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Wyświetlanie 1-6 z 6
Tytuł:
Combustion Characteristics and Mechanism of Boron-based, Fuel-rich Propellants with Agglomerated Boron Powder
Autorzy:
Xu, H. -X.
Pang, W.-Q.
Guo, H.-W.
Zhao, F.-Q.
Wang, Y.
Sun, Z.-H.
Powiązania:
https://bibliotekanauki.pl/articles/358733.pdf
Data publikacji:
2014
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
analytical chemistry
boron-based fuel-rich solid propellants
agglomerated boron powder
combustion performance
combustion mechanism
Opis:
In order to extend the burning rate of boron-based, fuel-rich solid propellants with agglomerated boron powder, the effects of the boron content, the AP content, and of the magnesium powder content, on the burning rate and pressure exponent have been studied systematically. It has been shown that when the AP content is constant, the burning rate of the propellants increases with an increase in the agglomerated boron content. Furthermore, the burning rate and pressure exponent increase with increasing the contents of AP and magnesium powder. By means of single colour frame amplification photography and combustion wave tests, the combustion mechanism of these propellants has been investigated. It has been shown that the flame of the propellants becomes brighter by increasing the AP content, the dT/dxcp and dT/dxgp of the propellant FR-5 being around 6815 and 5789 °C/mm respectively, higher than those of FR-4, resulting in greater burning rates. The Ts of these propellants is above 683 °C, which is higher than the decomposition peak temperatures of agglomerated boron powder and of propellants (about 649 °C), which indicates that agglomerated boron powder is partially oxidized on the combustion surface, and the heat released from it may be beneficial to the combustion of the propellants.
Źródło:
Central European Journal of Energetic Materials; 2014, 11, 4; 575-587
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Synthesis and Characterization of a High Energy Combustion Agent (BHN) and Its Effects on the Combustion Properties of Fuel Rich Solid Rocket Propellants
Autorzy:
Pang, W.-Q.
Zhao, F.-Q.
Xue, Y.-N.
Xu, H.-X.
Fan, X.-Z.
Xie, W.-X.
Zhang, W.
Lv, J.
Deluca, L. T.
Powiązania:
https://bibliotekanauki.pl/articles/358474.pdf
Data publikacji:
2015
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
fuel rich solid propellant
BHN
DSC
TG-DTG
burning rate
combustion properties
Opis:
A high energy combustion agent (tetraethylammonium decahydrodecaborate, BHN) was prepared by means of an ion exchange reaction (IER), and the prepared samples were characterized by the advanced diagnostic techniques of Scanning Electron Microscopy (SEM), X-ray diffraction (XRD), Thermogravimetric Analysis (TGA), and Differential Scanning Calorimetry (DSC) etc. The effects of BHN particles on the hazard and combustion properties of fuel rich solid propellants were investigated. The results showed that the BHN samples and fuel rich propellants containing BHN particles can be prepared successfully and solidified safely. The peak temperature of thermal decomposition and the heat of decomposition of the BHN samples prepared were 305.8 °C and 210.9 J•g-1 at a heating rate of 10 K•min-1, respectively. The burning rate and pressure exponent of fuel rich solid propellants decreases with increases in the fraction of BHN particles in the propellant formulation. Compared with the reference formulation (sample BP-1), the burning rate of the propellant with 10% mass fraction of BHN particles (sample BP-4) had decreased 30% at 3.0 MPa, and the pressure exponent had dropped from 0.44 to 0.41.
Źródło:
Central European Journal of Energetic Materials; 2015, 12, 3; 537-552
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Synthesis and Characterization of PolyNIMMO-HTPB-polyNIMMO Triblock Copolymer as a Potential Energetic Binder
Autorzy:
Wang, X.
Shu, Y.
Lu, X.
Mo, H.
Xu, M.
Powiązania:
https://bibliotekanauki.pl/articles/358529.pdf
Data publikacji:
2018
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
triblock copolymer
cationic ring opening polymerization
polymer
DSC
Opis:
Triblock copolymer polyNIMMO-HTPB-polyNIMMO was synthesized by cationic ring opening polymerization of NIMMO (3-nitratomethyl-3-methyloxetane) in the presence of hydroxyl-terminated polybutadiene catalyzed by BF3·OEt2. The polymer was characterized by FT-IR, 1H NMR, 13C NMR spectroscopy, and GPC. DSC was used to investigate the thermal behaviour of the triblock copolymer and its exothermic decomposition peak was found to be at 215 °C. All of the results indicated that the triblock copolymer polyNIMMO-HTPB-polyNIMMO might serve as a potential energetic propellant binder.
