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    Wyświetlanie 1-3 z 3
    Tytuł:
    Measurement of the Heat of Reaction of Polytetrafluoroethylene/Aluminum Composites Based on Laser Initiation
    Autorzy:
    Li, S.
    Wu, Y.
    Lin, Q.
    Huang, C.
    Yang, S.
    Li, J.
    Powiązania:
    https://bibliotekanauki.pl/articles/358195.pdf
    Data publikacji:
    2017
    Wydawca:
    Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
    Tematy:
    reactive materials
    PTFE/Al composites
    heat of reaction
    laser initiation
    Opis:
    Polytetrafluoroethylene/aluminum (PTFE/Al) composites are reactive materials which can release energy due to exothermic chemical reactions initiated under shock loading conditions. In order to accurately measure the potential maximum heat of reaction of PTFE/Al composites in an inert atmosphere, we propose in this paper a heat of reaction measurement system based on laser initiation. Our results show that the measurement system successfully initiates the chemical reaction between PTFE and Al in an argon atmosphere. The comparison between theoretical calculations and experimental data demonstrates that our measurement method is highly accurate and exhibits excellent consistency. Thus, the heat of reaction measurement system based on laser initiation is applicable for measuring the heat of reaction of PTFE/Al composites and also other complicated reactive materials.
    Źródło:
    Central European Journal of Energetic Materials; 2017, 14, 3; 534-546
    1733-7178
    Pojawia się w:
    Central European Journal of Energetic Materials
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Enhanced Non-linear Viscoelastic Properties of Polymer Bonded Explosives Based on Graphene and a Neutral Polymeric Bonding Agent
    Autorzy:
    Lin, C.
    He, G.
    Liu, J.
    Pan, L.
    Liu, S.
    Powiązania:
    https://bibliotekanauki.pl/articles/358748.pdf
    Data publikacji:
    2017
    Wydawca:
    Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
    Tematy:
    polymer bonded explosives
    graphene
    neutral polymeric bonding agent
    creep behaviour
    Opis:
    During their long-term storage and transport, polymer bonded explosives (PBXs) will be subjected to complex thermal physical environments with combined thermal and mechanical loads. The creep behaviour results in a change of physical and mechanical properties, which consequently influences the explosive performance. In this work, graphene and a neutral polymeric bonding agent (NPBA) were selected to improve the non-linear creep properties of 1,3,5-triamino-2,4,6-trinitrobenzene (TATB)-based PBXs. The results were compared with the creep response of the corresponding PBXs without additives and with graphene alone. It was observed that graphene and an NPBA exhibited a positive effect, improving the creep resistance of TATB-based PBXs. The compressive and tensile strength of 0.5 wt.% graphene-filled PBXs were improved by 5.1% and 29.2%, respectively, compared to raw TATB-based PBXs without additives. The performance of the PBXs was further enhanced by the addition of 0.1 wt.% NPBA. For a given stress and temperature, the TATB-based PBXs with graphene and NPBA deformed significantly less than the PBXs filled with graphene alone.
    Źródło:
    Central European Journal of Energetic Materials; 2017, 14, 4; 788-805
    1733-7178
    Pojawia się w:
    Central European Journal of Energetic Materials
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Dft investigation of a high energy density polynitro compound, 2,2’-Bis(trinitromethyl)-5,5’-azo-1,2,3,4- tetrazole
    Autorzy:
    Lin, H.
    Zhu, S. G.
    Chen, P. Y.
    Li, K.
    Li, H. Z.
    Peng, X. H.
    Powiązania:
    https://bibliotekanauki.pl/articles/358030.pdf
    Data publikacji:
    2013
    Wydawca:
    Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
    Tematy:
    polynitro
    electronic structure
    thermodynamic properties
    crystal structure
    detonation performance
    stability
    Opis:
    A novel polynitro compound, 2,2’-bis(trinitromethyl)-5,5’-azo- 1,2,3,4-tetrazole, was designed and investigated at the DFT-B3LYP/6-31G(d) level. Its properties, such as electronic structure, IR spectrum, heat of formation, thermodynamic properties and crystal structure, were predicted. This compound is most likely to crystallize in the P21 space group, and the corresponding cell parameters are Z = 2, a = 5.46 Å, b = 9.72 Å, c = 14.05 Å, α = 90°, β = 90°, γ = 90°. In addition, the detonation velocity and pressure were also estimated by using the empirical Kamlet-Jacobs equations, and were predicted to be 8.28 km/s and 31.61 GPa respectively. The oxygen balance of this compound is +13.79%, which indicates that it could serve as an oxidizer. Bond dissociation energy calculations show that the C(13)-N(21)O2 and C(14)-N(30)O2 bonds are the locations of thermal decomposition and that this compounds meets the thermal stability requirements as an exploitable explosive. Keywords: polynitro, electronic structure, thermodynamic properties, crystal structure, detonation performance, stability.
    Źródło:
    Central European Journal of Energetic Materials; 2013, 10, 3; 325-338
    1733-7178
    Pojawia się w:
    Central European Journal of Energetic Materials
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
      Wyświetlanie 1-3 z 3

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