Temat: nitrides - Katalog OPAC zbiorów

Skocz do pozycji: 1.

Tytuł:: Utilization of spent iron catalyst for ammonia synthesis
Autorzy:: Arabczyk, W.
Narkiewicz, U.
Lendzion-Bieluń, Z.
Moszyński, D.
Pełech, I.
Ekiert, E.
Podsiadły, M.
Pelka, R.
Jędrzejewski, R.
Moszyñska, I.
Sibera, D.
Powiązania:: https://bibliotekanauki.pl/articles/778207.pdf
Data publikacji:: 2007
Wydawca:: Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:: katalizator żelazowy
azotki żelaza
nanorurka węglowa
nanowłókna
iron catalyst
iron nitrides
carbon nanotubes
nanofibers
Opis:: Several methods of the utilization of spent iron catalyst for ammonia synthesis have been presented. The formation of iron nitrides of different stoichiometry by direct nitriding in ammonia in the range of temperatures between 350°C and 450°C has been shown. The preparation methods of carbon nanotubes and nanofibers where iron catalyst catalyse the decomposition of hydrocarbons have been described. The formation of magnetite embedded in a carbon material by direct oxidation of carburized iron catalyst has been also presented.
Źródło:: Polish Journal of Chemical Technology; 2007, 9, 3; 108-113
1509-8117
1899-4741
Pojawia się w:: Polish Journal of Chemical Technology
Dostawca treści:: Biblioteka Nauki

Artykuł

Skocz do pozycji: 2.

Tytuł:: Kinetics of nanocrystalline iron nitriding
Autorzy:: Arabczyk, W.
Zamłynny, J.
Moszyński, D.
Powiązania:: https://bibliotekanauki.pl/articles/778372.pdf
Data publikacji:: 2010
Wydawca:: Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:: azotki żelaza
materiały mikroporowate
synteza chemiczna
analiza termograwimetryczna
dyfrakcja promieniowania rentgenowskiego
iron nitrides
microporous materials
chemical synthesis
thermogravimetric analysis
X-ray diffraction
Opis:: Nitriding of nanocrystalline iron was studied under the atmosphere of pure ammonia and in the mixtures of ammonia - hydrogen - nitrogen at temperatures between 350°C and 500°C using thermogravimetry and x-ray diffraction. Three stages of nitriding were observed and have been ascribed to the following schematic reactions: (1) α-Fe → γ-Fe4N, (2) γ- Fe4N → ε - Fe3N and (3) ε - Fe3N → ε - Fe2N. The products of these reactions appeared in the nitrided nanocrystalline iron not sequentially but co-existed at certain reaction ranges. The dependence of a reaction rate for each nitriding stage on partial pressure of ammonia is linear. Moreover, a minimal ammonia partial pressure is required to initiate the nitriding at each stage.
Źródło:: Polish Journal of Chemical Technology; 2010, 12, 1; 38-43
1509-8117
1899-4741
Pojawia się w:: Polish Journal of Chemical Technology
Dostawca treści:: Biblioteka Nauki

Artykuł

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