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Wyświetlanie 1-15 z 20
Tytuł:
Study of uni-univalent H+/K+ and uni-bivalent H+/Mg2+ ion exchange reactions using nuclear grade resin Indion-223
Autorzy:
Singare, P. U.
Mohammed, A. K. L.
Dixit, N. N.
Powiązania:
https://bibliotekanauki.pl/articles/411848.pdf
Data publikacji:
2014
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
ion exchange equilibrium
nuclear grade resins
cation exchange
enthalpy change
equilibrium constant
Indion-223
Opis:
In the present paper the uni-univalent and uni-bivalent ion exchange reactions were investigated using nuclear grade anion exchange resin Indion-223 in H+ form. For both H+/K+ uni-univalet ion exchange reactions and H+/Mg2+ uni-bivalet ion exchange reactions, the equilibrium constant K values increases from 0.01710 to 0.02374 and from 0.000177 to 0.000333 respectively as the reaction temperature rises from 35.0 °C to 45.0 °C. The increase in K values with temperature suggest endothermic ion exchange reactions having the enthalpy change values of 22.72 and 51.46 kJ/ mol respectively. The results of such studies will help in selection of suitable ion exchange resins in order to bring about efficient separation of different ionic species present in the waste water effluents released from nuclear as well as chemical process industries.
Źródło:
International Letters of Chemistry, Physics and Astronomy; 2014, 14, 2; 231-239
2299-3843
Pojawia się w:
International Letters of Chemistry, Physics and Astronomy
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Frequency Dependent Incidence Model for Acute and Chronic Schistosomiasis
Autorzy:
Derick, Ngobi
Onuorah, Martins O.
Powiązania:
https://bibliotekanauki.pl/articles/1077429.pdf
Data publikacji:
2019
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
Schistosomiasis
acute
chronic
endemic
equilibrium
stability
Opis:
In this research work, a deterministic mathematical model for schistosomiasis transmission dynamics is presented. The model consists of five non-liniar ordinary differential equations incorporating the acute and chronic infectious compartments. The basic reproductive number, (the number of secondary infections when a single infectious individual is introduced into a population where everyone is susceptible) was obtained. Furthermore, we gained and analyzed for stability, the disease-free and endemic equilibrium. The qualitative feature of the model shows that the long-term behavior of the model is independent of initial conditions. Numerical simulation of the various state variables were obtained using matlab software.
Źródło:
World News of Natural Sciences; 2019, 23; 276-296
2543-5426
Pojawia się w:
World News of Natural Sciences
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Generalization of Onsager’s reciprocal relations
Autorzy:
Etkin, V. A.
Powiązania:
https://bibliotekanauki.pl/articles/1182820.pdf
Data publikacji:
2017
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
consequences
differential reciprocal relations
generalization
non-equilibrium thermodynamics
substantiation
verification
Opis:
Shows, that it is possible to expand the existing theory of irreversible processes to processes of useful transformation of any forms of energy by a finding of motive forces and the speeds of real processes as derivative of energy, but not entropy; that for such processes there are differential reciprocal relations with Onsager’s symmetry and Cazimir’s anti-symmetry conditions resulting from them; that Maxwell’s equations follows from these correlation, confirming their equity for a wide class of processes, satisfying to these equations
Źródło:
World Scientific News; 2017, 64; 44-53
2392-2192
Pojawia się w:
World Scientific News
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The Inverse Reaction Cross Sections for Some Charged Particles Using the Optical Model Parameters
Autorzy:
Ahmed, Rasha S.
Powiązania:
https://bibliotekanauki.pl/articles/1193016.pdf
Data publikacji:
2016
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
Optical reaction cross-sections
charged particles
neutrons
pre-equilibrium models
Opis:
p-nucleus, (_1^2)H-nucleus, (_1^3)H-nucleus, and (_2^4)He-nucleus inverse reaction cross sections have been determined using the optical model potentials in a wide range of target nuclei started from A=1 to A=232 using several incident particle energies ( E = 2, 8, 10, 20, and 40 MeV). In this work, a large number of optical model available parameters were used to calculate the inverse reaction cross section and compared to investigate the effect of the mass number and incident particle energy on the inverse reaction cross section. All the calculations were performed using MATHLAB programming language.
