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Wyświetlanie 1-5 z 5
Tytuł:
Water Bound in Elytra of the Weevil Liparus glabrirostris (Küster, 1849) by NMR and Sorption Isotherm (Coleoptera: Curculionidae)
Autorzy:
Harańczyk, H.
Florek, M.
Nowak, P.
Knutelski, S.
Powiązania:
https://bibliotekanauki.pl/articles/1490163.pdf
Data publikacji:
2012-02
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
82.56.Na
Opis:
Scanning electron microscopy micrograms of the elytra of Liparus glabrirostris showed a different dorsal and ventral surface and a multilayered inner structure. Hydration kinetics, sorption isotherm, and proton free induction decays are measured for hydrated elytra of the weevil species Liparus glabrirostris (Coleoptera: Curculionidae) in the atmosphere with controlled humidity. Very tightly bound water fraction with the mass Δ m/$m_0$ = 0.037 ± 0.004, and very short hydration time, tightly bound water Δ m/$m_0$ = 0.034 ± 0.009, and hydration time $t_1^{h}$ = (3.31 ± 0.93) h, and finally loosely bound water fraction with $t_2^{h}$ = (25.5 ± 7.8) h were distinguished. The sorption isotherm is sigmoidal in form, with the mass of water saturating primary water binding sites equal of Δ M/$m_0$ = 0.036. The proton free induction decays show the presence of solid signal (well fitted by a Gaussian function) from elytra ($T_{2G}$* ≈ 18 μs), the immobilized water fraction ($T_{2L_1}$* ≈ 120 μs) and mobile water pool ($T_{2 L_2}$* ≈ 300 μs). The hydration dependence of the water bound in elytra of L. glabrirostris, L/S is linear showing the absence of water-soluble solid fraction and negligible content of water pool "sealed" in pores of the structure.
Źródło:
Acta Physica Polonica A; 2012, 121, 2; 491-496
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Initial Phases of DNA Rehydration by NMR and Sorption Isotherm
Autorzy:
Harańczyk, H.
Czak, J.
Nowak, P.
Nizioł, J.
Powiązania:
https://bibliotekanauki.pl/articles/1539094.pdf
Data publikacji:
2010-02
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
82.56.Na
Opis:
T*he initial stages of rehydration of salmon sperm deoxyribonucleic acid (DNA) lyophilizates were observed using hydration kinetics, sorption isotherm, and high power proton relaxometry (at 30 MHz). T*he hydration kinetics reveals (i) a very tightly bound water not removed by incubation over silica gel ($A_0^{h}$ = 0.057 ± 0.010), (ii) a tightly bound water [saturating at $A_1^{h}$ = 0.149 ± 0.007, hydration time $t_1^{h}$ = (0.27 ± 0.08) h], a tightly bound water (iii) [saturating at $A_2^{h}$ = 0.694 ± 0.039, with the hydration time $t_2^{h}$ = (9.8 ± 3.2) h], and (iv) a loosely bound water fraction for the samples hydrated at p/$p_{0}$ ≥ 76% [with the hydration time $t_3^{h}$ = (44 ± 14) h, and the contribution progressively increasing with the air humidity]. For the hydration at p/$p_{0}$ = 100%, after $t_{0}$ = (244 ± 22) h of incubation the swelling process begins. T*he amount of additional water uptake at swelling depended on the macrostructure of the sample. Sorption isotherm is sigmoidal in form and is fitted well by the Dent model with the mass of water saturating primary binding sites Δ M/$m_{0}$ = 0.114. Proton free induction decay is a superposition of the immobilized proton signal (Gaussian, with $T_{2S}^\ast$ ≈ 20 μs) and two liquid signal components coming from tightly bound ($T_{2L_1}^\ast$ ≈ 100 μs, with the mass saturating at Δ m/$m_{0}$ = 0.111 ± 0.044) and loosely bound water fraction (with the amplitude proportional to the mass of water added).
Źródło:
Acta Physica Polonica A; 2010, 117, 2; 397-402
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Initial Phases of Antarctic Ramalina terebrata Hook f. & Taylor Thalli Rehydration Observed by Proton Relaxometry
Autorzy:
Harańczyk, H.
Pater, Ł.
Nowak, P.
Bacior, M.
Olech, M.
Powiązania:
https://bibliotekanauki.pl/articles/1490119.pdf
Data publikacji:
2012-02
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
82.56.Na
Opis:
Hydration kinetics, sorption isotherm, and proton free induction decays are measured for Ramalina terebrata thalli rehydrated from gaseous phase. Very tightly, tightly, and loosely bound water fractions are distinguished. Sorption isotherm is sigmoidal in form with the mass of water saturating primary water binding sites equal to Δ m/$m_0$ = 0.046. Proton free induction decays show the presence of immobilized water fraction ($T_{2 L_1}$* ≈ 100 μs) and mobile water pool ($T_{2 L_2}$* ≈ 330 μs). Sorption isotherm fitted to the NMR data shows the absence of water fraction "sealed" in pores of dry thallus.
