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    Wyświetlanie 1-4 z 4
    Tytuł:
    Foci for Determining the Insensitivity Features of Nanometer RDX: Nanoscale Particle Size and Moderate Thermal Reactivity
    Autorzy:
    Wang, Y.
    Song, X.
    Song, D.
    Zhang, J.
    Song, K.
    Powiązania:
    https://bibliotekanauki.pl/articles/358576.pdf
    Data publikacji:
    2015
    Wydawca:
    Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
    Tematy:
    nanometer RDX
    sensitivities
    reactivity
    hot spots
    kinetics
    Opis:
    In this paper, the reasons why nanometer RDX showed lower sensitivity than micro RDX is discussed. Herein we supposed two factors affect the sensitivity of nanometer RDX. Firstly, according detonation physics models, a nanometer particle size results in small hot spots and a high critical temperature. These features suggested high safety for nanometer RDX based on the hot spot theory. A further factor is the thermal reactivity of nanometer RDX, which considerably affects the safety of nanometer energetic materials. Employing the Kinetic Compensation Effect, we calculated the kinetic parameters of micro and nanometer RDX. The results indicated that there was no obvious distinction between the activation energies of micro and nanometer RDX, which implies almost the same reactivity of micro and nanometer RDX. Incorporating the results of small hot spots, high critical temperature, and the unchanged reactivity of micro and nanometer RDX, we concluded that nanometer RDX should exhibit low sensitivity as an intrinsic feature.
    Źródło:
    Central European Journal of Energetic Materials; 2015, 12, 4; 799-815
    1733-7178
    Pojawia się w:
    Central European Journal of Energetic Materials
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    On the Mechanism of Molecular Condensed EMs Transformation under the Effect of Shock and Detonation Waves
    Autorzy:
    Dremin, A. N.
    Powiązania:
    https://bibliotekanauki.pl/articles/358857.pdf
    Data publikacji:
    2008
    Wydawca:
    Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
    Tematy:
    detonation
    decomposition regularities
    homogeneous and hot spots mechanism
    Opis:
    Considerations based on available experimental data on regularities of molecular condensed EMs decomposition under the effect of shock waves of different intensities are presented. It follows from the considerations that there exist shock wave pressures p* typical for each charge (for TNT charges p* ~ 12 GPa) and the charges’ initial density ?0* (for TNT 0* ~ 1.40 g/cm3) such that at larger pressure and density EMs' decomposition proceeds according to the homogeneous mechanism (does not depend on the charge structure: initial density, size and structure of explosive particles, explosive state-liquid or solid, …) and at lower pressure and density – according to the hot spots mechanism (depends on the charge structure).
    Źródło:
    Central European Journal of Energetic Materials; 2008, 5, 1; 31-44
    1733-7178
    Pojawia się w:
    Central European Journal of Energetic Materials
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Detonation Characteristics of a NOx-Free Mining Explosive Based on Sensitised Mixtures of Low Concentration Hydrogen Peroxide and Fuel
    Autorzy:
    Araos, M.
    Onederra, I.
    Powiązania:
    https://bibliotekanauki.pl/articles/358423.pdf
    Data publikacji:
    2017
    Wydawca:
    Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
    Tematy:
    hydrogen peroxide
    NOx free mining explosives
    detonation
    hot spots
    Opis:
    Mining explosives based on ammonium nitrate(V) are safe and effective, however, the risk of NOx fume production during blasting is still present. In 2013, a project to eliminate NOx fumes from blasting began and hydrogen peroxide was chosen to replace ammonium nitrate(V) as the oxidiser. Previous work in this area demonstrated that hydrogen peroxide/fuel-based mixtures were able to detonate, provided that they are initiated under a situation of high confinement and also using hydrogen peroxide at relatively high concentrations. In contrast, a comprehensive study was conducted to determine the detonation properties of hydrogen peroxide/fuel-based mixtures that used hydrogen peroxide at lower concentrations (below 50 wt.%), detonated in unconfined conditions and used void sensitisation to achieve an efficient detonation reaction. This article presents the results of the influence of the density, water content, critical diameter and type of void sensitisation on the velocity of detonation (VOD) of hydrogen peroxide/ fuel-based explosive mixtures. The results indicate that the mixtures can achieve a different VOD which depends on the size of the sensitising voids and more importantly, the mixtures behave as non-ideal explosive, similarly to ammonium nitrate-based explosives, but with the advantage of being a NOx-free explosive.
    Źródło:
    Central European Journal of Energetic Materials; 2017, 14, 4; 759-774
    1733-7178
    Pojawia się w:
    Central European Journal of Energetic Materials
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Analitical criteria of homogeneous and heterogeneous detonation of liquid energetic materials
    Autorzy:
    Kaim, S.
    Powiązania:
    https://bibliotekanauki.pl/articles/92588.pdf
    Data publikacji:
    2013
    Wydawca:
    Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
    Tematy:
    mechanism detonation initiation
    hot spots
    nanopores
    emission atoms and molecules
    shock dissociation molecules
    Opis:
    Statistical theory of liquids is used to investigate mechanism of detonation initiation on fronts of flat shock waves in homogeneous liquid and in liquid containing spherical nanopores. We calculated thermodynamic parameters of liquid methane sufficient for shock dissociation of molecules at a front of a shock wave. Calculations of the average single-particle force potential show that at high pressures and temperatures atoms and molecules get emitted from the surface into a nanopore with hyper-thermal speeds. Implosion of spherically symmetric stream of molecules may lead to destruction of the molecules at impact. We explained existence of top and bottom bounds for pressure during detonation initiation in heterogeneous energetic materials. In terms of pair interaction potentials and correlation functions there are formulated criteria for boundary values of thermodynamic parameters which are required for initiation of homogeneous and heterogeneous detonations based on the "hot spot"’ mechanism.
    Źródło:
    Materiały Wysokoenergetyczne; 2013, T. 5; 5-13
    2083-0165
    Pojawia się w:
    Materiały Wysokoenergetyczne
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
      Wyświetlanie 1-4 z 4

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