- Tytuł:
- EPR Spectra of the Genuine-Organic and Metal-Organic TCNQ-Based Anion Radical Salts
- Autorzy:
-
Botko, M.
Čižmár, E.
Kajňaková, M.
Feher, A. - Powiązania:
- https://bibliotekanauki.pl/articles/1368637.pdf
- Data publikacji:
- 2014-07
- Wydawca:
- Polska Akademia Nauk. Instytut Fizyki PAN
- Tematy:
-
75.50.Xx
76.30.-v - Opis:
- We have measured the electron paramagnetic resonance spectra of genuine-organic anion-radical salts $[Me-2,6-di-Me-Py](TCNQ)_{2}$, $[Me-3,5-di-Me-Py](TCNQ)_{2}$, $[N-Me-OH-Me-Py](TCNQ)_{2}$, $[N-Et-OH-Me-Py](TCNQ)_{2}$, and metal-organic anion-radical salt $[Mn-phen_{3}](TCNQ)_{2}$·$H_{2}O$ in the temperature range from 2 K to 300 K in the X-band frequency range. A comparison study of the shape of spectra, g-factors and linewidths with respect to the composition and crystal structure of studied compounds is presented. While the genuine-organic anion-radical salts display a typical EPR response originating from TCNQ pairs, the spectra of metal-organic anion-radical salt are dominated by the contribution of transition metal.
- Źródło:
-
Acta Physica Polonica A; 2014, 126, 1; 252-253
0587-4246
1898-794X - Pojawia się w:
- Acta Physica Polonica A
- Dostawca treści:
- Biblioteka Nauki
Artykuł