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Wyszukujesz frazę "inhibition efficiency" wg kryterium: Temat


Wyświetlanie 1-2 z 2
Tytuł:
Corrosion inhibition potential of Terminalia avicennioides extract on mild steel in 1.0 M HCl: kinetics, thermodynamics and synergestic studies
Autorzy:
Ijuo, G. A.
Surma, N.
Oloruntoba, S. O.
Powiązania:
https://bibliotekanauki.pl/articles/1177459.pdf
Data publikacji:
2018
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
Terminalia avicennioides
inhibition efficiency
physisorption
synergestic effect
Opis:
The corrosion inhibition effect of Terminalia avicennioides (TA) stem extract in 1.0 M HCl solution was investigated using weight loss and electrochemical method. The operation variables considered include temperature (303-333 K) and concentration of the inhibitor (0.2 - 1.0 g/L). Inhibition efficiency increased from 21.88% to 88.71% with concentration but decreased with rise in temperature which is suggestive of physisorption. This was supported by the values of activation energies (Ea) obtained ranging from 22.67 KJ mol−1 to 60.67 KJ mol−1 which was lower than 80 KJ mol−1. The values of Gibb’s free energy of adsorption (∆Gads) indicated that the adsorption of the inhibitor on mild steel surface was a spontaneous process. The Kinetic treatment of the data followed a pseudo-first order reaction while the positive values obtained for enthalpy and entropy of activation is reflective of endothermic reaction nature and associative activation complex respectively. The adsorption mechanism followed the Langmuir adsorption isotherm model. Electrochemical analysis showed that the inhibitor functioned as a mixed type inhibitor. The inhibition efficiency of the inhibitor was found to be enhanced by the presence of KI. Therefore the extract functioned as good corrosion inhibitor for mild steel in 1.0 M HCl.
Źródło:
World Scientific News; 2018, 102; 1-16
2392-2192
Pojawia się w:
World Scientific News
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Characterization and optimization study of Ficus exasperata extract as corrosion inhibitor for mild steel in seawater
Autorzy:
Oyewole, O.
Aondoakaa, E.
Abayomi, T. S.
Ogundipe, S. J.
Oshin, T. A.
Powiązania:
https://bibliotekanauki.pl/articles/1031411.pdf
Data publikacji:
2021
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
Corrosion
Ficus exasperata
inhibition efficiency
optimization
weight loss
Opis:
This study investigated the characterization of Ficus exasperata extract and the optimization of the process variables on inhibition of mild steel in seawater environment. Box Behnken Design was employed to examine the influence of three process variables: Temperature: 25-29 °C; Time: 3 – 6 days; Inhibitor concentration: 1-5 v/v. Phytochemical screening of the extract was done. The physicochemical constituents of the seawater were also determined. The experimental data was statistically determined and Scanning Electron Microscope (SEM) was used to characterize the mild steel. The result of the phytochemical screening of the Ficus exasperata plant extract (FEPE) showed the presence of contain inhibitive constituents: alkaloids, tannins, saponins, flavonoids and glycosides. The highest inhibition efficiency of 86.31% at a temperature of 29 ℃ for 6days at an inhibition concentration of 3v/v was observed from the experimental run. The optimal process levels of time: 5.74 days, temperature: 27.95 ℃ and inhibitor concentration: 2.90v/v, gave 87.52% as its inhibition efficiency. The result of the SEM from the optimal process level validated showed that more passive film was formed which can be attributed to the adsorption of the Ficus exasperata extract. It can be concluded that the Ficus exasperata was a good eco-friendly inhibitor.
Źródło:
World Scientific News; 2021, 151; 78-94
2392-2192
Pojawia się w:
World Scientific News
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-2 z 2

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