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    Wyświetlanie 1-6 z 6
    Tytuł:
    Review of the Photodecomposition of Some Important Energetic Materials
    Autorzy:
    Sun, Y.
    Shu, Y.
    Xu, T.
    Shui, M.
    Zhao, Z.
    Gu, Y.
    Wang, X.
    Powiązania:
    https://bibliotekanauki.pl/articles/358397.pdf
    Data publikacji:
    2012
    Wydawca:
    Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
    Tematy:
    photodecomposition mechanisms
    energetic materials
    Opis:
    The photodecomposition mechanisms of energetic materials vary with molecular structure, photodissociation wavelength, the phase of the material, experimental pressure and temperature etc. In this paper, the significant progress on photodecomposition studies of some important energetic materials achieved in recent years is introduced in detail, including nitromethane, DMNA (dimethylnitramine), TATB (1,3,5-triamino-2,4,6-trinitrobenzene), RDX (hexahydro-1,3,5-trinitro-1,3,5-triazine), HMX (1,3,5,7-tetranitro-1,3,5,7- tetrazacycloctane) and CL-20 (2,4,6,8,10,12-hexanitrohexaazaisowurtzitane). The difficulties and prospects of photodecomposition research of energetic materials are also indicated.
    Źródło:
    Central European Journal of Energetic Materials; 2012, 9, 4; 411-423
    1733-7178
    Pojawia się w:
    Central European Journal of Energetic Materials
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Study on Underwater Explosive Welding of Al-Steel Coaxial Pipes
    Autorzy:
    Yu, Y.
    Ma, H.
    Zhao, K.
    Shen, Z.
    Cheng, Y.
    Powiązania:
    https://bibliotekanauki.pl/articles/358620.pdf
    Data publikacji:
    2017
    Wydawca:
    Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
    Tematy:
    metal-matrix composites
    explosive welding
    surface ablation
    microstructures
    bonding interface
    Opis:
    In order to solve the aluminum surface ablation issue of Al-Steel bimetallic pipes manufactured by the explosive welding technique, a novel explosive welding system has been designed to weld Al-Steel coaxial pipes. The stand-off distance was chosen according to an empirical formula. A special Explosive Cord with an aluminum coating was used as the explosive. Four experiments were performed using Explosive Cords 1, 2, 3 and 4, respectively. In each experiment, three reliable PVDF (Polyvinylidene Fluoride) piezoelectric film sensors were used to sample the impact pressure between the parent pipe and the flyer pipe along the detonation direction. p-t Curves were obtained at different points on the bimetallic pipe manufactured by Explosive Cord 1. In order to observe the inner surface and to judge the bonding interface, specimens were cut along the axial direction. BSE (Backscattering Electron) images of the interfaces were obtained. According to these pictures from all of the specimens cut along the axial direction, the surface ablation phenomenon has disappeared. The bimetallic pipe manufactured by the new welding system using Explosive Cord 3 has an irregular wavy interface, between micro and small wavy interface, which is one of the best bonding forms.
    Źródło:
    Central European Journal of Energetic Materials; 2017, 14, 1; 251-265
    1733-7178
    Pojawia się w:
    Central European Journal of Energetic Materials
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Unravelling the Effect of Anthraquinone Metal Salts as Wide-range Plateau Catalysts to Enhance the Combustion Properties of Solid Propellants
    Autorzy:
    Wang, Y.
    Yan, Q.-L.
    An, T.
    Chen, B.
    Ji, Y.-P.
    Wang, W.
    Zhao, F.
    Powiązania:
    https://bibliotekanauki.pl/articles/358042.pdf
    Data publikacji:
    2018
    Wydawca:
    Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
    Tematy:
    solid propellants
    burning rate catalysts
    anthraquinone metal salts
    wide-range plateau combustion
    Opis:
    Novel lead and copper salts based on anthraquinone, including 1,8-dihydroxyanthraquinone,1,4,5,8-tetrahydroxyanthraquinone and 1,8-dihydroxy-4,5-dinitroanthraquinone, were prepared and characterized by Fourier transform infrared spectroscopy (FTIR), elemental analysis (EA), and X-ray fluorescence (XRF). The catalytic effects of these compounds on the decomposition of nitrocellulose (NC) and on the combustion properties of double-base (DB) and composite modified double-base (CMDB) propellants were comprehensively investigated. The results demonstrated that the burning rate is significantly increased (by 200%) in the lower pressure range (2-6 MPa) as compared to the control systems without added anthraquinone-based salts. Concurrently, the pressure exponents (n) were obviously lower, exhibiting a “wide-range plateau” combustion phenomenon in the middle-pressure region. Specifically, for the DB propellants such a plateau region extended from 10 MPa to 16 MPa for n equal to 0.10, from 10 MPa to 18 MPa for n equal to 0.11 and from 8 MPa to 18 MPa when n is 0.05. In the case of RDX-CMDB propellants, the plateau was found to be in the range 6-18 MPa, with n in the range 0.16-0.27, depending on the type of catalyst, in contrast to the reference CMDB sample, which was characterized by n equal to 0.7 for the same pressure range.
    Źródło:
    Central European Journal of Energetic Materials; 2018, 15, 2; 376-390
    1733-7178
    Pojawia się w:
    Central European Journal of Energetic Materials
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Influence of Polytetrafluorethylene on the Mechanical and Safety Properties of a Composite Modified Double Base Propellant
    Autorzy:
    Sun, S.
    Zhang, T.