Źródło:
World Scientific News; 2016, 28; 72-83
2392-2192
Pojawia się w:
World Scientific News
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Stability Analysis of Mahananda River Embankment in Bangladesh
Autorzy:
Ali, Rubieyat Bi
Islam, Md. Mofizul
Sikder, Bijoy
Alim, Md. Abdul
Powiązania:
https://bibliotekanauki.pl/articles/1075439.pdf
Data publikacji:
2019
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
Mahananda River
Stability of slope
limit equilibrium method
seismic coefficient
Opis:
Stability of structures such as embankments, dams and natural riverside slopes are hampered due to the seismic loading. To evaluate the seismic effect on the stability of slopes is a major concern in the field of geotechnical engineering. Two-dimensional limit equilibrium method (LEM) is a common approach for analyzing slope stability. Usually LEM is used to find out potential failure mechanisms and factors of safety for the slopes. The aim of this study is to evaluate the effect of seismic loading on the stability of Mahananda River Embankment of Bangladesh by using LEM. The Bishop, Spencer, Fellenius, Janbu and Morgenster-price simplified methods were used for LEM. To conduct the study three locations of Mahananda River Embankment were selected. Soil properties were obtained from laboratory testing. The numerical analysis was carried out using geotechnical software GEO5 which is generally used for analyzing LEM based slope stability problems. From the analysis, it was noted that the factors of safety decreased with the increase of horizontal seismic coefficient for the slopes. The horizontal seismic coefficient alone affects the stability of slope severely than the combined effect of horizontal and vertical seismic coefficient. The results concluded that the present condition of the Mahananda river embankment is stabilized under seismic loading.
Źródło:
World Scientific News; 2019, 126; 118-135
2392-2192
Pojawia się w:
World Scientific News
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The phenomenon of gravitational repulsion in the cosmic medium
Autorzy:
Etkin, V. A.
Powiązania:
https://bibliotekanauki.pl/articles/1163538.pdf
Data publikacji:
2018
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
Universe
attraction and repulsive force
baryonic and non-baryonic matter
gravitational equilibrium
Opis:
On the basis of the thermodynamic theory of transfer and transformation of all forms of energy and of the principle of mass-energy equivalence is established a more general law of gravity, according to which in the non-baryonic matter there is a gravitational force of attraction and repulsion. This theory predicts the existence of gravitational equilibrium, strong and weak gravity, as well as the presence of huge free gravitational energy reserves with the possibility of its use. This makes unnecessary the introduction of dark energy as a hypothetical medium, causing the accelerated expansion of the Universe. The theory considers the occurrence of radiation capable baryonic matter as a result of the phase transition (condensation) non-baryonic matter during its compaction forces of gravity with the rise of the new degrees of freedom. She explains the presence of libration zones, phenomenon of stellar matter overflow in binary systems, the anomalies in the behavior of space probes, structuring processes in the Universe, collapse, flash "supernova" etc. The predictions of the theory are confirmed data of astronomical observations of recent years.
Źródło:
World Scientific News; 2018, 109; 167-179
2392-2192
Pojawia się w:
World Scientific News
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Thermodynamics of uni-univalent H+/K+ and uni-bivalent H+/Ca2+ ion exchange reactions using nuclear grade resin Indion-223
Autorzy:
Singare, P. U.
Mohammed, A. L. K.
Dixit, N. N.
Powiązania:
https://bibliotekanauki.pl/articles/412388.pdf
Data publikacji:
2014
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
ion exchange
nuclear grade resins
cation exchangers
enthalpy change
standard equilibrium constant
Indion-223
Opis:
The present paper deals with the thermodynamic of uni-univalent and uni-bivalent ion exchange reactions using nuclear grade anion exchange resin Indion-223. It was observed that with rise in temperature the equilibrium constants K values for H+/K+ uni-univalet ion exchange reaction increases from 0.01710 to 0.02374. Similarly for H+/Ca2+ uni-bivalet ion exchange reaction the equilibrium constants K values increases from 0.000397 to 0.000639. The increase in K values with rise in temperature for both the reactions indicates its endothermic nature having the enthalpy change values of 22.72 and 38.92 kJ/ mol respectively. The technique used here can be extended further to standardise the process parameters in order to bring about the efficient separation of the desired ionic species from the solution.
