- Tytuł:
- Angular Distortion around $Cr^{3+}$ Ions Doped Diammonium Hexaaqua Magnesium Sulphate Single Crystal
- Autorzy:
-
Ciresan, M.
Vaida, M.
Avram, N. - Powiązania:
- https://bibliotekanauki.pl/articles/1815473.pdf
- Data publikacji:
- 2007-11
- Wydawca:
- Polska Akademia Nauk. Instytut Fizyki PAN
- Tematy:
-
75.10.Dg
76.30.-v
71.70.Ch - Opis:
- The aim of the present study is to explain the local distortion around $Cr^{3+}$ ions doped in the title crystal using the latest experimental data regarding optical and EPR spectra. We calculated $g_ǁ$, $g_⊥$, and D spin-Hamiltonian parameter as function of angle between the $C_3$ axis and metal-ligand chemical bond in local distorted octahedral cluster $[CrO_6]^{9-}$ formed after doped crystal. The method is based on the single spin-orbit coupling parameter model, in the cluster approach using Macfarlane high order perturbation formulae. The results compared with experimental data give a reasonable agreement.
- Źródło:
-
Acta Physica Polonica A; 2007, 112, 5; 835-839
0587-4246
1898-794X - Pojawia się w:
- Acta Physica Polonica A
- Dostawca treści:
- Biblioteka Nauki
Artykuł