Informacja

Drogi użytkowniku, aplikacja do prawidłowego działania wymaga obsługi JavaScript. Proszę włącz obsługę JavaScript w Twojej przeglądarce.

English (EN)·Polski (PL)·Yкраїнський (UK)
Przejdź do strony domowej biblioteki Centralna Biblioteka Wojskowa Link otwiera się w nowym oknie Logo biblioteki Prolib Integro - strona głównaCentralna Biblioteka Wojskowa

Wyszukujesz frazę "Singh, S. B." wg kryterium: Autor

  Lista filtrów
Wyrównaj
    Wyświetlanie 1-4 z 4
    Tytuł:
    Evaluation of Potassium Perchlorate as a Burning Rate Modifier in Composite Propellant Formulations
    Autorzy:
    Jain, S.
    Mehilal, D.
    Singh, P. P.
    Bhattacharya, B.
    Powiązania:
    https://bibliotekanauki.pl/articles/358405.pdf
    Data publikacji:
    2016
    Wydawca:
    Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
    Tematy:
    composite propellant
    burning rate
    ammonium perchlorate
    potassium perchlorate
    Opis:
    The burning rate of a solid composite propellant is one of its most important ballistic properties. To achieve a specified burning rate, transition metal oxides are used as burning rate modifiers. However, addition of transition metal oxides creates inertness in the composition. To avoid such inertness, an attempt has been made to incorporate potassium perchlorate (KP) as a burning rate modifier by partially replacing ammonium perchlorate (AP), up to the 10% level, and the composition was then studied in detail for its mechanical, thermal and ballistic properties. The data revealed that no change occurred in the case of the mechanical properties, however, the thermal stability decreased as the KP content was increased. The burning rate data revealed that on incorporation of 10% KP, there was an enhancement in the burning rate of up to 35% in comparison to the original composite propellant formulation, but beyond this no enhancement in burning rate was observed, indicating that the optimum content for KP in the composition had been reached.
    Źródło:
    Central European Journal of Energetic Materials; 2016, 13, 1; 231-245
    1733-7178
    Pojawia się w:
    Central European Journal of Energetic Materials
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Optimization of Ammonium Sulfamate Nitration for the Preparation of Ammonium Dinitramide
    Autorzy:
    Mandal, A. K.
    Kunjir, G. M.
    Singh, J.
    Adhav, S. S.
    Singh, S. K.
    Pandey, R. K.
    Bhattacharya, B.
    Lakshmi Kantam, M.
    Powiązania:
    https://bibliotekanauki.pl/articles/358022.pdf
    Data publikacji:
    2014
    Wydawca:
    Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
    Opis:
    The reaction kinetics for the preparation of ammonium dinitramide (ADN) is described. ADN is the ammonium salt of the dinitramide anion, and belongs to the group of inorganic oxidizers, mainly useful for energetic rocket propellant formulations, particularly for underwater applications. It is also a potential candidate to replace ammonium perchlorate (AP), in order to develop chlorine-free, green propellants. At HEMRL, ADN is prepared by the nitration of ammonium sulfamate (AS) using mixed acid, followed by hydrolysis, neutralization with ammonia (g) and rectification using solvent. The nitration of ammonium sulfamate (AS) is carried out at a subzero temperature of -40 ±1 °C. The yield of ADN is reliant on the formation of dinitramidic acid, an intermediate product formed during the hydrolysis step, and its stability is predominantly dependent upon the level of acidity and temperature of the reaction medium. Prior to these kinetics studies, process optimization of the nitration of ammonium sulfamate (AS) was performed and gave the final mole ratio of AS:HNO3:H2SO4. Since the nitration of AS is sensitive to temperature, the rate of reaction was studied at fixed temperatures with variation of time, keeping all of the other parameters, such as vessel volume, agitator speed, feed rate etc., constant. During these studies, predetermined quantities of ammonium sulfamate (AS) and mixed acid were allowed to react at a fixed temperature (-40 ±1 °C) for different reaction periods to generate the concentration profile of AS. Using this concentration profile, the reaction order and reaction rate constant were evaluated. In order to find the effect of temperature on the reaction rate and yield, experiments were conducted at other temperatures such as -30 and -50 °C. In the present studies, it was found that the optimum temperature of nitration is -40 ±1 °C and that the rate of reaction follows a pseudo second order process with rate constant 0.01113 (min-1)•(mol/L)-1. The reaction time evaluated for 55 to 60% conversion is about 70-80 minutes at -40 ±1 °C, based on this kinetics. The activation energy of AS nitration was found to be -4.6 kcal/mol, using the reaction kinetic data based on the temperature dependent rate equation derived from Arrhenius’s law.
    Źródło:
