- Tytuł:
- Synthesis and Spectral Studies of Ru(II) Carbonyl Schiff Base Complexes
- Autorzy:
-
Prabhakaran, B.
Santhi, N.
Emayavaramban, M. - Powiązania:
- https://bibliotekanauki.pl/articles/412248.pdf
- Data publikacji:
- 2013
- Wydawca:
- Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
- Tematy:
-
Schiff base
ruthenium(II) complexes
tetradentate ligands
octahedral environment - Opis:
- The synthesis and characterization of hexa co-ordinated ruthenium(II) complexes of the type [Ru(CO)(B)(L)] (where B = PPh3, AsPh3, py or pip and L = dibasic tetradentate Schiff base ligand) were synthesized from the reaction of [RuHCl(CO)(B)(EPh3)2] (where E = P, B = PPh3, py or pip, E = As, B = AsPh3) with different tetradentate ligands. The ligands were derived by the condensation of 5-chloro-4-methyl-2-hydroxy benzophenone with ethylenediamine, propylenediamine and o-phenylene-diamine in 1:1 molar ratio. All the compounds have been characterized by elemental analysis and spectral (FT-IR, UV-VIS and 1H-NMR) methods. An octahedral environment around Ru(II) ion has been tentatively proposed for all the complexes.
- Źródło:
-
International Letters of Chemistry, Physics and Astronomy; 2013, 3; 53-66
2299-3843 - Pojawia się w:
- International Letters of Chemistry, Physics and Astronomy
- Dostawca treści:
- Biblioteka Nauki
Artykuł