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Wyszukujesz frazę "Mössbauer Spectroscopy" wg kryterium: Temat


Wyświetlanie 1-3 z 3
Tytuł:
High temperature transformation of iron-bearing minerals in basalt: Mössbauer spectroscopy studies
Autorzy:
Kądziołka-Gaweł, Mariola
Wojtyniak, Marcin
Klimontko, Joanna
Powiązania:
https://bibliotekanauki.pl/articles/2086563.pdf
Data publikacji:
2022
Wydawca:
Polskie Towarzystwo Mineralogiczne
Tematy:
basalts
high temperature affects
Mössbauer spectroscopy
Fe-bearing minerals
Opis:
The high temperature decomposition of basalt from Lower Silesia (Poland) was followed by Mössbauer spectroscopy investigation. The Fe content of the sample was ~9.0 at.%. The X-ray diffraction analysis shows that augite (37%) and olivine (12%) are major Fe-bearing mineral components. The sample also contains significant amount of anorthite (22%) and nepheline (17%). The sample was heated at various temperatures between 200o C and 1100o C for three hours. Up to a temperature of 500o C changes in contribution of Fe-bearing minerals are insignificant. Heating in the temperature range from 500o C to 1100o C leads to a systematic increase in contribution of iron oxides at the cost of contribution of silicate minerals, like augite and olivine. Mössbauer spectrum obtained after heating at 1100o C showed hematite as the main iron oxide phase. The ratio of Fe3+/Fetot in the non-heated sample was equal to 0.51 and after heating at 1100o C this ratio amounted to 0.89.
Źródło:
Mineralogia; 2022, 53, 1; 10--19
1899-8291
1899-8526
Pojawia się w:
Mineralogia
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Characterization of granites by 57Fe Mössbauer spectroscopy
Autorzy:
Hassan, Kamaleldin M.
Powiązania:
https://bibliotekanauki.pl/articles/2086511.pdf
Data publikacji:
2009
Wydawca:
Polskie Towarzystwo Mineralogiczne
Tematy:
granitic type
clinopyroxene
mica
amphibole
Mössbauer spectroscopy
oxygen fugacity
Western Desert
Opis:
Two granite complexes in Egypt, a sodic type and an aluminous type are characterized by Mössbauer spectroscopy. Mössbauer spectra (MS) of the sodic granite show a major doublet of ferric (Fe3+) iron that is attributable to octahedral coordination (M1) sites plus/minus a tetrahedron Fe3+ doublet plus/minus a doublet of ferrous (Fe2+) iron on the M1 sites plus/ minus another Fe2+ (M1) doublet and a sextet of Fe3+. The sextet is attributed to -Fe2O3 (hematite) and the other Fe components are due to NaCaFeSi2O6 (aegirine-augite) plus/minus minor contributions from (Ca2(Mg,Fe)5(Si,Al)8O22(OH)2 (magnesium-hornblende). Changes in the quadrupole splitting and width line of Fe2+ ions are likely composition-related. The MS of the aluminous-type granite, on the other hand, shows evidence only of single doublets containing Fe2+ or Fe3+ in the octahedral M1 sites, with parameters that remain almost constant. This consistency implies that the existing minerals – K(Mg,Fe2+)3 (Al,Fe3+)Si3O10(OH,F)2 (biotite), (Mg,Fe)6(Si,Al)4O10(OH)8 (clinochlore), (Na,K)Ca2(Fe,Mg)5(Al,Si)8O22(OH)2 (ferrohornblende and magnesiohornblende) – have similar iron positions. The intensity of iron oxidized (Fe3+/Fe) for the sodic granite is 79.1 to 100% and for the aluminous granite, 28.4 to 38.2%. The observed Fe3+/Fe differences between the two granites are source- -related and consistent with distributions of other redox-sensitive elements.
Źródło:
Mineralogia; 2009, 40, 1/4; 95--106
1899-8291
1899-8526
Pojawia się w:
Mineralogia
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Characterization of granites by 57Fe Mössbauer spectroscopy
Autorzy:
Hassan, K. M.
Powiązania:
https://bibliotekanauki.pl/articles/2086557.pdf
Data publikacji:
2009
Wydawca:
Polskie Towarzystwo Mineralogiczne
Tematy:
granitic type
clinopyroxene
mica
amphibole
Mössbauer spectroscopy
oxygen fugacity
Western Desert
Opis:
Two granite complexes in Egypt, a sodic type and an aluminous type are characterized by Mössbauer spectroscopy. Mössbauer spectra (MS) of the sodic granite show a major doublet of ferric (Fe3+) iron that is attributable to octahedral coordination (M1) sites plus/minus a tetrahedron Fe3+ doublet plus/minus a doublet of ferrous (Fe2+) iron on the M1 sites plus/ minus another Fe2+ (M1) doublet and a sextet of Fe3+. The sextet is attributed to -Fe2O3 (hematite) and the other Fe components are due to NaCaFeSi2O6 (aegirine-augite) plus/minus minor contributions from (Ca2(Mg,Fe)5(Si,Al)8O22(OH)2 (magnesium-hornblende). Changes in the quadrupole splitting and width line of Fe2+ ions are likely composition-related. The MS of the aluminous-type granite, on the other hand, shows evidence only of single doublets containing Fe2+ or Fe3+ in the octahedral M1 sites, with parameters that remain almost constant. This consistency implies that the existing minerals – K(Mg,Fe2+)3 (Al,Fe3+)Si3O10(OH,F)2 (biotite), (Mg,Fe)6(Si,Al)4O10(OH)8 (clinochlore), (Na,K)Ca2(Fe,Mg)5(Al,Si)8O22(OH)2 (ferrohornblende and magnesiohornblende) – have similar iron positions. The intensity of iron oxidized (Fe3+/Fe) for the sodic granite is 79.1 to 100% and for the aluminous granite, 28.4 to 38.2%. The observed Fe3+/Fe differences between the two granites are source- -related and consistent with distributions of other redox-sensitive elements.
Źródło:
Mineralogia; 2009, 40, 1/4; 95--106
1899-8291
1899-8526
Pojawia się w:
Mineralogia
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-3 z 3

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