- Tytuł:
- Theoretical evaluation of ultrasonic velocities of binary liquid mixtures of 1-bromopropane in chlorobenzene at 303.15, 308.15, 313.15 and 318.15 K
- Autorzy:
-
Babu, Ch. P.
Kumar, G. P.
Nagarjun, B.
Samatha, K. - Powiązania:
- https://bibliotekanauki.pl/articles/412079.pdf
- Data publikacji:
- 2014
- Wydawca:
- Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
- Tematy:
-
ultrasonic velocities
molecular interactions
1-bromopropane and chlorobenzene - Opis:
- Theoretical velocities of binary liquid mixtures of 1-bromopropane with chlorobenzene at 2 MHz and four different temperatures 303.15, 308.15, 313.15 and 318.15 K, have been evaluated as a function of concentration and temperature. The experimental values are compared with theoretical models of liquid mixtures such as Nomoto, Van Dael-Vangeel, Impedance Relation, Rao’s Specific Velocity Method, Junjie’s relations and Free Length Theory. In the chosen system there is a good agreement between experimental and theoretical values calculated by Nomoto’s theory. The deviation in the variation of U2exp/ U2imx from unity has also been evaluated for explaining the non ideality in the mixtures. The results are explained in terms of intermolecular interactions occurring in these binary liquid mixtures.
- Źródło:
-
International Letters of Chemistry, Physics and Astronomy; 2014, 11, 1; 9-17
2299-3843 - Pojawia się w:
- International Letters of Chemistry, Physics and Astronomy
- Dostawca treści:
- Biblioteka Nauki
Artykuł