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Wyświetlanie 1-5 z 5
Tytuł:
Different Ignition Responses of Powdery and Bulky 1,3,5-Triamino-2,4,6-trinitrobenzene (TATB) Based Polymer-bonded Explosives under Ultra-high Voltage Electrostatic Discharge
Autorzy:
Lyu, Z.
Long, X.
Li, Z.
Dai, X.
Deng, C.
He, S.
Li, M.
Yao, K.
Wen, Y.
Powiązania:
https://bibliotekanauki.pl/articles/358240.pdf
Data publikacji:
2018
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
electrostatic spark sensitivity
ultra-high voltage electrostatic discharge
thermal effect
electric field effect
Opis:
The electric spark induced ignition mechanism for explosives needs further study. The ignition of powdery and bulky TATB by electrostatic discharge (ESD) was investigated. Up to 200 kV ultra-high voltage ESD was applied to powdery and bulky explosives of two TATB-based polymer-bonded explosives (named PBX-1 and PBX-2). The results showed that the spark sensitivities of powdery and bulky explosives are extremely different for the same formulation. The 50% ignition voltages of powdery PBX-1 and PBX-2 were 10.8 kV and 8.5 kV, respectively, while the values for the bulky samples (tablets) were not less than 200 kV. Both heat and the electric field can be transmitted into the powdery samples, on the other hand only the electric field can be transmitted into the bulk samples. The electric field has a smaller contribution while the heat has a larger contribution to the ignition during an ESD, i.e., the thermal effect plays a main role in the ignition process. Our experimental results are in good agreement with recent results calculated by density functional theory.
Źródło:
Central European Journal of Energetic Materials; 2018, 15, 2; 283-298
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Influence of Processing Techniques on Mechanical Properties and Impact Initiation of an Al-PTFE Reactive Material
Autorzy:
Feng, B.
Fang, X.
Li, Y.-C.
Wu, S.-Z.
Mao, Y.-M.
Wang, H.-X.
Powiązania:
https://bibliotekanauki.pl/articles/358654.pdf
Data publikacji:
2016
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
Al-PTFE
reactive materials
quasi-static compression
impact initiation
Opis:
Reactive materials (RMs) or impact-initiated materials have received much attention as a class of energetic materials in recent years. To assess the influence of processing techniques on mechanical properties and impact initiation behaviors of an Al-PTFE reactive material, quasi -static compression tests and drop-weight tests were performed. Scanning electron microscopy (SEM) was used to identify the characteristics of the interior microstructures of the Al-PTFE samples. A sintering process was found to transform Al-PTFE from a brittle to a ductile material with an increased elasticity modulus (from 108-160 MPa to 256-336 MPa) and yield stress (from 12-16 MPa to 19-20 MPa). Increasing the molding pressure from 36 MPa to 182 MPa increased the elastic modulus of all Al-PTFE samples and also the yield stress of unsintered ones. Unsintered samples in general required less energy to initiate than sintered ones. As the molding pressure increased, the impact initiation energy for sintered Al-PTFE fell from 96 J to 68 J, whereas the initiation energy for unsintered Al-PTFE rose from 68 J to 85 J. PTFE nanofiber networks observed in sintered samples formed under the higher molding pressures could contribute to the opposite trends observed in the impact initiation energy of unsintered and sintered Al-PTFE samples.
Źródło:
Central European Journal of Energetic Materials; 2016, 13, 4; 989-1004
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Dft investigation of a high energy density polynitro compound, 2,2’-Bis(trinitromethyl)-5,5’-azo-1,2,3,4- tetrazole
Autorzy:
Lin, H.
Zhu, S. G.
Chen, P. Y.
Li, K.
Li, H. Z.
Peng, X. H.
