- Tytuł:
- Barium oxide as a modifier to stabilize the γ-Al2O3 structure
- Autorzy:
-
Pakdeh, S. G.
Rasoolzadeh, M.
Moghadam, A. S. - Powiązania:
- https://bibliotekanauki.pl/articles/778807.pdf
- Data publikacji:
- 2016
- Wydawca:
- Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
- Tematy:
-
γ-Al2O3
thermal stability
phase transition
barium oxide
pentacoordinated Al3+ ions - Opis:
- This research concentrated on the structural stability of γ-alumina (γ-Al2O3 ) was investigated by a combination of differential thermal analysis, X-ray diffractometry and surface-area measurements. The γ –to– θ and then α phase transitions were observed as an exothermic peak at 1000°C–1400°C in the DTA curves. The role of barium oxide as a modifier to stabilize γ-Al2O3 structure has been investigated. XRD measurements show that after calcination at 1000°C for 2 h, a significant fraction of the pure γ-Al2O3 (BaO-free) transformed to θ-Al2O3 while that the transition phase in alumina samples modified by BaO have been reduced significantly. Barium oxide, eliminate pentacoordinated aluminum ions through coordinative saturation and alter these ions into octahedral cations and effectively suppressed the γ –to– α phase transition in Al2O3 , which concluded as improving the thermal stability and porous properties of the experimental samples.
- Źródło:
-
Polish Journal of Chemical Technology; 2016, 18, 4; 1-4
1509-8117
1899-4741 - Pojawia się w:
- Polish Journal of Chemical Technology
- Dostawca treści:
- Biblioteka Nauki
Artykuł