    Zhao, B.
    Zhang, G.
    Li, X.
    Luo, Y.
    Powiązania:
    https://bibliotekanauki.pl/articles/358296.pdf
    Data publikacji:
    2018
    Wydawca:
    Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
    Tematy:
    PTFE fibres
    CMDB propellant
    mechanical properties
    mechanical sensitivity
    combustion
    Opis:
    A novel Composite Modified Double Base (CMDB) propellant, formed by mechanically mixing aluminium/polytetrafluorethylene (Al/PTFE) powders, was prepared through a rolling process. A variety of tests, such as tensile properties, particle size analysis etc., were carried out to study the influence of PTFE on the CMDB propellant properties. The PTFE deformed from particles to fibres under a uniform shear force, forming a fibre network which greatly improved the propellant’s mechanical properties. Compared to that of the CMDB propellant without PTFE, the elongation of the propellant containing 6% PTFE was increased by 26 times, and moreover, the impact strength was enhanced by 326% at −40 °C. Significantly, the propellant friction and impact sensitivities were reduced by 75.8% and 35.6%, respectively. In addition, the presence of PTFE in the propellant resulted in fluorination of the Al. The gaseous combustion product AlF3 reduced the propellant combustion agglomeration. Consequently, PTFE significantly promoted the propellant’s mechanical performance, decreased the shock (friction, impact) sensitivity and reduced combustion agglomeration.
    Źródło:
    Central European Journal of Energetic Materials; 2018, 15, 3; 468-484
    1733-7178
    Pojawia się w:
    Central European Journal of Energetic Materials
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Combustion Characteristics and Mechanism of Boron-based, Fuel-rich Propellants with Agglomerated Boron Powder
    Autorzy:
    Xu, H. -X.
    Pang, W.-Q.
    Guo, H.-W.
    Zhao, F.-Q.
    Wang, Y.
    Sun, Z.-H.
    Powiązania:
    https://bibliotekanauki.pl/articles/358733.pdf
    Data publikacji:
    2014
    Wydawca:
    Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
    Tematy:
    analytical chemistry
    boron-based fuel-rich solid propellants
    agglomerated boron powder
    combustion performance
    combustion mechanism
    Opis:
    In order to extend the burning rate of boron-based, fuel-rich solid propellants with agglomerated boron powder, the effects of the boron content, the AP content, and of the magnesium powder content, on the burning rate and pressure exponent have been studied systematically. It has been shown that when the AP content is constant, the burning rate of the propellants increases with an increase in the agglomerated boron content. Furthermore, the burning rate and pressure exponent increase with increasing the contents of AP and magnesium powder. By means of single colour frame amplification photography and combustion wave tests, the combustion mechanism of these propellants has been investigated. It has been shown that the flame of the propellants becomes brighter by increasing the AP content, the dT/dxcp and dT/dxgp of the propellant FR-5 being around 6815 and 5789 °C/mm respectively, higher than those of FR-4, resulting in greater burning rates. The Ts of these propellants is above 683 °C, which is higher than the decomposition peak temperatures of agglomerated boron powder and of propellants (about 649 °C), which indicates that agglomerated boron powder is partially oxidized on the combustion surface, and the heat released from it may be beneficial to the combustion of the propellants.
    Źródło:
    Central European Journal of Energetic Materials; 2014, 11, 4; 575-587
    1733-7178
    Pojawia się w:
    Central European Journal of Energetic Materials
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Synthesis and Characterization of a High Energy Combustion Agent (BHN) and Its Effects on the Combustion Properties of Fuel Rich Solid Rocket Propellants
    Autorzy:
    Pang, W.-Q.
    Zhao, F.-Q.
    Xue, Y.-N.
    Xu, H.-X.
    Fan, X.-Z.
    Xie, W.-X.
    Zhang, W.
    Lv, J.
    Deluca, L. T.
    Powiązania:
    https://bibliotekanauki.pl/articles/358474.pdf
    Data publikacji:
    2015
    Wydawca:
    Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
    Tematy:
    fuel rich solid propellant
    BHN
    DSC
    TG-DTG
    burning rate
    combustion properties
    Opis:
    A high energy combustion agent (tetraethylammonium decahydrodecaborate, BHN) was prepared by means of an ion exchange reaction (IER), and the prepared samples were characterized by the advanced diagnostic techniques of Scanning Electron Microscopy (SEM), X-ray diffraction (XRD), Thermogravimetric Analysis (TGA), and Differential Scanning Calorimetry (DSC) etc. The effects of BHN particles on the hazard and combustion properties of fuel rich solid propellants were investigated. The results showed that the BHN samples and fuel rich propellants containing BHN particles can be prepared successfully and solidified safely. The peak temperature of thermal decomposition and the heat of decomposition of the BHN samples prepared were 305.8 °C and 210.9 J•g-1 at a heating rate of 10 K•min-1, respectively. The burning rate and pressure exponent of fuel rich solid propellants decreases with increases in the fraction of BHN particles in the propellant formulation. Compared with the reference formulation (sample BP-1), the burning rate of the propellant with 10% mass fraction of BHN particles (sample BP-4) had decreased 30% at 3.0 MPa, and the pressure exponent had dropped from 0.44 to 0.41.
    Źródło:
    Central European Journal of Energetic Materials; 2015, 12, 3; 537-552
    1733-7178
    Pojawia się w:
    Central European Journal of Energetic Materials
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
      Wyświetlanie 1-6 z 6

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