- Tytuł:
- Defect Mode in $LaB_{6}$
- Autorzy:
-
Anisimov, M.
Bogach, A.
Glushkov, V.
Demishev, S.
Samarin, N.
Gavrilkin, S.
Mitsen, K.
Shitsevalova, N.
Levchenko, A.
Filippov, V.
Gabani, S.
Flachbart, K.
Sluchanko, N. - Powiązania:
- https://bibliotekanauki.pl/articles/1371551.pdf
- Data publikacji:
- 2014-07
- Wydawca:
- Polska Akademia Nauk. Instytut Fizyki PAN
- Tematy:
- 65.40.Ba
- Opis:
- The specific heat of high quality $La^{N}B_{6}$ (N=10, 11, natural) single crystals is investigated in a wide range of temperatures 2 - 300 K. The obtained data allow to estimate correctly (i) the electronic γ· T term of specific heat (γ ≈ 2.4 mJ/(mol·$K^{2}$)), (ii) the contribution from quasilocal vibrating mode of $La^{3+}$ ions ($Θ_{E}$ ≈ 150 - 152 K), (iii) the Debye-type term from rigid boron cages ($Θ_{D}$ ≈ 1160± 40 K). Our data also suggest an additional defect-mode component (iv) which may be attributed to a contribution of 1.5% boron vacancies in $LaB_{6}$. The obtained results may be interpreted in terms of formation of two level systems, which appear when $La^{3+}$ ions are displaced from their centrosymmetric positions in the cavities of rigid boron cages, apart from randomly distributed boron vacancies in the $LaB_{6}$ matrix.
- Źródło:
-
Acta Physica Polonica A; 2014, 126, 1; 350-351
0587-4246
1898-794X - Pojawia się w:
- Acta Physica Polonica A
- Dostawca treści:
- Biblioteka Nauki
Artykuł