- Tytuł:
- Crystal structure and EPR investigation of pyrazinamide containing copper (II) 2-nitrobenzoate single crystal
- Autorzy:
-
Çelik, Y.
Bozkurt, E.
Karabulut, B.
Dege, N. - Powiązania:
- https://bibliotekanauki.pl/articles/1070369.pdf
- Data publikacji:
- 2016-07
- Wydawca:
- Polska Akademia Nauk. Instytut Fizyki PAN
- Tematy:
-
61.05.cp
75.10.Dg
76.30.-v
78.30.-j - Opis:
- The crystal structure and paramagnetism in the pyrazinamide containing copper(II) 2-nitrobenzoate single crystal were investigated using X-ray diffraction, Fourier-transform infrared spectroscopy, and electron paramagnetic resonance techniques. X-ray diffraction analysis shows that the complex crystallizes in monoclinic system having two molecules in the unit cell. After using curve fitting method to the electron paramagnetic resonance spectra, anisotropic g and hyperfine A tensors were obtained. The local symmetry, spin Hamiltonian parameters, and molecular bonding coefficients of the paramagnetic Cu²⁺ ion were determined. Perturbation approach was applied to the spin Hamiltonian to calculate the g and A values.
- Źródło:
-
Acta Physica Polonica A; 2016, 130, 1; 163-166
0587-4246
1898-794X - Pojawia się w:
- Acta Physica Polonica A
- Dostawca treści:
- Biblioteka Nauki
Artykuł