- Tytuł:
- Frustrated zig-zag spin chains formed by hydrogen bonds in [Cu(H₂O)(OH)(tmen)]₂[Pd(CN)₄]·2H₂O
- Autorzy:
-
Čižmár, E.
Orendáčová, A.
Orendáč, M.
Kuchár, J.
Feher, A.
Park, J.
Meisel, M. - Powiązania:
- https://bibliotekanauki.pl/articles/1054768.pdf
- Data publikacji:
- 2017-04
- Wydawca:
- Polska Akademia Nauk. Instytut Fizyki PAN
- Tematy:
-
75.30.Et
76.30.-v
75.40.-s - Opis:
- The magnetic properties of the novel dimeric compound [Cu(H₂O)(OH)(tmen)]₂[Pd(CN)₄]·2H₂O (tmen=N,N,N',N'-tetramethylethylenediamine) with modulated crystal structure were studied in the temperature range from 95 mK to 300 K. Magnetic measurements revealed a presence of weak antiferromagnetic exchange coupling in the compound. The temperature dependence of specific heat is characterized by the presence of a Schottky-like maximum at 0.47 K and a λ-anomaly at 0.28 K, indicating the formation of long-range order in the system. The comparison of the experimental data with theoretical predictions revealed the presence of antiferromagnetic intradimer exchange coupling J/k_{B}= -1.2 K and interdimer coupling of a similar strength mediated via hydrogen bonds between dimeric units forming a frustrated magnetic zig-zag chain structure.
- Źródło:
-
Acta Physica Polonica A; 2017, 131, 4; 940-942
0587-4246
1898-794X - Pojawia się w:
- Acta Physica Polonica A
- Dostawca treści:
- Biblioteka Nauki
Artykuł