Źródło:
International Letters of Chemistry, Physics and Astronomy; 2014, 14, 2; 190-198
2299-3843
Pojawia się w:
International Letters of Chemistry, Physics and Astronomy
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Comparative study of uni-univalent H⁺/Na⁺ and uni-bivalent H⁺/Ca²⁺ ion exchange reactions using nuclear grade resin Indion-223
Autorzy:
Singare, P. U.
Mohammed, A. L. K.
Dixit, N. N.
Powiązania:
https://bibliotekanauki.pl/articles/411747.pdf
Data publikacji:
2014
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
ion exchange reactions
nuclear grade resins
cation exchange resins
enthalpy
equilibrium constant
Indion-223
Opis:
The present paper deals with the ion exchange equilibrium studies of uni-univalent and uni-bivalent ion exchange reactions using nuclear grade anion exchange resin Indion-223 in H⁺ form towards Na⁺ and Ca²⁺ ions in the solution. It was observed that with rise in temperature the equilibrium constants K values for H⁺/Na⁺ uni-univalet ion exchange reaction increases from 0.01389 to 0.01855. Similarly for H⁺/Ca²⁺ uni-bivalet ion exchange reaction the equilibrium constants K values increases from 0.000397 to 0.000639. The increase in equilibrium constant values with rise in temperature indicate endothermic ion exchange reactions having the enthalpy change values of 25.55 and 38.92 kJ/ mol respectively.
Źródło:
International Letters of Chemistry, Physics and Astronomy; 2014, 14, 2; 127-135
2299-3843
Pojawia się w:
International Letters of Chemistry, Physics and Astronomy
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Modeling and analysis of batch extraction process for efficient removal of cadmium and pathogens from aqueous solution using modified plantain peel biochar
Autorzy:
Nworie, F. S.
Oti, W. O.
Nwali, U.
Powiązania:
https://bibliotekanauki.pl/articles/1193435.pdf
Data publikacji:
2021
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
Aspergillus
Biochar
Candida
Escherichia coli
Pseudomonas aeuroginosa
Staphylococcus aureus
cadmium (II)
equilibrium studies
mass transfer
pathogens
Opis:
Consumption of water contaminated with pathogens and heavy metals is responsible for the demise of millions of people around the globe. To find a low cost, facile and benign route for developing a biosorbent capable of handling the challenges associated with unsafe drinking water, the study report the preparation, activation, adsorption and removal of cadmium and pathogenic organisms from water samples. Modified plantain peel biochar (MPPB) was characterized using Braunauer-Emmett-Teller (BET) surface area and X-Ray diffraction (XRD). Surface area and pore size of the MPPB determined from BET surface area plot are 8.79 cc/g and 16.69 m2/g respectively with XRD crystallite size of 14.56 nm. The maximum adsorption capacity was observed to be 366.300 mmolkg-1. Equilibrium isotherm indicated the coefficient of determination to increase from Jovanovich →Elovic→Temkin→Freundlich→Langmuir model. Surface interaction and mass transfer kinetics shows a mixture of intra-particle diffusion and mass transfer process. The adsorption kinetics and surface interaction models coefficient of determination increased from Bangham pore diffusion →mass transfer model→Liquid film diffusion→pseudo first order→Dunwald-Wagner→Elovic→Pseudo-second order→Weber and Moris model. The adsorption indicated a chemisorption process with rate limitimg step likely to involve electron pair donor-acceptor interactions, hydrogen bonding and dipole dipole interactions. Antimicrobial evaluation of MPPB showed that it is a potential antimicrobial agent against common micro-organisms.
