- Tytuł:
- Vibrational Corrections to Transition Properties
- Autorzy:
-
Pluta, T.
Sadlej, A. J. - Powiązania:
- https://bibliotekanauki.pl/articles/2014250.pdf
- Data publikacji:
- 2000-10
- Wydawca:
- Polska Akademia Nauk. Instytut Fizyki PAN
- Tematy:
- 33.20.Fb
- Opis:
- The vibrational contributions to second-order transition properties are considered in the framework of the Born-Oppenheimer approximation. It is shown that the usual formula for vibrational second-order transition matrix elements is incomplete and needs to be supplemented by a term of purely vibrational origin. This pure vibrational contribution is calculated for vibrational transition polarizabilities in LiH and BeF and found to be quite significant. Its inclusion in theoretically calculated data for the Raman intensities appears to be necessary.
- Źródło:
-
Acta Physica Polonica A; 2000, 98, 4; 363-371
0587-4246
1898-794X - Pojawia się w:
- Acta Physica Polonica A
- Dostawca treści:
- Biblioteka Nauki
Artykuł