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    Wyświetlanie 1-4 z 4
    Tytuł:
    Groups of Paramagnetic Centres in Reduced and Methylated Low Rank Coal
    Autorzy:
    Pilawa, B.
    Wachowska, H.
    Kozłowski, M.
    Więckowski, A.
    Najder-Kozdrowska, L.
    Powiązania:
    https://bibliotekanauki.pl/articles/1401865.pdf
    Data publikacji:
    2015-09
    Wydawca:
    Polska Akademia Nauk. Instytut Fizyki PAN
    Tematy:
    33.35.+r
    61.66.Hq
    76.30.-v
    76.30.Rn
    89.30.ag
    Opis:
    Low rank Illinois No. 6 coal was studied by electron paramagnetic resonance EPR spectroscopy. The parameters of EPR spectra (spectroscopic splitting factors g, linewidths $\DeltaB_{pp}$, concentrations of paramagnetic centres N) were measured for row and chemically treated coal (demineralized, reduced and methylated samples). The multi-component structure of experimental spectra of this coal was proved. Two groups of paramagnetic centres responsible for broad Lorentzian 1 and narrow Lorentzian 2 lines exist in studied samples. Paramagnetic centres connected with component lines revealed different behaviour during chemical treatments.
    Źródło:
    Acta Physica Polonica A; 2015, 128, 3; 264-267
    0587-4246
    1898-794X
    Pojawia się w:
    Acta Physica Polonica A
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    EPR characteristics of activated carbon for hydrogen production by the thermo-catalytic decomposition of methane
    Autorzy:
    Więckowski, A.
    Najder-Kozdrowska, L.
    Rechnia, P.
    Malaika, A.
    Krzyżyńska, B.
    Kozłowski, M.
    Powiązania:
    https://bibliotekanauki.pl/articles/1158900.pdf
    Data publikacji:
    2016-09
    Wydawca:
    Polska Akademia Nauk. Instytut Fizyki PAN
    Tematy:
    33.35.+r
    61.66.Hq
    76.30.-v
    82.30.Lp
    82.65.+r
    88.30.ej
    Opis:
    The electron paramagnetic resonance (EPR) method was used to characterize samples of activated coal before and after reactions of the catalytic decomposition of methane and ethanol at temperatures of 1023 K (750°C), 1123 K (850°C) and 1223 K (950°C). The EPR parameters: spectroscopic splitting factor g, peak-to-peak linewidth ΔBₚₚ, and spin concentration c were measured. During the ethanol-assisted catalytic decomposition of methane carbon-located-spin radicals are partially transformed into oxygen-located-spin radicals.
    Źródło:
    Acta Physica Polonica A; 2016, 130, 3; 701-704
    0587-4246
    1898-794X
    Pojawia się w:
    Acta Physica Polonica A
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    EPR Study of Gamma Irradiated Cholestanone Single Crystal
    Autorzy:
    Caliskan, B.
    Powiązania:
    https://bibliotekanauki.pl/articles/1206732.pdf
    Data publikacji:
    2014-01
    Wydawca:
    Polska Akademia Nauk. Instytut Fizyki PAN
    Tematy:
    87.64.kh
    87.80.Lg
    61.72.Hh
    33.35.+r
    76.30.Rn
    32.10.Fn
    33.15.Pw
    71.18.+y
    76.30.-v
    61.82.Pv
    61.72.-y
    Opis:
    Cholestanone ($C_{27}H_{46}O$) single crystals were irradiated with ⁶⁰Co-γ rays at room temperature. The spectra were recorded for different orientations of the crystal in the magnetic field at 120 K using the EPR technique. Radiation damage center was attributed to $CHCH_2CH_2$ radical. The principal values of the hyperfine coupling tensor of the unpaired electron with the protons and the principal values of the g tensor were determined. The results were found to be in good agreement with the existing literature.
    Źródło:
    Acta Physica Polonica A; 2014, 125, 1; 135-138
    0587-4246
    1898-794X
    Pojawia się w:
    Acta Physica Polonica A
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Optimization of Antioxidant Properties of Creams with Berry Extracts by Artificial Neural Networks
    Autorzy:
    Makarova, K.
    Zawada, K.
    Wagner, D.
    Skowyra, J.
    Powiązania:
    https://bibliotekanauki.pl/articles/1030222.pdf
    Data publikacji:
    2017-07
    Wydawca:
    Polska Akademia Nauk. Instytut Fizyki PAN
    Tematy:
    07.05.Mh
    33.35.+r
    61.72.Hh
    76.30.-v
    87.64.kh
    87.80.Lg
    Opis:
    Oxidative stress and the excess of free radicals accelerate the ageing process of human skin. The application of skin cream with antioxidant compounds could reduce the damage caused by free radicals. In this work we studied two types of skin creams with extracts from aronia (Aronia melanocarpa), elderberry (Sambucus nigra) and bilberry (Vaccinium myrtillus) because of their high content of anthocyanins, i.e. strong natural antioxidants. The 2,2-diphenyl-1-picrylhydrazyl (DPPH) radical scavenging ability of the skin creams with berry extracts were studied with ESR spectroscopy. The artificial neural networks were applied to optimize the berry extract concentration and storage time for oil-in-water and water-in-oil creams. Based on experimental results chokeberry and elderberry extracts in oil-in-water cream base revealed higher DPPH radical scavenging ability than in the corresponding water-in-oil. Artificial neural networks predicts maxima of DPPH radical scavenging for 1-week stored elderberry (2.23 mg DPPH/g) and 1-week stored chokeberry (5.84 mg DPPH/g) and bilberry (5.26 mg DPPH/g) 0.76% extracts in oil-in-water creams. The maxima of DPPH radical scavenging for water-in-oil creams were predicted for 6-week stored 0.8% aronia extract, freshly prepared 0.76% bilberry extract and 1-week stored 0.56% elderberry extract. The artificial neural networks predicted values are in good agreement with the experimental values. DPPH-EPR could be combined with artificial neural networks to optimize the extract concentration, and the type of cream base as well as to predict the effect of storage based on a limited number of experiments and samples.
    Źródło:
    Acta Physica Polonica A; 2017, 132, 1; 44-51
    0587-4246
    1898-794X
    Pojawia się w:
    Acta Physica Polonica A
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
      Wyświetlanie 1-4 z 4

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