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Wyszukujesz frazę "Dede, B." wg kryterium: Autor


Wyświetlanie 1-2 z 2
Tytuł:
Novel metal(II) complexes with bidentate Schiff base ligand: Synthesis, spectroscopic properties and dye decolorization functions
Autorzy:
Karakaya, C.
Dede, B.
Cicek, E.
Powiązania:
https://bibliotekanauki.pl/articles/1065151.pdf
Data publikacji:
2016-02
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
81.20.Ka
82.80.-d
89.60.-k
Opis:
The bidentate Schiff base ligand 4-chloro-2-[1-(4-phenylphenyl)ethylideneamino]phenol and its mononuclear Co(II), Ni(II), Cu(II) and Zn(II) complexes have been synthesized. Ligand and metal complexes were characterized by elemental analyses, magnetic susceptibility, molar conductivity, ¹H- and ¹³C-NMR, the Fourier transform infrared, UV-Vis, inductively coupled plasma optical emission spectrometry, and thermogravimetric-differential thermogravimetric studies. The results suggest that the mononuclear complexes have a metal to ligand mole ratio of 1:2 and the metal(II) ions are coordinated with the phenolic oxygen and imine nitrogen atoms. Octahedral structures are proposed for the complexes of the Schiff base ligand. Furthermore, the complexes were checked for their efficiency to decolorize the dye methylene blue. In our experiments we found that metal(II) complexes had an acceptable decolorization efficiency against the dye methylene blue.
Źródło:
Acta Physica Polonica A; 2016, 129, 2; 208-212
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Synthesis, Characterization of Novel Dinuclear Co(II)-Cu(II) Complexes and Investigation of Their Catecholase and Catalase-Like Activities
Autorzy:
Dede, B.
Cicek, E.
Karipcin, F.
Powiązania:
https://bibliotekanauki.pl/articles/1398819.pdf
Data publikacji:
2016-02
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
81.20.Ka
82.80.-d
87.15.R-
Opis:
The purpose of this study is synthesis, characterization and enzyme activity functions of novel dinuclear metal complexes. Therefore two new dinuclear heterometallic cobat(II)-copper(II) complexes have been synthesized and structurally characterized by using Fourier transform infrared method, elemental analysis, inductively coupled plasma optical emission spectrometry, molar conductivity, magnetic moment measurements and thermal analysis. Spectroscopic and stoichiometric data of the metal complexes indicated that the metal:ligand ratio of the complexes were found to be 2:1. Both of the complexes are 1:2 electrolytes as shown by their molar conductivities and paramagnetism. The subnormal magnetic moment values of the dinuclear complexes were explained by an antiferromagnetic interaction. Additionally complexes were each tested both for their ability to oxidation reaction of 3,5-di-tert-butylcatechol to the 3,5-di-tert-butyl-o-benzoquinone presence of O₂ and catalyse the disproportionation of hydrogen peroxide in the presence of the added base imidazole. It was found that both of the complexes exhibited good catecholase and catalase-like enzyme activity.
Źródło:
Acta Physica Polonica A; 2016, 129, 2; 203-207
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-2 z 2

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