Źródło:
World Scientific News; 2021, 157; 1-24
2392-2192
Pojawia się w:
World Scientific News
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Mathematical Modeling of Control Strategies for Visceral leishmaniasis
Autorzy:
Onyekwelu, Onuorah Martins
Baker, Nasasira
Powiązania:
https://bibliotekanauki.pl/articles/1839477.pdf
Data publikacji:
2021
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
Stability
equilibrium
parameterization
endemic
basic reproductive number
simulation
visceral Leishmaniasis
Visceral leishmaniasis
kala-azar
Cutaneous leishmanisis
Opis:
In this paper, a deterministic mathematical model for the transmission dynamics of Visceral leishmaniasis (VL) was formulated and analyzed. The basic reproductive number R0 was obtained using the next generation matrix method. The model which was parameterized using the 2011 cases of Visceral Leishmaniasis in South Sudan, was used to assess two control measures. Numerical simulation reveals that the exposed population is reduced by high detection rate, and low biting rate of sandflies. Further, our model simulation gave the values of the contact rate of susceptible human, α1 and the detection rate of new cases, σ at which the basic reproductive number is less than one, (R0 < 1), equal to one (R0 = 1) and greater than one (R0 > 1).
Źródło:
World News of Natural Sciences; 2021, 37; 102-116
2543-5426
Pojawia się w:
World News of Natural Sciences
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Ion exchange equilibrium studies of uni-univalent H+/Na+ and uni-bivalent H+/Mg2+ ion exchange reactions using nuclear grade resin Indion-223
Autorzy:
Singare, P. U.
Mohammed, A. L. K.
Dixit, N. N.
Powiązania:
https://bibliotekanauki.pl/articles/412153.pdf
Data publikacji:
2014
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
cation exchange
nuclear grade resins
ion exchangers
change in enthalpy
equilibrium constant in standard state
Indion-223
Opis:
In the present investigation the uni-univalent and uni-bivalent ion exchange reactions were studied using nuclear grade anion exchange resin Indion-223 in H+ form. It was observed that for H+/Na+ uni-univalet ion exchange reaction, with rise in temperature the equilibrium constants K values increases from 0.01389 to 0.01855. Similarly increase in K values was observed from 0.000177 to 0.000333 for H+/Mg2+ uni-bivalet ion exchange reaction. The increase in equilibrium constant values with rise in temperature indicate endothermic ion exchange reactions having the enthalpy change values of 25.55 and 51.46 kJ/ mol respectively. It is expected that the present study will provide valuable information in order to decide about the selection of those resins for efficient separation of various ionic species present in the industrial waste water effluents.
Źródło:
International Letters of Chemistry, Physics and Astronomy; 2014, 14, 2; 199-207
2299-3843
Pojawia się w:
International Letters of Chemistry, Physics and Astronomy
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Modified Coulomb law
Autorzy:
Etkin, V. A.
Powiązania:
https://bibliotekanauki.pl/articles/1179008.pdf
Data publikacji:
2017
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
Coulomb and Newton laws
attraction and repulsion
dipole representation
electric charge
equilibrium
interaction
polarization
unified field theory
Opis:
A field form of the Coulomb law is proposed, which describes the electric field as a function of the charge density gradient. This law is analogous in form to the modified Newton's law and similarly it reveals the possibility of attraction and repulsion of charges of the same sign as a function of the direction of the gradient of its density, and also the existence of electrostatic equilibrium. As an example of the use of this law, the erroneousness of the assertion that there are no free charges in the volume of the conductor is shown and a new treatment of the polarization processes is given as a result of the redistribution of charges of the same sign in it. A solution is proposed for the stability of atoms and their nuclei on the basis of electrostatic equilibrium and the wave concept of the structure of matter. Experimental confirmations of the proposed concept are presented.
Źródło:
World Scientific News; 2017, 87; 163-174
2392-2192
Pojawia się w:
World Scientific News
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Study on preferential selectivity of nuclear grade resin Indion-223 towards some bivalent ions
Autorzy:
Singare, P. U.
Mohammed, A. L. K.
Dixit, N. N.
