- Tytuł:
- Low Temperature Crystal Structure Behaviour of Complex Yttrium Aluminium Oxides YAlO_3 and Y_3Al_5O_{12}
- Autorzy:
-
Senyshyn, A.
Vasylechko, L. - Powiązania:
- https://bibliotekanauki.pl/articles/1399474.pdf
- Data publikacji:
- 2013-08
- Wydawca:
- Polska Akademia Nauk. Instytut Fizyki PAN
- Tematy:
-
61.66.Fn
61.05.F-
65.40.De
65.60.+a
63.70.+h - Opis:
- Crystal structures of two yttrium aluminium oxides, namely $YAlO_3$ and $Y_3Al_5O_{12}$, were investigated in the temperature range 3.4-300 K by high-resolution neutron powder diffraction. Neither traces of phase transformations nor discontinuous changes of physical properties were observed. Thermal expansion of yttrium aluminium oxides was evaluated in terms of 1st order Grüneisen approximation, where the Debye temperatures and the Grüneisen parameters have been estimated for both compositions. Anomalies in the thermal expansion of yttrium aluminium perovskite have been observed and modelled using the Einstein oscillator with negative Grüneisen parameter. Extended bond length analysis revealed significant thermally-driven modifications of the aluminium-oxygen framework.
- Źródło:
-
Acta Physica Polonica A; 2013, 124, 2; 329-335
0587-4246
1898-794X - Pojawia się w:
- Acta Physica Polonica A
- Dostawca treści:
- Biblioteka Nauki