Powiązania:
https://bibliotekanauki.pl/articles/358030.pdf
Data publikacji:
2013
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
polynitro
electronic structure
thermodynamic properties
crystal structure
detonation performance
stability
Opis:
A novel polynitro compound, 2,2’-bis(trinitromethyl)-5,5’-azo- 1,2,3,4-tetrazole, was designed and investigated at the DFT-B3LYP/6-31G(d) level. Its properties, such as electronic structure, IR spectrum, heat of formation, thermodynamic properties and crystal structure, were predicted. This compound is most likely to crystallize in the P21 space group, and the corresponding cell parameters are Z = 2, a = 5.46 Å, b = 9.72 Å, c = 14.05 Å, α = 90°, β = 90°, γ = 90°. In addition, the detonation velocity and pressure were also estimated by using the empirical Kamlet-Jacobs equations, and were predicted to be 8.28 km/s and 31.61 GPa respectively. The oxygen balance of this compound is +13.79%, which indicates that it could serve as an oxidizer. Bond dissociation energy calculations show that the C(13)-N(21)O2 and C(14)-N(30)O2 bonds are the locations of thermal decomposition and that this compounds meets the thermal stability requirements as an exploitable explosive. Keywords: polynitro, electronic structure, thermodynamic properties, crystal structure, detonation performance, stability.
Źródło:
Central European Journal of Energetic Materials; 2013, 10, 3; 325-338
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The Microstructural Evolution in HMX Based Plastic-bonded Explosive During Heating and Cooling Process: an in situ Small-angle Scattering Study
Autorzy:
Yan, G.
Tian, Q.
Liu, J.
Fan, Z.
Sun, G.
Zhang, C.
Wang, Y.
Chen, B.
Gong, J.
Zhou, X.
Yang, Z.
Nie, F.
Li, J.
Li, X.
Powiązania:
https://bibliotekanauki.pl/articles/358618.pdf
Data publikacji:
2016
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
SANS
SAXS
HMX-PBX
thermal damages
phase transition
Opis:
The thermal damage in octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine (HMX) based plastic-bonded explosive (PBX) was investigated using in situ small-angle neutron and X-ray scattering techniques. The microstructural evolution was quantitatively characterized by the model fitting parameters of total interfacial surface area (Sv) and void volume distribution. The Sv of HMX-PBX decreased markedly above 100 °C, indicating the movement of binder into the voids. After subsequent cooling to room temperature, the scattering intensity increased significantly with increasing storage time, and a new population of voids with average diameter of 20 nm was observed, accompanied by the gradual phase transition of HMX from δ- to β-phase. The experimental results implied that serious damage within the HMX-PBX was developed during storage after heating.
Źródło:
Central European Journal of Energetic Materials; 2016, 13, 4; 916-926
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Oxygen-containing Tetrazole Salts of 3-Hydrazino-4-amino-1,2,4-triazole (HATr): Nitrogen-rich Ionic Materials with High Thermal Stability
Autorzy:
Wu, J.-T.
Zhang, J.-G.
Yin, X.
Li, T.
Wu, L.
Zhang, Z.-B.
Powiązania:
https://bibliotekanauki.pl/articles/358927.pdf
Data publikacji:
2017
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
energetic salts
thermal stability
oxygen-containing tetrazoles
3-hydrazino-4-amino-1,2,4-triazole
Opis:
Energetic salts of doubly-protonated 3-hydrazino-4-amino-1,2,4-triazole (2-4), and mono-protonated 3-hydrazino-4-amino-1,2,4-triazole (5-7), have been prepared in high yields from the corresponding oxygen-containing tetrazoles by (i) reaction of free acids and neutral 3-hydrazino-4-amino-1,2,4-triazole, or (ii) metathesis reactions of 3-hydrazinium-4-amino-1H-1,2,4-triazolium di-chloride with the silver salts of the corresponding oxygen-containing tetrazoles. All of these energetic salts were fully characterized by single-crystal X-ray diffraction, FT-IR and DSC measurements. All of the structures are dominated by extensive hydrogen bonds due to amino groups, hydrazino groups and oxygen atoms in the molecules. These salts exhibit good thermal stability, especially the salt 3-hydrazinium-4-amino-1H-1,2,4-triazolium 1H,1’H-5,5’-bitetrazole-1,1’-diolate (4), which exhibits a measured onset of decomposition temperature of 237 °C. Quantum chemical calculations, carried out using the Gaussian 03 suite of programs and based on the experimental densities were used to calculate the detonation pressures and velocities of all of the salts.
Źródło:
Central European Journal of Energetic Materials; 2017, 14, 1; 217-232
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-5 z 5

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