Powiązania:
https://bibliotekanauki.pl/articles/412085.pdf
Data publikacji:
2014
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
bivalent exchange reactions
nuclear grade resins
cation exchange
reaction thermodynamics
enthalpy change
ionic selectivity
equilibrium constant
Indion-223
Opis:
In the present paper attempts are made to understand the selectivity of nuclear grade cation exchange resin Indion-223 in H+ form towards Ca2+ and Mg2+ bivalent ions in the solution based on thermodynamic concept. It was observed that with rise in temperature the equilibrium constant K values for H+/Ca2+ uni-bivalet ion exchange reactions increases from 0.000397 to 0.000639. Similarly for H+/Mg2+ uni-bivalet ion exchange reactions the equilibrium constant K values increases from 0.000177 to 0.000333. The increase in equilibrium constant values with rise in temperature indicate endothermic ion exchange reactions having the enthalpy change values of 38.92 and 51.46 kJ/ mol respectively. The difference in K values and enthalpy values were used to predict the selectivity behaviour of the resin towards the Ca2+ and Mg2+ bivalent ions in the solution. The thermodynamic concept of the present study can be applied to understand the selectivity behaviour of different nuclear as well as non-nuclear grade resins towards wide range of ionic species present in the exchanging liquid medium.
Źródło:
International Letters of Chemistry, Physics and Astronomy; 2014, 15; 11-21
2299-3843
Pojawia się w:
International Letters of Chemistry, Physics and Astronomy
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Thermodynamic study to evaluate the selectivity behaviour of nuclear grade resin Indion-223 towards some univalent ions
Autorzy:
Singare, P. U.
Mohammed, A. L. K.
Dixit, N. N.
Powiązania:
https://bibliotekanauki.pl/articles/412486.pdf
Data publikacji:
2014
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
uni-univalent ion exchange reactions
ionic selectivity
nuclear grade resins
cation exchangers
enthalpy change
equilibrium constant
Indion-223
Opis:
The present paper deals with the application of thermodynamic concept in understanding the preferential selectivity of nuclear grade anion exchange resin Indion-223 in H+ form towards Na+ and K+ ions in the solution. In the study it was observed that the equilibrium constants K values for H+/Na+ and H+/K+ uni-univalet ion exchange reactions increases from 0.01389 to 0.01855 and from 0.01710 to 0.02374 respectively as the temperature increases from 35.0 °C to 45.0 °C. The increase in K values with rise in temperature suggests endothermic ion exchange reactions having the enthalpy change values of 25.55 and 22.72 kJ/ mol respectively. Based on difference in K values and enthalpy values for the two uni-univalent ion exchange reactions, the preferential selectivity of the resin for the univalent ions in the solution was predicted. From the results of present study, it appears that the experimental technique used here can be applied further to understand the ionic selectivity of different industrial grade ion exchange resins. It is expected that such studies will provide valuable information in order to decide about the selection of those resins for efficient separation of various ionic species present in the industrial waste water effluents.
Źródło:
International Letters of Chemistry, Physics and Astronomy; 2014, 15; 22-29
2299-3843
Pojawia się w:
International Letters of Chemistry, Physics and Astronomy
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Study on Halide Ions Selectivity of Industrial Grade Anion Exchange Resin Auchlite A-378
Autorzy:
Singare, P. U.
Patange, A. N.
Powiązania:
https://bibliotekanauki.pl/articles/412220.pdf
Data publikacji:
2014
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
selectivity
ion exchange reactions
halide ions
industrial grade resins
anion exchange resins
enthalpy
equilibrium constant
Auchlite A-378
Opis:
The thermodynamic approach was applied to predict the trend selectivity of industrial grade anion exchange resin Auchlite A-378 in chloride form towards iodide and bromide ions in the solution. The study was conducted by performing the Clˉ/Iˉ and Clˉ/Brˉ uni-univalent ion exchange reactions under gradually increasing temperature conditions. The thermodynamic equilibrium constants K values were used to calculate the enthalpies of the two uni-univalent ion exchange reactions. It was observed that the K values for Clˉ/Iˉ ion exchange reaction were higher than Clˉ/Brˉ exchange reaction under identical experimental conditions. Also the enthalpy values for the two uni-univalent ion exchange reactions were calculated as -39.51 and -18.38 kJ/mol respectively. The high K and low enthalpy values obtained for Clˉ/Iˉ ion exchange reaction is responsible for higher selectivity of the resin towards iodide ions as compared to that towards bromide ions, when both the ions are present in the same solution.
Źródło:
International Letters of Chemistry, Physics and Astronomy; 2014, 11, 1; 44-50
2299-3843
Pojawia się w:
International Letters of Chemistry, Physics and Astronomy
Dostawca treści:
Biblioteka Nauki
Artykuł
Wyświetlanie 1-15 z 20

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