- Tytuł:
- Degradations of 2,4-dichlorophenol and polychlorinated biphenyls with zero valent iron under subcritical conditions. Importance of subcritical water oxidation
- Autorzy:
-
Oh, S.-Y.
Yoon, M.-K. - Powiązania:
- https://bibliotekanauki.pl/articles/207444.pdf
- Data publikacji:
- 2015
- Wydawca:
- Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
- Tematy:
-
chemicals removal
water treatment
degradation
gas chromatography
iron
mass spectrometry
organic pollutants
polychlorinated biphenyls
2,4-dichlorophenol
DCP
polychlorinated biphenyl
PCBs
usuwanie chemikaliów
uzdatnianie wody
degradacja
chromatografia gazowa
żelazo
spektrometria masowa
zanieczyszczenia organiczne
polichlorowane bifenyle
PCB
2,4-dichlorofenol - Opis:
- The abiotic transformations of 2,4-dichlorophenol (DCP) and polychlorinated biphenyls (PCBs) has been examined in the presence and of zero valent iron (Fe(0)) under subcritical conditions. It was found that the degradation of DCP was significantly enhanced, showing complete degradation of DCP in 3 h at 300 °C. Control experiments without Fe(0) indicated that the removal of DCP in the iron–water system was mostly due to subcritical water oxidation and that the enhancement of degradation in the presence of Fe(0) was less significant. Regardless of Fe(0), PCBs were rapidly decomposed, showing 93% destruction in 5 h at 300 °C. Product identification by gas chromatography-mass spectrometry (GC-MS) analysis showed that the reductive transformation of DCP and PCBs w Fe(0) existed under subcritical conditions. Our results suggest that subcritical water degradation may be a possible remediation option to treat DCP and PCBs in water and soil.
- Źródło:
-
Environment Protection Engineering; 2015, 41, 3; 73-86
0324-8828 - Pojawia się w:
- Environment Protection Engineering
- Dostawca treści:
- Biblioteka Nauki
Artykuł