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Wyszukujesz frazę "Yang, C" wg kryterium: Autor


Wyświetlanie 1-4 z 4
Tytuł:
Predicted Crystal Structures, Analysis, Impact Sensitivities and Morphology of Solid High-Energy Complexes: Alkaline-Earth Carbohydrazide Perchlorates
Autorzy:
Liu, Y.
Zhang, R.
Feng, C.-G.
Yang, L.
Zhang, T.-L.
Powiązania:
https://bibliotekanauki.pl/articles/358890.pdf
Data publikacji:
2015
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
crystal structure
density of state
thermodynamic property
impact sensitivity
crystal morphology
Opis:
The crystal structures, density of states, energy gap, thermodynamic properties, impact sensitivities and morphology of beryllium carbohydrazide perchlorate ([Be(CHZ)3](ClO4)2), magnesium carbohydrazide perchlorate ([Mg(CHZ)3](ClO4)2), calcium carbohydrazide perchlorate ([Ca(CHZ)3] (ClO4)2), strontium carbohydrazide perchlorate ([Sr(CHZ)3](ClO4)2) and barium carbohydrazide perchlorate ([Ba(CHZ)3](ClO4)2) were investigated using the density functional theory (DFT) and crystal morphology theory. The results show that all of the complexes have six-coordinated distorted octahedra, which is different from previous works. This was rationalised by consideration of the intermolecular interactions in the crystal structures. Hence the crystal structure is now more reliable. The chemical reactions of the whole molecule may be triggered by an electron transition of CHZ or ClO4 −. Furthermore the energy gaps were observed, and the values of the impact sensitivities were inferred to have the following sequence: [Be(CHZ)3](ClO4)2 > [Mg(CHZ)3](ClO4)2 > [Sr(CHZ)3](ClO4)2 > [Ca(CHZ)3](ClO4)2 > [Ba(CHZ)3](ClO4)2. In addition, the thermodynamic equations at 25-1000 K were obtained. The positive values of the standard molar free enthalpies shows that carbohydrazide perchlorates are stable at 298.15 K. The (1 0 -1) and (0 0 2) faces are the most important growth directions of the crystal morphologies, and have the minimum growth rates. From the cleaved main growth faces, it can be deduced that surface active agents with active hydrogen atoms in the functional groups could be used as crystal-control reagents to control the crystal morphology for alkaline-earth carbohydrazide perchlorates.
Źródło:
Central European Journal of Energetic Materials; 2015, 12, 2; 229-248
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Measurement of the Heat of Reaction of Polytetrafluoroethylene/Aluminum Composites Based on Laser Initiation
Autorzy:
Li, S.
Wu, Y.
Lin, Q.
Huang, C.
Yang, S.
Li, J.
Powiązania:
https://bibliotekanauki.pl/articles/358195.pdf
Data publikacji:
2017
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
reactive materials
PTFE/Al composites
heat of reaction
laser initiation
Opis:
Polytetrafluoroethylene/aluminum (PTFE/Al) composites are reactive materials which can release energy due to exothermic chemical reactions initiated under shock loading conditions. In order to accurately measure the potential maximum heat of reaction of PTFE/Al composites in an inert atmosphere, we propose in this paper a heat of reaction measurement system based on laser initiation. Our results show that the measurement system successfully initiates the chemical reaction between PTFE and Al in an argon atmosphere. The comparison between theoretical calculations and experimental data demonstrates that our measurement method is highly accurate and exhibits excellent consistency. Thus, the heat of reaction measurement system based on laser initiation is applicable for measuring the heat of reaction of PTFE/Al composites and also other complicated reactive materials.
Źródło:
Central European Journal of Energetic Materials; 2017, 14, 3; 534-546
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Investigation on Stripping-down TNT from Waste Munitions by Supercritical CO2 Fluid Extraction under Low Temperature Conditions
Autorzy:
Yang, T.-M.
Li, J.-S.
Su, C.-S.
Lu, K.-T.
Yeh, T.-F.
Powiązania:
https://bibliotekanauki.pl/articles/358681.pdf
Data publikacji:
2018
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
treatment of waste munitions
supercritical fluid extraction technique
TNT
stripping-down
low temperature conditions
Opis:
The traditional methods of waste munitions treatment are expensive and also have potential risks during the treatment process. The supercritical fluid extraction technique has been a rapidly developing technique in the chemical industry in recent years. CO2 is used as the solvent, which has some advantages, such as low pollution, low cost, good chemical stability and can be operated under low temperature conditions. This research explored the feasibility of reclaiming TNT from waste munitions by supercritical CO2 fluid extraction. It was found interestingly that the melting point of TNT can be lowered in supercritical CO2 fluid. Therefore, the melting process of TNT was observed under different temperature and pressure conditions to determine the best operating conditions for stripping-down TNT from waste munitions. Afterwards, simulated warheads with weight loadings of 60 g, 500 g and 1 kg of TNT were prepared and stripping-down tests from the simulated warheads were carried out using supercritical CO2 fluid at temperatures lower than the normal melting point of TNT. The results showed that TNT could be completely removed from the simulated warheads and the optimum operating conditions were determined as 55 °C and 25 MPa. This study will contribute to the feasibility evaluation of stripping-down TNT-based high explosives.
Źródło:
Central European Journal of Energetic Materials; 2018, 15, 1; 191-205
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The Microstructural Evolution in HMX Based Plastic-bonded Explosive During Heating and Cooling Process: an in situ Small-angle Scattering Study
Autorzy:
Yan, G.
Tian, Q.
Liu, J.
Fan, Z.
Sun, G.
Zhang, C.
Wang, Y.
Chen, B.
Gong, J.
Zhou, X.
Yang, Z.
Nie, F.
Li, J.
Li, X.
Powiązania:
https://bibliotekanauki.pl/articles/358618.pdf
Data publikacji:
2016
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
SANS
SAXS
HMX-PBX
thermal damages
phase transition
Opis:
The thermal damage in octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine (HMX) based plastic-bonded explosive (PBX) was investigated using in situ small-angle neutron and X-ray scattering techniques. The microstructural evolution was quantitatively characterized by the model fitting parameters of total interfacial surface area (Sv) and void volume distribution. The Sv of HMX-PBX decreased markedly above 100 °C, indicating the movement of binder into the voids. After subsequent cooling to room temperature, the scattering intensity increased significantly with increasing storage time, and a new population of voids with average diameter of 20 nm was observed, accompanied by the gradual phase transition of HMX from δ- to β-phase. The experimental results implied that serious damage within the HMX-PBX was developed during storage after heating.
Źródło:
Central European Journal of Energetic Materials; 2016, 13, 4; 916-926
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-4 z 4

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