Źródło:
Acta Physica Polonica A; 2012, 121, 2; 480-484
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The Effect of Mild Rehydration on Freeze-Dried Dipalmitoylphosphatidylcholine (DPPC) Multilamellar Membranes as Observed by Proton NMR and Sorption Isotherm
Autorzy:
Harańczyk, H.
Leja, A.
Nowak, P.
Baran, E.
Strzałka, K.
Powiązania:
https://bibliotekanauki.pl/articles/1398809.pdf
Data publikacji:
2016-02
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
82.56.Na
87.16.D-
Opis:
Between neighbouring bilayers of lyophilized dipalmitoylphosphatidylcholine (DPPC) multilamellar vesicles the total number of water molecules equals 9 H₂O molecules/1 DPPC molecule. One of these molecules is very tightly bound to the lipid molecule, seven are in immobilized (tightly bound) water fraction whereas the last one belongs to mobile water fraction. The rehydration from the gaseous phase of the DPPC model membranes was investigated using hydration kinetics, sorption isotherm, and high power proton relaxometry. The obtained data for DPPC were compared with these obtained for wheat photosynthetic membranes. Rehydrated photosynthetic membranes differ from DPPC model membranes in hydration kinetics. The average hydration time has a similar value: (22.0 ± 2.8) h (photosynthetic membrane) and (19.8 ± 1.6) h (DPPC), however hydration kinetics was described by one-exponential function for photosynthetic membrane, while for model membrane it shows fine double exponential form. The sigmoidal form of sorption isotherm is better fitted using Dent model than by the Brunauer-Emmett-Teller formula. The Brunauer-Emmett-Teller/Dent deviation parameter b =0.93 either for photosynthetic or for model membranes. The mass of water saturating primary water binding sites equals ΔM/m₀= 0.017 (wheat photosynthetic membranes) and 0.027 (DPPC). The detected by NMR-isotherm study mass of water "sealed" in model membrane structures was about ΔMₛ/m₀=0.182 (about 7-8 H₂O molecules/1 DPPC molecule), and ΔMₛ/m₀= 0.066 for photosynthetic membrane.
Źródło:
Acta Physica Polonica A; 2016, 129, 2; 179-184
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Rehydration of CTMA Modified DNA Powders Observed by NMR
Autorzy:
Harańczyk, H.
Kobierski, J.
Zalitacz, D.
Nowak, P.
Romanowicz, A.
Marzec, M.
Nizioł, J.
Hebda, E.
Pielichowski, J.
Powiązania:
https://bibliotekanauki.pl/articles/1490149.pdf
Data publikacji:
2012-02
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
82.56.Na
Opis:
The rehydration of salmon sperm deoxyribonucleic acid (DNA) and cetyltrimethylammonium chloride $(C_{19}H_{42}ClN)$ complexes was observed using hydration kinetics, sorption isotherm, and high power proton relaxometry (at 30 MHz). The hydration kinetics shows (i) a very tightly bound water not removed by incubation over silica gel ($A_0^{h}$ = 0.061 ± 0.004), (ii) a tightly bound water saturating at $A_1^{h}$ = 0.039 ± 0.011, with the hydration time $t_1^{h}$ = (1.04 ± 0.21) h, a loosely bound water fraction (iii) with the hydration time $t_2^{h}$ = (19.1 ± 3.2) h and the contribution progressively increasing with the air humidity. For the hydration at $p//p_0$ = 100%, after $t_0$ = (152.6 ± 2.5) h of incubation the swelling process begins. The swelling time was $t_3^{h}$ = (12.5 ± 5.4) h, and the swelling amplitude $A_3^{h}$ = 0.140 ± 0.016. The sorption isotherm is sigmoidal in form and is fitted by the Dent model with the mass of water saturating primary binding sites Δ M/$m_0$ = 0.102 ± 0.021. Proton free induction decay is a superposition of the immobilized proton signal (Gaussian, with $T_{2S}$* ≈ 30 μs) and two liquid signal components coming from tightly bound ($T_{2 L_1}$* ≈ 100 μs) and loosely bound water fraction with the amplitude proportional to the mass of water added ($T_{2 L_2}$* ≈ 1000 μs).
Źródło:
Acta Physica Polonica A; 2012, 121, 2; 485-490
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-5 z 5

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