- Tytuł:
- Vibration and Luminescence Spectroscopic Investigations of the Alkali Rare Earth Double Phosphates M$\text{}_{3}$(RE,Eu)(PO$\text{}_{4}$)$\text{}_{2}$ (M=K, Rb; RE=La, Gd)
- Autorzy:
-
Kloss, M.
Schwarz, L.
Hölsä, J. P. K. - Powiązania:
- https://bibliotekanauki.pl/articles/1995573.pdf
- Data publikacji:
- 1999-03
- Wydawca:
- Polska Akademia Nauk. Instytut Fizyki PAN
- Tematy:
-
61.50.-f
61.66.Fn
63.20.-e
71.20.Dg
71.20.Eh
71.70.-d
78.30.-j
78.55.-m - Opis:
- The room temperature IR- and Raman spectra of the different M$\text{}_{3}$RE(PO$\text{}_{4}$)$\text{}_{2}$ (M = K, Rb; RE = La, Eu, Gd) double phosphates were analysed and used to interpret the vibronic side band structure in the photoluminescence spectra. The intraconfigurational 4f-4f electronic transitions in the photoluminescence spectra of the Eu$\text{}^{3+}$ doped M$\text{}_{3}$RE(PO$\text{}_{4}$)$\text{}_{2}$ were analysed in detail. The crystal field fine structure of the $\text{}^{5}$D$\text{}_{0}$ → $\text{}^{7}$F$\text{}_{J}$ (J=0-4) transitions was analysed accounting for the information on the crystal structure. The effect of the temperature as well as the alkali host cation was evaluated. Finally, a preliminary crystal field energy level scheme for the $\text{}^{7}$F$\text{}_{J}$ (J=0-4) ground term was deduced from the analysis of the photo-luminescence as well as IR- and Raman spectra.
- Źródło:
-
Acta Physica Polonica A; 1999, 95, 3; 343-349
0587-4246
1898-794X - Pojawia się w:
- Acta Physica Polonica A
- Dostawca treści:
- Biblioteka Nauki
Artykuł