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Wyświetlanie 1-3 z 3
Tytuł:
Multifunctional oligoetherols and polyurethane foams with carbazole ring
Autorzy:
Lubczak, R.
Powiązania:
https://bibliotekanauki.pl/articles/778805.pdf
Data publikacji:
2016
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
carbazole
sorbitol
hydroxyalkylation
oligoetherols
thermal stability of foams
Opis:
A new method of preparation of multifunctional oligoetherols containing carbazole ring is presented. The oligoetherols were obtained in the reaction of 9-(2,3-epoxypropyl)carbazole with sorbitol and oxiranes like ethylene and propylene oxide. The structure of obtained oligoetherols was determined by IR, H-NMR and MALDI-ToF spectroscopies. Physical properties of the products render them good candidates for preparing polyurethane foams. The foams were obtained and their properties were examined. It has been found that the foams are rigid at room temperature and their apparent density was 50–70 kg/m3. The water uptake was low, maximum to 6.5 mass%. Obtained foams have high thermal resistance. Dynamic thermal analysis of these foams showed that 5% mass loss was initiated at 250–300oC, while temperature of 50% mass loss was 370–404oC. Concomitantly the increase of compression strength was observed.
Źródło:
Polish Journal of Chemical Technology; 2016, 18, 1; 120-126
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Polyurethane foams with pyrimidine rings
Autorzy:
Kania, E.
Lubczak, J.
Powiązania:
https://bibliotekanauki.pl/articles/778772.pdf
Data publikacji:
2014
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
barbituric acid
glycidol
alkylene carbonates
oligoetherols
polyurethane foams
thermal stability
Opis:
Oligoetherols based on pyrimidine ring were obtained upon reaction of barbituric acid with glycidol and alkylene carbonates. These oligoetherols were then used to obtain polyurethane foams in the reaction of oligoetherols with isocyanates and water. The protocol of foam synthesis was optimized by the choice of proper kind of oligoetherol and synthetic composition. The thermal resistance was studied by dynamic and static methods with concomitant monitoring of compressive strength. The polyurethane foams have similar physical properties as the classic ones except their enhanced thermal resistance. They stand long-time heating even at 200°C. Moreover thermal exposition of foams results generally in increase of their compressive strength.
Źródło:
Polish Journal of Chemical Technology; 2014, 16, 3; 1-6
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Polyetherols from melamine cyanurate and ethylene carbobate – synthesis and application
Autorzy:
Kijowska, D.
Legocka, I.
Powiązania:
https://bibliotekanauki.pl/articles/778889.pdf
Data publikacji:
2011
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
cyjanuran melaminy
węglan etylenu
polieterole
pianki poliuretanowe
melamine cyanurate
ethylene carbonate
polyetherols
polyurethane foams
Opis:
The results of the study on the reactions of melamine cyanurate with ethylene carbonate were presented. As a result of the reactions, polyetherols containing thermostabile 1,3,5-triazine and perhyroxo-1,3,5-triazine rings in their structure were obtained. Basic physical properties such as density, viscosity, hydroxyl number, weight changes were measured. The polyetherols were applied as a polyol component to receiving of thermoresistant polyurethane foams. Some of the properties of the obtained foams were investigated. The value of the apparent density is between 51 and 71 kg/m3, compressive strength 222–356 kPa and the content of the open pores between 14–33%. Thermal resistance was also studied by means of the TGA method. It was found that oxygen index of the selected compositions is between 20–22%.
Źródło:
Polish Journal of Chemical Technology; 2011, 13, 3; 42-46
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-3 z 3

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