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Wyświetlanie 1-3 z 3
Tytuł:
Characterization and Optimization study of Epiphyllum oxypetalum extract as corrosion inhibitor for mild steel in 3 M H2SO4 solutions
Autorzy:
Emembolu, L. N.
Onukwuli, O. D.
Okafor, V. N.
Powiązania:
https://bibliotekanauki.pl/articles/1030954.pdf
Data publikacji:
2020
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
Acid corrosion
Epiphyllum oxypetalum extract
Optimization
Photochemical
Response Surface Methodology
Opis:
This study investigated characterization of Epiphyllum oxypetalum (EO) leaf extracts and optimization of process variables on inhibition of mild-steel in 3 M H2SO4 aggressive environment. Response Surface Methodology (RSM) was employed to examine the influence of process variables namely acid concentration (1.0 – 3.0 mols), inhibitor concentration (0.2 – 1.0 g/l), time (1–10 hr) and temperature (303 -343K) on inhibition efficiency. The results of phytochemical screening showed that organic components present in EO extract as a good inhibitor. Fourier transform infrared spectroscopy (FTIR) and Scanning electron microscopy (SEM) studies established the presence of active compounds and adsorption of leaf extracts on metal surface. The experimental data was statistically analyzed and regression equations for corrosion rate and inhibition efficiency generated. The optimum conditions were achieved at acid concentration of 1.00 mol, inhibitor concentration of 0.055 g/l temperature of 333K, and time of 2.750 hr. The optimization results revealed that inhibition efficiency of 82.93 % was obtained at optimum combination of the extract concentration, the acid concentration, the temperature and the immersion time. The inhibitive potentials of EO extract was found to impede the localized and uniform corrosion of mild steel in acidic media, showing that the Epiphyllum oxypetalum leaf extract is a good inhibitor for mild steel in acidic solutions.
Źródło:
World Scientific News; 2020, 145; 256-273
2392-2192
Pojawia się w:
World Scientific News
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Optimization of polycondensation process of alkyd resin synthesis from modified Picralima nitida seed oil suitable for surface coating of metal
Autorzy:
Ezeugo, J. O.
Powiązania:
https://bibliotekanauki.pl/articles/1076136.pdf
Data publikacji:
2019
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
Artificial Neural Network
Picralima nitida seed oil
Response surface methodology
alkyd resin
Opis:
The potential of synthesizing an air drying alkyd resin through polycondensation of non-drying Picralima nitida seed oil (PNSO) was investigated. The structural elucidation of the raw PNSO, de-saturated PNSO and PNSO based alkyd resin were evaluated using FTIR. Design matrix and response Surface methodology were used to model the process variables. Artificial neural network was further used to examine the sensitivity analysis of the studied process variables. The results obtained showed that modified PNSO has high drying rate in the presence of drying agent, exhibit excellent adhesion, abrasion and chemical properties. Optimum responses of 82% conversion, viscosity of 269 cp and molecular weight average of 4434 g/mol were predicted at a temperature of 260 ºC, time of 134 mins, oil ratio of 0.286, catalyst concentration of 0.062 wt and a stirring rate of 595rpm. Correspondent experimental results using the same optimal conditions gave optimum conversion of 83% of alkyd resin, viscosity of 271cp and MWA of 4440 g/mol.
Źródło:
World Scientific News; 2019, 116; 62-90
2392-2192
Pojawia się w:
World Scientific News
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Production of Spindle Palm Petiole Fiber Reinforced High Density Polyethyele Composites
Autorzy:
Nneka, Ejikeugwu L.
Monday, Omotioma
Nnaemeka, Omeje B.
Uzoma, Eke R.
Powiązania:
https://bibliotekanauki.pl/articles/1839868.pdf
Data publikacji:
2021
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
Spindle palm petiole fiber
Sodium hydroxide
cellulose
chemical composition
Central Composite Design
Response Surface Methodology
tensile strength
polyethylene
Opis:
The work is on the production of spindle palm petiole fiber reinforced high density polyethylene (HDPE) composites. The Spindle Palm Petiole Fiber (SPPF) and HDPE composites were produced using injection molding machine. SPPF were characterized to determine their chemical compositions. Central Composite Design (CCD) was applied as an optimization tool of RSM for cellulose and tensile strength. The chemical composition of the SPPF is cellulose (65%), hemicelluloses (17.1%) and lignin (14.1%). Surface modifications of the fiber enhanced the properties of the fiber. Quadratic model adequately described the relationship between percentage cellulose yield and variables: chemical concentration, mass/volume ratio and time. The cellulose content at optimal level is 60.3% at 3.5wt% concentration, 4g/l mass/volume ratio and time of 16hr. Also for the composite, the quadratic model described the relationship between tensile strength and temperature, fiber/polymer ratio and time. The optimum tensile strength of 42.0 Mpa was obtained at fiber/polymer ratio of 29wt%, temperature of 172 °C and time of 10 min. Water absorbed by the untreated fiber was high compared to the chemically treated fiber. The chemical treatment created a better interfacial bonding of SPPF/HDPE and this could be responsible for the observations.
Źródło:
World News of Natural Sciences; 2021, 38; 98-119
2543-5426
Pojawia się w:
World News of Natural Sciences
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-3 z 3

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