Źródło:
Central European Journal of Energetic Materials; 2018, 15, 3; 456-467
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Thermally Induced Polymorphic Transformation of Hexanitrohexaazaisowurtzitane (HNIW) Investigated by in-situ X-ray Powder Diffraction
Autorzy:
Liu, Y.
Li, S.
Wang, Z.
Xu, J.
Sun, J.
Huang, H.
Powiązania:
https://bibliotekanauki.pl/articles/358065.pdf
Data publikacji:
2016
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
HNIW
polymorphism
in situ X-ray diffraction
phase transition
heat stimulation
Opis:
The ε→γ phase transition of HNIW induced by heat was investigated with in situ X-ray powder diffraction (PXRD). The effects of purity, particle size, insensitive additives and the time of isothermal heat treatment on the phase transition were evaluated. It was found that the phase transition is irreversible with changes in temperature, and the two phases can coexist in a certain temperature range. Moreover, the initial phase transition temperature increases with increasing purity and decreasing particle size of HNIW, and thus with the approximate crystal density. The addition of graphite and paraffin wax to HNIW as insensitive additives leads to a decrease in the initial phase transition temperature, but the addition of TATB does not affect the initial phase transition temperature. Thus, TATB is a suitable insensitive additive. Moreover, at the critical temperature, the isothermal time determined the efficiency of the ε- to γ-phase transition. This work lays the foundations for the choice of molding technologies, performance test methods, ammunition storage options, as well as the manufacture of HNIW-based explosive formulations.
Źródło:
Central European Journal of Energetic Materials; 2016, 13, 4; 1023-1037
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Preparation and Characterization of Ultrafine HMX/TATB Explosive Co-crystals
Autorzy:
An, C.
Li, H.
Zhang, Y.
Ye, B.
Xu, C.
Wang, J.
Powiązania:
https://bibliotekanauki.pl/articles/358105.pdf
Data publikacji:
2017
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
HMX
TATB
ultrafine co-crystals
ball milling
mechanical sensitivity
Opis:
An explosive co-crystal of 1,3,5,7-tetranitro-1,3,5,7-tetraazacyclooctane (HMX) and 1,3,5-triamino-2,4,6-trinitrobenzene (TATB) was prepared by the ball milling method. The raw materials and co-crystals were characterized using scanning electron microscopy (SEM), X-ray diffraction (XRD), differential scanning calorimetry (DSC) and Raman spectroscopy. Impact and friction sensitivity of the co-crystals were tested and analyzed. The results showed that the HMX/TATB co-crystals are spherical in shape and 100-300 nm in size. The co-crystals are different from anintimate mixture of HMX/TATB and they exhibit a new co-crystal structure. HMX/TATB co-crystals are formed by N-O···H hydrogen bonding between −NO2 (HMX) and −NH2 (TATB). The drop height of ultrafine HMX/TATB explosive co-crystals is 12.7 cm higher than that of ultrafine HMX, whilst the explosion probability of friction is 20% lower than that of ultrafine HMX. Ultrafine HMX/TATB explosive co-crystals are difficult to initiate under impact and friction conditions.
Źródło:
Central European Journal of Energetic Materials; 2017, 14, 4; 876-887
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Research on the Mechanism and Kinetics of Polymorphic Transitions of ε CL-20 in Composite Systems
Autorzy:
Guo, X.-Y.
Zhang, P.
Xu, J.-J.
Wang, Z.-H.
Jiao, Q.-J.
Powiązania:
https://bibliotekanauki.pl/articles/358032.pdf
Data publikacji:
2015
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
polymorphic transition
kinetics
activation energy
transition temperature
Opis:
In order to explore the polymorphic transition law for ε-CL-20 in composite systems, the polymorphic transition process of pure ε-CL-20 crystals stimulated by heat was investigated by the X-ray Diffraction (XRD) method, and the kinetic parameters of the polymorphic transition process were calculated (including the apparent activation energy Ea and the pre-exponential factor lnA). Meanwhile the effects of different additives on the polymorphic transition process and kinetics of ε-CL-20 were explored in detail. The experimental results showed that the ε-form tends to transform into the γ- form on heating and that the Ea and lnA for the transition process were 209.97 kJ/mol and 57.47, respectively. The first group of additives clearly promoted the polymorphic transition of ε-CL-20 and lowered the initial transition temperature and the activation energy. The second and third groups of additives inhibited the polymorphic transition of ε-CL-20 and raised the initial transition temperature and the activation energy.
Źródło:
Central European Journal of Energetic Materials; 2015, 12, 4; 689-702
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-6 z 6

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