    Central European Journal of Energetic Materials; 2014, 11, 1; 83-97
    1733-7178
    Pojawia się w:
    Central European Journal of Energetic Materials
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Experimental Studies on Advanced Sheet Explosive Formulations Based on 2,4,6,8,10,12-Hexanitro-2,4,6,8,10,12-hexaazaisowurtzitane (CL-20) and Hydroxyl Terminated Polybutadiene (HTPB), and Comparison with a RDX-based System
    Autorzy:
    Jangid, S. K.
    Talawar, M. B.
    Singh, M. K.
    Nath, T.
    Sinha, R. K.
    Powiązania:
    https://bibliotekanauki.pl/articles/358055.pdf
    Data publikacji:
    2016
    Wydawca:
    Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
    Tematy:
    hazardous materials
    sheet explosive
    explosive reactive armour (ERA)
    CL-20
    RDX
    Opis:
    The present investigation reports the use of 2,4,6,8,10,12-hexanitro2,4,6,8,10,12-hexaazaisowurtzitane (CL-20) in sheet explosive formulations. In this study, hydroxyl terminated polybutadiene (HTPB) based sheet explosives were prepared incorporating the powerful explosive CL-20 as a partial replacement for hexahydro-1,3,5-trinitro-1,3,5-triazine(RDX). The effects of incorporating CL-20 on the performance, sensitivity, thermal and mechanical properties of the sheet explosive compositions are reported. Sheet explosive formulation containing 80% of RDX and 20% of HTPB-binder was studied as control sample. HTPBbinder consisted of 12% HTPB, 2.9% dioctyl adipate (DOA) and 5.1% dioctyl phthalate (DOP). HTPB was cured with 4,4’-methylene diphenyl di-isocyanate (MDI) to form urethane linkages. The incorporation of 20% of CL-20 in place of RDX led to a remarkable increase in the velocity of detonation (VOD), of the order of 7680 m/s, and to better mechanical properties in terms of tensile strength (1.14 MPa) compared to the control formulation [RDX /HTPB-binder (80/20)]. The 20% CL-20 incorporated sheet explosive formulation also showed remarkable increases in impact and shock sensitivity. Thermal analysis of the sheet explosive compositions has also been carried out using differential scanning calorimetry (DSC).
    Źródło:
    Central European Journal of Energetic Materials; 2016, 13, 1; 135-147
    1733-7178
    Pojawia się w:
    Central European Journal of Energetic Materials
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Studies on High Burning Rate Composite Propellant Formulations using TATB as Pressure Index Suppressant
    Autorzy:
    Mehilal, -
    Jawalkar, S.
    Kurva, R.
    Sundaramoorthy, N.
    Dombe, G.
    Singh, P. P.
    Bhattacharya, B.
    Powiązania:
    https://bibliotekanauki.pl/articles/951502.pdf
    Data publikacji:
    2012
    Wydawca:
    Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
    Tematy:
    composite propellant
    ammonium perchlorate
    TATB
    pressure index suppressant
    Opis:
    High burning rate propellant compositions are generally used in gas generators to eject missile from canister. Because of high burning rate, pressure index of the composition increases during burning. To reduce the pressure index, a high burning rate composite propellant formulations (~20 mm/s) based on AP/HTPB/Al have been prepared by incorporating TATB and studied in detail for viscosity build-up, thermal and mechanical properties, sensitivity as well as burning rate and pressure index (n). The data indicate that there is a decrease in end of mix viscosity on increasing the percentage of TATB. The same trend was also observed with mechanical properties while significant improvement in overall thermal stability was clearly observed. The sensitivity data indicate that impact and friction values show decreasing trend infer better safe to handle. The burn rate data reveal that on addition of TATB from 0.5 to 2% decrease in burning rate was not observed while on addition of further TATB up to 5% and beyond this significant decrease in burning rate was observed. The data on pressure index (n) also reveal that TATB is very effective in reducing the 'n' value up to 2% and beyond this 'n' value increases close to standard composition. The data on 'n' value reveal that it reduces from 0.47 to that of standard composition to 0.36 for the compositions containing TATB up to 2.0% in the pressure range of 60-90 kg/cm2.
    Źródło:
    Central European Journal of Energetic Materials; 2012, 9, 3; 237-249
    1733-7178
    Pojawia się w:
    Central European Journal of Energetic Materials
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
      Wyświetlanie 1-4 z 4

      Ta witryna wykorzystuje pliki cookies do przechowywania informacji na Twoim komputerze. Pliki cookies stosujemy w celu świadczenia usług na najwyższym poziomie, w tym w sposób dostosowany do indywidualnych potrzeb. Korzystanie z witryny bez zmiany ustawień dotyczących cookies oznacza, że będą one zamieszczane w Twoim komputerze. W każdym momencie możesz dokonać zmiany ustawień dotyczących cookies